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811-97-2 1330-78-5 85-68-7

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                                         MATERIAL SAFETY DATA SHEET
Trade Name: Johnsen's R-134a Oil Charge For Retrofit
MSDS NO. 6535
Revision Date: 01/26/2009
Date Printed 01/26/2009
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Johnsen's R-134a Oil Charge For Retrofit
Chemical Family: Refrigerant gas/lubricant
Synonyms: None
Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300

Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033


2. COMPOSITION/INFORMATION ON INGREDIENTS
Weight % OSHA TWA OSHA STEL OSHA SKIN
Component
50 - 80 Not Listed Not Listed Not Listed
1,1,1,2-Tetrafluoroethane
811-97-2
<1 Not Listed Not Listed Not Listed
Tricresyl phosphate
1330-78-5
<1 Not Listed Not Listed Not Listed
Butyl Benzyl Phthalate
85-68-7


Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling
Component
50 - 80 Not Listed Not Listed Not Listed
1,1,1,2-Tetrafluoroethane
811-97-2
<1 Not Listed Not Listed Not Listed
Tricresyl phosphate
1330-78-5
<1 Not Listed Not Listed Not Listed
Butyl Benzyl Phthalate
85-68-7


ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling
Component
Not Listed Not Listed Not Listed
1,1,1,2-Tetrafluoroethane
811-97-2
Not Listed Not Listed Not Listed
Tricresyl phosphate
1330-78-5
Not Listed Not Listed Not Listed
Butyl Benzyl Phthalate
85-68-7

Other: Contains no other ingredients in concentrations >.1% that are now known to be hazardous as defined by OSHA.

3. HAZARDS IDENTIFICATION
Emergency Overview: Content under pressure. "Frostbite-like" effects may occur if the liquid or escaping vapors contact the eyes
or skin. Gross inhalation overexposure may cause: Central nervous system depression with dizziness,
confusion, incoordination, drowsiness or unconsciousness or death.

HMIS Classification: Health: 1 Flammability: 1 Physical Hazard: 2
NFPA Rating: Health: 2 Flammability: 1 Reactivity: 1


4. FIRST AID MEASURES
Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention immediately after flushing.
Ingestion: DO NOT INDUCE VOMITING. Give nothing by mouth. Get medical attention! If vomiting occurs, keep
head lower than hips to prevent aspiration.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult give oxygen. Get medical attention.

Page 1 of 1
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsen's R-134a Oil Charge For Retrofit
MSDS NO. 6535
Revision Date: 01/26/2009
Date Printed 01/26/2009
4. FIRST AID MEASURES
Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get
medical attention. Remove contaminated clothing and shoes, and launder before reuse. Use approved
skin lotions or creams to replace lost skin oils. Treat for frostbite if necessary by gently warming affected
area.


5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point 癋(癈): >300 F.
Flash Point Method: COC
Flammable Limits in Air - Lower (%): NT
Flammable Limits in Air - Upper (%): Not Determined
Autoignition Temperature 癋(癈): Not Determined
Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical. Use water spray to keep containers cool that are exposed
to heat or flames.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Warning!! Contents under pressure. Container may rupture under fire conditions. Decomposition may
occur. Wear approved positive-pressure self-contained breathing apparatus and protective clothing.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide.
Aerosol Comments: NFPA Level 1 Aerosol


6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact.
Spill Procedures: Wear protective equipment specified. Contain any liquid from leaking containers. Ventilate spill area. Soak
up material with absorbent and place in chemical waste container.
Action to be taken if material is released Increase area ventilation. Do not puncture or incinerate container. Contents under pressure.
or spilled:
Environmental Precautions: Keep away from drains.


7. HANDLING AND STORAGE
Handling and Storage: CAUTION: COMPRESSED GAS. Do not puncutre, incinerate or store above 120 F. Do not store in
passenger compartment of automobile. Avoid breathing vapors, if exposed to high vapor concentration,
leave area at once. Avoid contact with skin and eyes. Should not be mixed with air for leak testing or used
for any other purpose above atmospheric pressure.


8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Showers.
Eyewash stations.
Eyes: Wear safety glasses or goggles to protect against exposure.
Skin Protection: Avoid skin contact. Wear protective clothing and gloves.
Respiratory Protection: Use in a well ventilated area.



9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Colorless gas with clear to yellow liquid.
Odor: MILD ETHER LIKE
pH Value: Not Determined
Vapor Pressure: Not Determined
Vapor Density (Air=1): Not Determined
Boiling Point (癋): -15.7 F. (Lowest Component)
Melting/Freezing Point: Not determined.
Solubility in Water: NEGLIGIBLE
Bulk Density at 20癈: Not Determined
Molecular Weight: Mixture
Specific Gravity (H20=1): Not determined.
Viscosity: Not determined.

Page 2 of 2
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsen's R-134a Oil Charge For Retrofit
MSDS NO. 6535
Revision Date: 01/26/2009
Date Printed 01/26/2009
9. PHYSICAL AND CHEMICAL PROPERTIES
Evaporation Rate: >1
VOC Content(%): Not determined.
Decomposition Temperature: Not Known


10. STABILITY AND REACTIVITY
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Do not expose to heat or store at temperatures above 120 F.
Materials to Avoid: Avoid contact with acidic, basic or oxidizing agents. Avoid contact with alkali or alkaline earth metals.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. This material can be decomposed by high temperatures forming
hydrofluoric acid and possibly carbonyl fluoride.
Hazardous Polymerization: WILL NOT OCCUR


11. TOXICOLOGICAL INFORMATION
Toxicological Data:

Component
Route Species Dose
3
Inhalation Rats LC50 1500 gm/m /4H
1,1,1,2-Tetrafluoroethane
811-97-2
Oral Rats LD500 3 gm/kg
Tricresyl phosphate
1330-78-5
Oral Rats LD50 2330 mg/kg
Butyl Benzyl Phthalate
85-68-7

Carcinogenicity:

Component
IARC NTP OSHA
Not Listed Not Listed Not Listed
1,1,1,2-Tetrafluoroethane
811-97-2
Not Listed Not Listed Not Listed
Tricresyl phosphate
1330-78-5
Group 3 (not classifiable) Not Listed Not Listed
Butyl Benzyl Phthalate
85-68-7

12. ECOLOGICAL INFORMATION
Remarks: Ecological testing has not been conducted on this product.


13. DISPOSAL CONSIDERATION
Waste Classification: Not determined.
Waste Management: Not determined.
Disposal Method: Disposal should be made in accordance with federal, state and local regulations.


14. TRANSPORTATION INFORMATION
U.S. DOT:
Proper Shipping Name: 1,1,1,2-Tetrafluoroethane
Hazard Class: 2.2
UN/NA Number: UN 3159
DOT Packing Group: NA

IMDG:
Proper Shipping Name: 1,1,1,2-Tetrafluoroethane
Hazard Class: 2.2
Hazard Subclass: Not determined.
UN No.: UN 3159
Page 3 of 3
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsen's R-134a Oil Charge For Retrofit
MSDS NO. 6535
Revision Date: 01/26/2009
Date Printed 01/26/2009
14. TRANSPORTATION INFORMATION
Packing Group: NA
Marine Pollutant: No


15. REGULATORY INFORMATION
US Federal Regulations:

SARA 313 SARA 302 TPQ RQ
Component
Not Listed Not Listed Not Listed Not Listed
1,1,1,2-Tetrafluoroethane
811-97-2
Not Listed Not Listed Not Listed Not Listed
Tricresyl phosphate
1330-78-5
Not Listed Not Listed Not Listed Not Listed
Butyl Benzyl Phthalate
85-68-7

SARA 311/312 Hazard Catagories: Not Determined.

State Regulations:

California Prop. 65 California - Prop 65 California Prop. 65 California Prop. 65
Component
Cancer list Developmental Toxicity Reproductive Female Reproductive Male
Not Listed Not Listed Not Listed Not Listed
1,1,1,2-Tetrafluoroethane
811-97-2
Not Listed Not Listed Not Listed Not Listed
Tricresyl phosphate
1330-78-5
Not Listed Listed: December 2, 2005 Not Listed Not Listed
Butyl Benzyl Phthalate
Developmental toxin.
85-68-7


New Jersey Right-to-Know List:
Component
Substance no. 3130
Tricresyl phosphate
1330-78-5
Substance no. 2896
Butyl Benzyl Phthalate
Substance no. 3005
85-68-7

U.S. TSCA: The components of this product are listed on the TSCA Inventory.
Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory.
Consumer Product Safety Improvement Act of 2008 General Conformity Certification

The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in
compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and
enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant
Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced
by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols.
No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product
container.

16. OTHER INFORMATION
General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.




Page 4 of 4
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsen's R-134a Oil Charge For Retrofit
MSDS NO. 6535
Revision Date: 01/26/2009
Date Printed 01/26/2009
16. OTHER INFORMATION
Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable.
However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness
NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual
conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results
obtained or for incidental or consequential damages, including lost profits, arising from the use of these
data. No warranty against infringement of any patent, copyright or trademark is made or implied.





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