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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.02.2010 Revision: 12.02.2010
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: Suprotex?BNS
?Article number: 114260
?Application of the substance / the preparation Vulcanisation agent
?Manufacturer/Supplier:
Weserland GmbH
P.O. Box 21 04 80, 30404 Hannover (Germany)
Hansastrasse 9 - 17, 30419 Hannover (Germany)
phone: +49 (0)511 / 97997-0 / fax: +49 (0)511 / 97997-70
e-mail: info@weserland.eu
www.weserland.eu
?Further information obtainable from:
Quality / environment department, Andreas Ehrle, email: ehrle@weserland.eu
?Information in case of emergency:
Due operating hours
Dept. Quality/Environment
Phon +49 511 97997-36
or Phon +49 511 97997-0
* 2 Hazards identification
?Hazard description:
Xi Irritant
N Dangerous for the environment
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitisation by skin contact.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
* 3 Composition/information on ingredients
?Description:
Aqueous dispersion of zinc oxide, sulphur, anti-aging agent, vulcanisations accelerators and additives.
?Dangerous components:
CAS: 1314-13-2 zinc oxide 2.5-10%
EINECS: 215-222-5 N; R 50/53
2.5%
CAS: 7704-34-9 sulphur, precipitated, sublimed or colloidal
EINECS: 231-722-6 Xi; R 38
2.5%
CAS: 1310-58-3 potassium hydroxide
EINECS: 215-181-3 C, Xn; R 22-35
2.5%
CAS: 14324-55-1 zinc bis(diethyldithiocarbamate)
EINECS: 238-270-9 Xn, Xi, N; R 22-36/37/38-43-50/53
2.5%
CAS: 102-06-7 1,3-diphenylguanidine
EINECS: 203-002-1 Repr. Cat. 3; Xn, Xi, N; R 22-36/37/38-62-51/53
2.5%
CAS: 149-30-4 benzothiazole-2-thiol
EINECS: 205-736-8 Xi, N; R 43-50/53
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.02.2010 Revision: 12.02.2010
Trade name: Suprotex?BNS
(Contd. of page 1)
?Additional information: For the wording of the listed risk phrases refer to section 16.
* 4 First aid measures
?General information:
Immediately remove any clothing soiled by the product.
Take affected persons out of danger area. Remove any clothig soiled by the product.
?After inhalation: Supply fresh air and to be sure call for a doctor.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact: Rinse opened eye for several minutes under running water.
?After swallowing:
Seek medical advice immediately show this material safety data sheet.
If swallowed, rinse mouth with water (only if the person is conscious).
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Special hazards caused by the substance, its products of combustion or resulting gases:
May be released in case of fire:
harmfulgases/vapours
?Protective equipment: Wear self-contained respiratory protective device.
?Additional information
Being an aqueous system, product itself does not burns. Fire extinguishing measures to be adopted to
ambient fire.
6 Accidental release measures
?Person-related safety precautions: Wear protective clothing.
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
7 Handling and storage
?Handling:
?Information for safe handling: No special precautions are necessary if used correctly.
?Information about fire - and explosion protection: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
?Information about storage in one common storage facility: Store away from foodstuffs.
?Further information about storage conditions:
Protect from frost.
+5 - +30癈
?Storage class: Storage classification (VCI-D): 12 Non-combustible liquids.
* 8 Exposure controls/personal protection
?Additional information about design of technical facilities:
In latex processing (e.g. in drying operations): Provide good ventilation or extraction.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.02.2010 Revision: 12.02.2010
Trade name: Suprotex?BNS
(Contd. of page 2)
?Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
?Personal protective equipment:
?General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
?Respiratory protection: Not required.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
?Material of gloves
Rubber gloves
(EN 374)
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
(EN 166)
?Body protection:
Protective work clothing
(EN 344)
9 Physical and chemical properties
?General Information
Fluid
Form:
Whitish
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: ~ 100癈
Not applicable.
?Flash point:
Product is not selfigniting.
?Self-igniting:
Product does not present an explosion hazard.
?Danger of explosion:
~ 1.3 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Fully miscible.
water:
10.5 - 11.5
?pH-value at 20癈:
?Viscosity:
2000 - 3000 mPas
Dynamic at 20癈:
?Solvent content:
0.0 %
Organic solvents:
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.02.2010 Revision: 12.02.2010
Trade name: Suprotex?BNS
(Contd. of page 3)
0.01 %
VOC (EC)
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
1314-13-2 zinc oxide
Oral LD50 15000 mg/kg (rat)
Inhalative 4h-LC50 > 5.7 mg/l (rat)
1310-58-3 potassium hydroxide
Oral LD50 273 mg/kg (rat)
14324-55-1 zinc bis(diethyldithiocarbamate)
Oral LD50 2450 mg/kg (rat)
Dermal LD50 >3160 mg/kg (rabbit)
149-30-4 benzothiazole-2-thiol
Oral LD50 100 mg/kg (rat)
Dermal LD50 >7940 mg/kg (rabbit)
?Primary irritant effect:
?on the skin: No data available.
?Sensitization: Sensitization possible through skin contact.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
?Sensitisation May cause sensitisation by skin contact.
12 Ecological information
?Ecotoxical effects:
?Acquatic toxicity:
1314-13-2 zinc oxide
72h-EC50 0.17 mg/l (green algae (Selenastrum capricornutum))
14324-55-1 zinc bis(diethyldithiocarbamate)
48h-EC50 0.24-0.44 mg/l (daphnia (daphnia magna))
96h-LC50 0.23 mg/l (fish (Oncorhynchus mykiss))
0.26 mg/l (fish (Pimephales promelas))
0.40 mg/l (fish (Lepomis macrochirus))
149-30-4 benzothiazole-2-thiol
96h-LC50 (static) 11 mg/l (fish (Pimephales promelas))
?General notes:
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.02.2010 Revision: 12.02.2010
Trade name: Suprotex?BNS
(Contd. of page 4)
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
?Recommended cleansing agents: Water, if necessary together with cleansing agents.
* 14 Transport information
?Land transport ADR/RID (cross-border)
9 Miscellaneous dangerous substances and articles.
?ADR/RID class:
?Danger code (Kemler): 90
3082
?UN-Number:
III
?Packaging group:
9
?Hazard label:
Symbol (fish and tree)
?Special marking:
?Description of goods: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc
oxide)
?Maritime transport IMDG:
9
?IMDG Class:
3082
?UN Number:
9
?Label
III
?Packaging group:
F-A,S-F
?EMS Number:
No
?Marine pollutant:
Symbol (fish and tree)
?Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc oxide)
?Air transport ICAO-TI and IATA-DGR:
9
?ICAO/IATA Class:
3082
?UN/ID Number:
9
?Label
Symbol (fish and tree)
?Special marking:
III
?Packaging group:
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 12.02.2010 Revision: 12.02.2010
Trade name: Suprotex?BNS
(Contd. of page 5)
?Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (zinc oxide)
* 15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
Xi Irritant
N Dangerous for the environment
?Hazard-determining components of labelling:
zinc bis(diethyldithiocarbamate)
?Risk phrases:
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
60 This material and its container must be disposed of as hazardous waste.
?National regulations:
?Breakdown regulations:
GERMAN ORDINANCE OF FAILURE
Annex I - No.: 9b
Threshold for operating range to ?1 sec. 1
- Record 1: 500000 kg
- Record 2: 2000000 kg
Scope: dangerous substances for the environment (risk phrases R 51/53).
?Classification according Safety of Operation Ordinance (german): -
* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
22 Harmful if swallowed.
35 Causes severe burns.
36/37/38 Irritating to eyes, respiratory system and skin.
38 Irritating to skin.
43 May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
62 Possible risk of impaired fertility.
?Department issuing MSDS: Quality / env. dept.
?Contact: Andreas Ehrle, email: ehrle@weserland.eu
?* Data compared to the previous version altered.
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