V2115838, V2119838, V2118838, 209565, 209750, 209751, 209752, 209719 Rust-Oleu... Page 1 of 6
Material Safety Data 24 Hour Assistance:
1-847-367-7700
Sheet
Rust-Oleum Corp.
www.rustoleum.com
Section 1 - Chemical Product / Company Information
Rust-Oleum High Performance
Industrial Enamel Aerosol - Metallics
Product Name: Revision Date: 08/27/2004
(Hard Hat)
V2115838, V2119838, V2118838,
Identification
209565, 209750, 209751, 209752,
Number:
209719
Product Use/Class: Metallic/Aerosol
Rust-Oleum Corporation Rust -Oleum Corporation
Supplier: Manufacturer:
11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, IL 60061 Vernon Hills, IL 60061
USA USA
Preparer: Cziczo, Ray
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA PEL-CEILING
Than
Toluene 108-88-3 35.0 50 PPM 150 PPM 200 PPM 300 PPM
Liquified Petroleum Gas 68476-86-8 35.0 1000 PPM N.E. 1000 PPM N.E.
Acetone 67-64-1 30.0 500 PPM 750 PPM 750 PPM N.E.
Xylene 1330-20 -7 10.0 100 PPM 150 PPM 100 PPM N.E.
Steel Flake Alloy MIXTURE 10.0 N.E. N.E. N.E. N.E.
Magnesium Silicate 14807-96-6 10.0 10 mg/m3 N.E. 15 mg/m3 N.E.
N-Butyl Acetate 123-86-4 10.0 150 PPM 200 PPM 150 PPM N.E.
Aluminum Flake 7429-90 -5 10.0 10 mg/m3 N.E. 15 mg/m3 N.E.
Stoddard Solvents 8052-41 -3 5.0 100 PPM N.E. 500 PPM N.E.
Ethylbenzene 100-41-4 5.0 100 PPM 125 PPM 100 PPM N.E.
Ethylene Glycol Monobutyl Ether 111-76-2 5.0 20 PPM N.E. 50 PPM N.E.
Propylene Glycol Monomethyl 108-65-6 5.0 N.E. N.E. N.E. N.E.
Ether Acetate
Titanium Dioxide 13463-67-7 5.0 10 mg/m3 N.E. 10 mg/m3 N.E.
Section 3 - Hazards Identification
*** Emergency Overview ***: Harmful if inhaled. May affect the brain or nervous system causing dizziness,
headache or nausea. Contents Under Pressure. Vapors may cause flash fire or explosion. Extremely flammable
liquid and vapor. Harmful if swallowed.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: May be harmful if absorbed through skin. Prolonged or repeated
contact may cause skin irritation. Substance may cause slight skin irritation.
Effects Of Overexposure - Inhalation: High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Avoid breathing vapors or mists. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Harmful if
inhaled.
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Effects Of Overexposure - Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage.
Substance may be harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: IARC lists Ethylbenzene as a possible human carcinogen (group
2B). May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness,
fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to
xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver,
cardiac abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been
associated with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and
cardiac abnormalities.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Section 4 - First Aid Measures
First Aid - Eye Contact: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Get medical
attention.
First Aid - Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists.
First Aid - Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued
difficulty is experienced, get medical assistance immediately.
First Aid - Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material
can enter the lungs and cause severe lung damage. Get immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point: -156 F LOWER EXPLOSIVE LIMIT: 1.0 %
(Setaflash) UPPER EXPLOSIVE LIMIT : 12.8 %
Extinguishing Media: Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: Vapors can travel to a source of ignition and flash back. Vapors may form
explosive mixtures with air. Closed containers may explode when exposed to extreme heat. Water spray may be
ineffective. FLASH POINT IS LESS THAN 20 ? F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!
Perforation of the pressurized container may cause bursting of the can. Isolate from heat, electrical equipment,
sparks and open flame. Keep containers tightly closed.
Special Firefighting Procedures: Evacuate area and fight fire from a safe distance.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert
absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not
incinerate closed containers.
Section 7 - Handling And Storage
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Handling: Wash thoroughly after handling. Wash hands before eating. Use only in a well -ventilated area. Follow
all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid
breathing vapor or mist.
Storage: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not
store above 120 ?F. Store large quantities in buildings designed and protected for storage of NFPA Class I
flammable liquids. Contents under pressure. Do not expose to heat or store above 120 ?F.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Use explosion-proof ventilation equipment. Prevent build -up of vapors by opening all doors
and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits.
Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA
approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain
circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is
any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air
purifying respirators may not provide adequate protection.
Skin Protection: Use impervious gloves to prevent skin contact and absorption of this material through the skin.
Nitrile or Neoprene gloves may afford adequate skin protection.
Eye Protection: Use safety eyewear designed to protect against splash of liquids.
Other protective equipment: Refer to safety supervisor or industrial hygienist for further information regarding
personal protective equipment and its application.
Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or smoking.
Section 9 - Physical And Chemical Properties
Boiling Range: 130 - 698 F Vapor Density: Heavier than air
Odor: Odor Threshold:
Solvent Like ND
Appearance: Evaporation Rate:
Liquid Faster than Ether
Solubility in H2O: Slight
Freeze Point: Specific Gravity:
ND 0.7520
Vapor Pressure: PH: NE
Physical State: Liquid
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Avoid all possible sources of ignition. Flammable hydrogen gas will evolve when product
comes in contact with water or damp air. Heat will be generated. The amount of heat generated will depend upon
the volume of material in contact. Avoid temperatures above 120 ?F.
Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
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Hazardous Decomposition: When heated to decomposition it emits acrid smoke and irritating fumes. By open
flame, carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: ND Product LC50: ND
Chemical Name LD50 LC50
Toluene N.D. N.D.
Liquified Petroleum Gas N.D. N.D.
Acetone N.D. N.D.
Xylene N.D. N.D.
Steel Flake Alloy N.D. N.D.
Magnesium Silicate N.D. TCLo:11mg/m3
inh.
N-Butyl Acetate 13100 mg/kg 2000 PPM (INH 4
(ORAL, RAT) Hr, RAT)
Aluminum Flake N.D. N.D.
Stoddard Solvents N.D. N.D.
Ethylbenzene 3500 mg/kg N.D.
(ORAL, RAT)
Ethylene Glycol Monobutyl Ether 1519 mg/kg 700 PPM (INH 7
(ORAL, MOUSE) Hr, RAT)
Propylene Glycol Monomethyl Ether Acetate >10000 mg/kg N.D.
(ORAL, RAT)
Titanium Dioxide >7500 mg/kg N.D.
(ORAL, RAT)
Section 12 - Ecological Information
Ecological Information: Product is a mixture of listed components.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do
not allow to enter storm drains or sewer systems.
Section 14 - Transportation Information
DOT Proper Shipping Name: Aerosol Packing Group: ---
DOT Technical Name: --- Hazard Subclass: ---
DOT Hazard Class: 2 Resp. Guide Page: 126
DOT UN/NA Number: UN 1950
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Section 15 - Regulatory Information
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA Section 313:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Toluene 108-88-3
Xylene 1330-20-7
Steel Flake Alloy MIXTURE
Ethylbenzene 100-41-4
Ethylene Glycol Monobutyl Ether 111-76-2
Toxic Substances Control Act:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of
TSCA 12(B) if exported from the United States:
None known
U.S. State Regulations: As follows -
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
Alkyd Resin MIXTURE
Acrylic Resin PROPRIETARY
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
Alkyd Resin MIXTURE
Acrylic Resin PROPRIETARY
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
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Chemical Name CAS Number
Ethylbenzene 100-41-4
Microcrystalline Silica 14808-60-7
Propylene Oxide 75-56-9
Benzene 71-43-2
Arsenic Compounds NOT SPECIFIED
Cadmium Compounds NOT SPECIFIED
Acetaldehyde 75-07-0
Nickel Compounds NOT SPECIFIED
Ethylene Oxide 75-21-8
Lead Compounds NOT SPECIFIED
Formaldehyde 50-00-0
Warning: The following ingredients present in the product are known to the state of California to cause birth
defects, or other reproductive hazards.
Chemical Name CAS Number
Toluene 108-88-3
Benzene 71-43-2
Arsenic Compounds NOT SPECIFIED
Cadmium Compounds NOT SPECIFIED
Mercury Compounds NOT SPECIFIED
Ethylene Glycol Monoethyl Ether 110-80-5
Ethylene Oxide 75-21-8
Lead Compounds NOT SPECIFIED
International Regulations: As follows -
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: AB5 D2A D2B
Section 16 - Other Information
HMIS Ratings:
Health: 2* Flammability: 4 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, g/l: 620 Max
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained on this MSDS has been checked and should be accurate. However, it is the
responsibility of the user to comply with all Federal, State, and Local laws and regulations.
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