Emergency Telephone No.
(800) 424-9300 Chemtrec
PRO ~ Date: 08/04/2005 Page 1/6
@
Revision: W7 (08/04/2005)
C!:hemica10Dye/ MATERIAL SAFETY .c..mpany: PgBEQ1~Q~J.!?I!<}~~
DATA SHEET
PO Box 14. Somerset, MA 02726
508-676-3838
fax 508-676-3980
Clear Solvent Based Gutta
www.prochemical.com
I-IDENTIFICATION OFTHE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Identification of the substance or preparation:
Name: Gutta solvant incolore / solvent based gutta colourless.
Product code: 162000.
Company/undertaking idcntification:
Registcred company name: PEBEO INDUSTRIES.
-BP106
Address: 305 A VENUE DU PIC DE BERTAGNE -.13881.GEMENOS CEDEX.FRANCE.
Telephone: 33 (0) 4.42.32.08.08. Fax:33 (0) 4.42.32.01.70. Telex:.
contact@pebeo.com
www.pcbeo.col1l
Emergency telephone: 33 (0) 1.45.42.59.59.
Association/Organisation: INRS /ORFILA http://www.centres-antipoison.net.
Use of thc substance/preparation:
Silk dye
-COMPOSITIONIINFORMATION
2 ON INGREDIENTS
Full text of risk phrases appearing in section 2: see section 16.
Hazardous substances present on theil' own:
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100% pure
state)
cINDEX R: %
60 1-008-00-2 AND ISOMERS I I 38 SO/53 65 67 50 <= x % < 100
Other substances representing a hazard:
No known substance in this category present.
Substances prescnt at a conccntration below the minimum danger threshold:
No knO\\11 substance in this category present.
Other substances with occupational exposure limits:
No knO\\11 substance in this category present.
-IDENTIFICATION
3 OF HAZARDS
This product is classed: Highly flammable liquid.
Possibility of irritation to the skin.
Vapors may cause drowsiness and dizziness.
Very toxic to aquatic organisms. may cause long-term adverse effects in the aquatic environment.
Preparation classification:
Irritant.
1]"t
lIt] h~Wo=~' [if'hIO
o
R SO/53 VC1Ytoxic to aquatic organisms, may cause long-tenn adverse effects in the aquatic
environment.
R38 Irritating to skin.
RII Highly flammable.
R67 Vapours may cause drowsiness and dizziness.
Other data:
Packaging < 125 ml.
- Made::under licence of European l.abel Sy~tenI'J{JMSOS software from Int()Oync a http://w\llw.infodyne.fr-
-2001/5S/EC
SAFETY DATA SHEET (91/155/EEC -ISO 11014-1) Date: OS/0412005 Page 2/6
Version: WI (OS/04/2005) Revision: W7 (OS/04/2005)
-
Name: Gutta solvant incolore / solvent based gutta colourless 162000 Company: PEBEO INDUSTRIES
-FIRST
4 AID MEASURES
As ~ageneral rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing in an unconscious person.
In the event of exposure by inhalation:
Ifa large quantity is inhaled, move the patient into the lTesh air and keep him/her wann and still.
In the event of splashes or contact with eyes:
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
Refer the patient to an ophthalmologist. in particular if there is any redness, pain or visual impainnent.
In the eveut of splashes or contact with skin:
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
DO NOT use solvents or thinners.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred
to hospital
In the event of swallowing:
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a
doctor.
Keep still. DO NOT induce vomiting.
Call a doctor immediately and show him the label.
5 - FIRE-FIGHTING MEASURES
Chemical powders, carbon dioxide and other extinguishing gas are suitable for small fires.
Suitable extinguishing media:
Carbon dioxide, chemical powders, foams, and other extinguishing gases.
In the event of fire, use specifically suitable extinguishing agents. Never use water.
Extinguishing media which must not be used for safety reasons:
Water is not generally recommended since it can be ineffective; however, it can be used successfully to cool containers
exposed to the fire and to disperse fumes.
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
Prevent the effluent of fire-fighting measures 1T0m entering drains or watenvays.
Special protective equipment for fire-fighters:
Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.
-ACCIDENTAL
6 RELEASE MEASURES
Personal precautions:
On account of the organic solvents contained in the preparation, eliminate sources of ignition and ventilate the premises.
A void inhaling the vapors.
A void any contact with the skin and eyes.
Consult the safety measures listed wIder headings 7 and S.
Environmental p.'ecautions:
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatom earth
in drums for waste disposal.
Prevent any materiallTom entering drains or watenvays.
Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
If the product contaminates waterways, rivers or drains, alen the relevant authorities in accordance with statutory procedures
Methods for cleaning up:
Clean preferably with a detergent, do not use solvents.
7 - HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled.
. Mad~underJic-c:nce
~)fEuropc<1n
LabelS)'stcm.Jj:
MSDSsojtw3r~from InfoDync-http://w\\\ infodync.fr.
-2001/58/EC
SAFETY DATA SHEET (91/155/EEC -ISO 11014-1) Date: 08/04/2005 Page 316
Version: WI (08/04/2005) Revision: W7 (08/04/2005)
-
Name: Gutta solvant incolore 1 solvent based gutta colourless 162000 Company: PEBEO INDUSTRIES
Handling:
Handle in well-ventilated areas.
The vapors are denser than air. They can spread along the ground and fonn explosive mixtures with air
Prevent the fonnation of flammable or explosive concentrations in air and avoid vapor concentrations higher than the
occupational exposure limits.
Fire prevention:
Prevent the accumulation of electrostatic charges with connections to earth
The preparation may become electrostatically charged; always place on the ground during transfer. Wear antistatic shoes and
clothes and make floors of conductive materials.
Use the product in premises where there are no naked flames or other sources of ignition and have protected electrical
equipment
Keep packages tightly closed and away ITom sources of heat, sparks and naked flanles.
Do not use tools which may produce sparks. Do not smoke.
Prevent access by unauthorised personnel.
Recommended equipment and procedures:
For personal safety, see ?.
Observe precautions stated on label and also industrial safety regulations
Packages which have been opened must be reclosed carefully and stored in an upright position
A void inhaling vapors.
A void contact ofproduct with the skin and eyes
Prohibited equipment and procedures:
Smoking, eating and drinking are prohibited in premises where the preparation is nsed
Never open the packages under pressure
Storage:
Keep the container tightly closed in a dry, well-ventilated place
-do not smoke.
Keep away ITom all sources of ignition
Keep well away ITom all sources of ignition, heat and direct sunlight
The floor must be impemleable and fonn a collecting basin so that, in the event of an accidental spillage, the liquid cannot
spread beyond this area.
8 - EXPOSURECONTROLS/PERSONALPROTECTION
08
Use personal protection equipment as per Directive 89!686/EEC.
Technical measures:
Ensure adequate ventilation, if possible with extractor fans at work posts and appropriate general extraction.
If this ventilation is insufficient to maintain the concentration of solvent vapors below the exposure limits, wear breathing
apparatus
Exposure limit values per INRS ND 2098-174-99 and ND 2114-176-99:
France VME-ppm: VME-mglm3: VLE-ppm: VLE-mg/m3: Notes: TMP N?
142-82-5 400 1600 - - - 84
Exposure limit values per 2000/39/EC and 98/24/EC:
Notes:
VLE-mglm3:
EC VME-ppm: VME-mglm3: VLE-ppm:
142-82-5 500 2085
Exposure limit values (2003):
Definition: Criterion:
STEL:
UKIOES TW A: Ceiling:
142-82-5 500 ppm
Respiratory protection:
Where workers encounter concentrations higher than the exposure limits, they must wear suitable, approved masks.
Hand protection:
Protective creams may be used for exposed skin, but they should not be applied after contact with the product.
- hnp:IIW\\o"w.infodyne.fr-
. Made und~r licence of European label SystenrJ() MSDS software (rom IntoDyne
-200 -
SAFETY DATA SHEET (911155/EEC 1/58/EC ISO 11014-1) Date: 08/0412005 Page 4/6
Version: WI (08/04/2005) Revision: W7 (08/04/2005)
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Name: Gutta solvant incolore / solvent based gutta colourless 162000 Company: PEBEO INDUSTRIES
Due to the solvents present, it is recommended that neoprene rubber or nitrile rubber gloves be worn
Eye and face protection:
A v~id contact with the skin and eyes. Wear safety goggles
Provide eye washes in workshops where the product is constantly handled
Skin protection:
For further intonnation, see ?II ofS.D.S. - Toxicological infonnation.
-PHYSICAL AND CHEMICAL
9 PROPERTIES
<1
Density:
not relevant.
Acidlbase character of preparation:
Insoluble.
Solubility of preparation in water:
Vapour tension at 50癈 of volatile constituents: Below 110kPa (1.10bar).
Physical state: viscous liquid
Flash point interval: Flash point: <= 21癈.
The pH is impossible to measure or its value is not relevant.
215癈.
Sel f-ignition temperature:
Decomposition temperature: not specified.
not relevant.
Melting temperature interval:
95癈.
A verage distillation temperature of solvents contained:
-4.00 dc.
Flash point:
10 - STABILITY AND REACTIVITY
When exposed to high temperatures, the preparation may release dangerous decomposition products such as carbon monoxide
and dioxide, smoke and nitrogen oxide
Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, l1tmaces etc.)
must not be allowed on the premises.
-TOXICOLOGICAL
II IN FORMA TlON
No data is available regarding the preparation itself.
Exposure to vapors ITom solvents contained in the preparation beyond the exposure limits stated may produce effects hannful
to health. such as:
Irritation of mucous membrane and respiratory system. kidneys, liver and central nervous system.
Symptoms produced wiII include headaches, numbness, dizziness, fatigue, muscular asthenia and, in extreme cases, loss of
consciousness.
Prolonged or repeated contact with the preparation may strip the skin of its natural oil and thus cause non-allergic dennatitis
on contact and absorption through the epidennis.
Splashes in the eyes may cause irritation and reversible damage
It is generally agreed that substances contained arc likely to cause significa.nt irritation which lasts for at least twenty tour
hours after application to the healtl1Y, lUlbroken skin of an animal for a period of up to 4 hours.
-ECOLOGICAL
12 INFORMATION
No ecological data on the product itselfis available.
'l11e product must not be allowed to run into drains or waterways.
Ecotoxicity:
Very toxic to aquatic organisms, may cause long-tenn adverse effects in the aquatic environment.
Other adverse effects:
Gennany: WGK 1 (VwVwS vom 17/05/99, KBws)
-DISPOSAL
13 CONSIDERATIONS
Do not pour into drains or waterways.
. Made under licence S}'stem')i, MSDS son"..are from InfoDync . hup:llwww.infod,yne.fr.
of European Label
-2001/58/EC
SAFETY DATA SHEET (91/155/EEC -ISO 11014-1) Date: 08/04/2005 Page 5/6
Version: WI (08/04/2005) Revision: W7 (08/04/2005)
-
Name: Gutta solvant incolore / solvent based ~utta colourless 162000 Com~: PEBEO INDUSTRIES
Waste:
Recycle or dispose of waste in compliance with current legislations, preferably via a certified collector or company.
Do,not contaminate the grOlUld or water with waste, do not dispose of waste into the environment.
Soiled packaging:
Empty recipient completely. Keep label(s) on recipient.
Give to a certified disposal contractor.
Codes of wastes (Decision 2001/573/EC, Directive 75/442/EEC, Directive 91/689/EEC on hazardous waste):
08 0 I 11 * waste paint and varnish containing organic solvents or other dangerous substances
- TR<\.NSPORT INFORMATION
14
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IA TA for air
transport
UNI263=PAINT tincluding painllacquer, enan1el. stain, shellac. varnish, polish. liquid filler and liquid lacquer base) or
PAINT RELATED MATERIAL (including paint thinning and reducing compound)
Proviso
ADRIRID Class Code Pack gr. Label Ident. LQ
l63-640H
3 FI III 3 33 LQ7
IMDG Class 2?Label Pack gr. LQ EMS Provis.
3 - 111 5L F-E,S-E 163 223 944 955
lATA note
Class 2癓abel Pack gr. Passager Passager Cargo Cargo
-
3 J!I 309 60 L 310 220 L A3, A72
-
3 III Y309 10L
-STATUTORY
15 INFORMATION
This preparation was classified in compliance with the directive known as 1999/45/EC and its adaptations
In addition directive 2004173/EC with the 29?adaptation of directive 67/548/EEC (Hazardous substances) have been taken
into account.
Packaging < 125 mt.
Preparation classification:
Irritant.
lXJ [iTbI'
Contains:
601-008-00-2 HEPTANE [AND ISOMERS]
Particular hazards associated with the preparation and safety recommendations:
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R38 Irritating to skin.
Rll Highly flammable.
R67 Vapours may cause drowsiness and dizziness.
S2 Keep out of reach of children.
S29 Do not empty into drains.
S 46 If swallowed, seek medical advice immediately andshow this container or label.
S 61 A void release to the environment. Refer to special instructions/Safety data sheets.
-no smoking.
S 16 Keep away from sources of ignition
S 37 Wear suitable gloves.
S 51 Use only in well ventilated areas.
S64 If swallowed. rinse mouth with water (only if the person is conscious)
S9 Keep container in a well-ventilated place.
Particular provisions:
Tactile warning of danger.
Germany: WGK I (VwVwS vom 17/05/99, KBws)
- hnp:IIW\\ow.infodyne.fr-
. J\tade under licence of European label SystemY,. MSDS :o>oftware from InfoDyne
-200l/58/EC
SAFETY DATA SHEET (91/155/EEC -1S0 11014-1) Date: 08/04/2005 Page 6/6
Version: WI (08/04/2005) Revision: W7 (08/0412005)
-
Name: Gutta solvant incolore / solvent based gutta colourless 162000 Company: PEBEO INDUSTRIES
-OTHER
16 INFORMA nON
Since the user's working conditions arc not known by us, the information supplied on this safety data sheet is based on ollr
current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining written
handling instmctions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local
regulations.
The infonl1ation given on this safety data sheet must be regarded as a description of the safety requirements relating to our
product and not a guarantee 0 f its properties
Full text of risk phrases appearing in section 2:
R II Highly flammable.
R 38 Irritating to skin.
R 50/53 Very toxic to aquatic organisms, may cause long-tenn adverse effects in the aquatic
enviromnent.
R65 Harmful. may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
. under licence of European Label System'i; MSDS soft\\
Made
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