Ciba Specialty Chemicals Corporation
P. O. Box 2444
High Point, NC 27261-2444
24-Hour Health/Environmental Emergency Phone: 1-800-873-1138
Material Safety Data Sheet
LODYNE S-152B
Value beyond chemistry
MSDS No: 37 Date Printed: 07/17/02 Effective Date: 4/30/02
Health 2
1. PRODUCT IDENTIFICATION 2
Flammability 2
2 0
Reactivity 0
Chemical Family: Surfactant
Protective Equipment J
Intended Use: Fluoroalkyl Sodium Sulfate
HMIS RATING
NFPA RATING
Product Name(s): Product Code:
LODYNE S-152B (Export Tote 800kg) 1185272FM
LODYNE S-152B DRUM 1185272VV
LODYNE S-152B EXPORT TOTE 1185272W0
LODYNE S-152B TOTE 1185272VX
2. COMPOSITION / INFORMATION ON INGREDIENTS
ACGIH/PPM OSHA/PPM
CAS No. Common Name: TWA STEL PEL % by Wt.
Confidential Fluorochemical anionic surfactant None None None 5-9
Dermal: Not evaluated
Inhalation: Not evaluated
Ingestion: Not evaluated
70969-47-0 Perfluoro telomer None None None 3-7
Dermal: Not evaluated
Inhalation: Not evaluated
Ingestion: Not evaluated
107-41-5 Hexylene glycol None 25 None 3.5
Dermal: (Rabbit) LD50 > 10,000 mg/kg
Inhalation: (Rat) ALC (saturated vapor) >
18,000 ppm (8 hr)
Ingestion: (Rat) LD50 = 4,470 mg/kg
Confidential Fluorochemical cationic surfactant None None None 1-5
Dermal: Not evaluated
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
Inhalation: Not evaluated
Ingestion: Not evaluated
75-65-0 Tert-butyl alcohol 100 None 100 2
Dermal: Not evaluated
Inhalation: Not evaluated
Ingestion: (Rat) LD50 = 3,500 mg/kg
3. HAZARDS IDENTIFICATION
Route(s) of Entry: Dermal and inhalation.
Potential Health Effects: May cause eye, skin, and respiratory irritation. Overexposure may result in anesthesia.
Carcinogenicity (NTP): Not listed.
Carcinogenicity (IARC): Not listed.
Carcinogenicity (OSHA): Not listed.
4. FIRST AID MEASURES
Ingestion: If conscious, give plenty of water to drink. Get medical attention. If unconscious, do not give anything to drink. Get
immediate medical attention.
Skin: Wash with mild soap and water. If irritation occurs, get medical attention. If clothing is contaminated, remove and wash
before reuse.
Inhalation: Remove to fresh air. Get medical attention.
Eyes: Flush eyes with water for at least 15 minutes. Get medical attention.
5. FIRE FIGHTING MEASURES
116癋 (47 癈)
Flash Point:
PMCC
Flash Point Method Used:
Not evaluated
Flammable Limits in Air (Lower - % by volume):
Not evaluated
Flammable Limits in Air (Upper - % by volume):
Not evaluated
Auto-Ignition Temperature:
TDG Classification in Sect. 14
TDG Flammability Class (Canada):
General Hazards: Combustible.
Fire Fighting Equipment: Use self contained breathing apparatus
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire and Explosion Hazards: No unusual hazards.
Hazardous Combustion Products: Thermal decomposition may produce oxides of sulfur, carbon and fluorine. Hydrofluoric acid
might be produced.
Explosive Data-Sensitivity to Mechanical Impact: Not evaluated.
Explosive Data-Static Discharge: Not evaluated.
Emergency Response Guidebook Information: None
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Absorb onto sand or other absorbent material. Shovel into closable container for disposal. Wear
protective equipment specified (Section 8). Do not use water, as large volumes of foam develop and slippery conditions may
result.
7. HANDLING AND STORAGE
WARNING! Combustible. Eye, skin, and respiratory irritant. Keep away from heat, sparks, and open flame. Avoid contact with
eyes, skin, and clothing. Avoid breathing dust, vapor, mist or gas. Keep container closed. Use with adequate ventilation. For
industrial use only. Keep from freezing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal Protective Equipment: Wear appropriate equipment to prevent probability of exposure and personal contact. Deluge
safety shower and eye wash should be located near work area.
Eye Protection: Wear splash-proof chemical goggles.
Skin Protection: Wear impervious gloves as a standard handling procedure.
Respiratory Protection: Self contained breathing apparatus for concentrations above TLV limits.
Engineering Controls: Local exhaust recommended, mechanical exhaust acceptable.
Emergency Response Protection: No additional specialized equipment should be required.
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Physical Form:
Light yellow
Color:
Not evaluated
Odor Threshold:
Not evaluated
Solubility in Water:
Not evaluated
Vapor Pressure:
1.12 (H20 = 1)
Specific Gravity:
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
> 83癈 (> 181 癋)
Boiling Point:
Not evaluated
Melting Point:
Not evaluated
Freezing Point:
Not evaluated
Decomposition Temperature:
Not evaluated
Evaporation Rate:
Not evaluated
Bulk Density:
Not evaluated
Vapor Density:
Not evaluated
pH:
Not evaluated
Coefficient of water/oil:
Volatile(s): 55%
10. STABILITY AND REACTIVITY
Stability: Stable
Incompatibility: None known.
Hazardous Decomposition Products: Burning may produce oxides of carbon, nitrogen, sulfur and fluorine. Hydrofluoric acid
may also be produced.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Eye Irritation: Not evaluated.
Skin Irritation: Not evaluated.
Inhalation Toxicity: Not evaluated.
Sensitization: Not evaluated.
Chronic/Carcinogenicity: Not evaluated.
Teratology: Not evaluated.
Reproduction: Not evaluated.
Mutagenicity: Not evaluated.
Acute Oral Effects: Not evaluated.
Acute Dermal Toxicity: Not evaluated.
Additional Information: None
12. ECOLOGICAL INFORMATION
Printed: 7/17/02 Page 4 of 9
Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
Biodegradability: Not evaluated
Ecotoxicity: (Fathead minnow) LC50 = 683 mg/l (96 HR)
Daphnia Toxicity: EC50 = 105 mg/l (48 HR) (Daphnia Magna)
Biological Oxygen Demand (BOD5): 53 mg O2/g
Chemical Oxygen Demand (COD): 669 mg O2/g
Activated Sludge Respiration Inhibition Test: EC50 > 1,000 mg/l
Additional Information: None
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method: Landfill in a site approved for the disposal of chemical and hazardous wastes. Do not incinerate.
Follow all federal, provincial, and local regulations.
Container Disposal Information: Emptied container may contain product residue and should not be reused.
RCRA Hazard Class: Refer to Section 15: Regulatory Information for RCRA status.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Not Regulated
Proper Shipping Name:
IATA:
Alcohols, n.o.s.
Proper Shipping Name:
(Contains butanol)
Technical Shipping Name (If n.o.s.):
3
Hazard Class:
UN 1987
ID Number:
PG III
Packing Group:
IMDG:
Alcohols, n.o.s.
Proper Shipping Name:
(Contains butanol)
Technical Shipping Name (If n.o.s.):
3.3
Hazard Class:
UN 1987
ID Number:
PG III
Packing Group:
TDG:
Alcohols, n.o.s.
Proper Shipping Name:
(Contains butanol)
Technical Shipping Name (If n.o.s.):
3
Hazard Class:
UN 1987
ID Number:
PG III
Packing Group:
DOT: Bulk
Alcohols, n.o.s.
Proper Shipping Name:
(Contains butanol)
Technical Shipping Name (If n.o.s.):
3
Hazard Class:
UN 1987
ID Number:
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
PG III
Packing Group:
Department of Transportation: Not regulated under Section 173.150 (f) (2) when classed as a combustible liquid in non-bulk
packaging shipped by motor freight or rail. This exception does not apply for shipments by air or marine vessel.
Additional Information: None
15. REGULATORY INFORMATION
US Federal Regulations:
Chemical Weapons Convention (CWC): This product does not contain any chemicals listed under the Chemical Weapons
Convention Schedule of Chemicals.
Clean Air Act -Hazardous Air Pollutants (HAP): This product does not contain any hazardous air pollutants (HAP), as defined
by the U.S. Clean Air Act Section 12 (40 CFR 61).
Clean Air Act - Ozone Depleting Substances (ODS): This product neither contains, nor was manufactured with, a Class I or
Class II ozone depleting substance (ODS), as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App. A+B).
Clean Water Act - Priority Pollutants (PP): This product does not contain any priority pollutants listed under the U.S. Clean
Water Act Section 307 (2)(1) Priority Pollutant List (40 CFR 401.15).
FDA: Food Packaging Status
Occupational Safety and Health Act (OSHA): This product is considered to be a hazardous chemical under the OSHA Hazard
Communication Standard (29 CFR 1910.1200). D001, Ignitable
Resource Conservation and Recovery Act (RCRA): This product is not considered to be hazardous waste under RCRA (40
CFR 261).
SARA Title III: Section 302 - Extremely Hazardous Substances (EHS): This product does not contain any chemicals regulated
under Section 302 (40 CFR 355) as extremely hazardous substances.
SARA Title III: Section 304 - CERCLA: This product does not contain any chemicals regulated under Section 304 (40 CFR
302) as hazardous chemicals for emergency release notification ("CERCLA" List).
SARA Title III: Section 311/312 - Hazard Communication Standard (HCS): Immediate / Flammable
SARA Title III: Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under section 313 (40 CFR 372). This information must be included in all MSDS's copied or
distributed for this material.
Chemical Name: 2-Propanol, 2-methyl-
Common Name: Tert-butyl alcohol
CASRN: 75-65-0
Percent in Composition: 2 % by wt
Comment:
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
TSCA Section 5(e) - Consent Order / SNUR: This product is not subject to a Section 5(e) Consent Order or Significant New
Use Rule (SNUR).
TSCA Section 8(b) - Inventory Status: All chemical(s) comprising this product are either exempt or listed on the TSCA
inventory.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
International Regulations:
Canadian Inventory Status: All components are listed on the Canadian DSL or notified in accordance with CEPA regulations.
Canadian WHMIS: This product contains the following chemicals listed on the Canadian WHMIS Ingredient Disclosure List.
Chemical Name: 2,4-Pentanediol, 2-methyl-
Common Name: Hexylene glycol
CASRN: 107-41-5
Percent in Composition: 3.5 % by wt
Chemical Name: Poly(oxy-1,2-ethanediyl), .alpha.-[(1,1,3,3-tetramethylbutyl)phenyl]-.omega.-hydroxy-
Common Name: Nonionic surfactant
CASRN: 9036-19-5
Percent in Composition: 0 - 4 % by wt
Chemical Name: 2-Propanol, 2-methyl-
Common Name: Tert-butyl alcohol
CASRN: 75-65-0
Percent in Composition: 2 % by wt
Controlled product, Class B, D2B
State Regulations:
California Proposition 65: This product does not contain any chemicals currently on the California list of Known Carcinogens
and Reproductive Toxins.
Massachusetts Right-to-Know: The following is required composition information:
Chemical Name: 2,4-Pentanediol, 2-methyl-
Common Name: Hexylene glycol
CASRN: 107-41-5
Percent in Composition: 3.5 % by wt
Chemical Name: 2-Propanol, 2-methyl-
Common Name: Tert-butyl alcohol
CASRN: 75-65-0
Percent in Composition: 2 % by wt
New Jersey Right-to-Know: The following is required composition information:
Chemical Name: 2,4-Pentanediol, 2-methyl-
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
Common Name: Hexylene glycol
CASRN: 107-41-5
Chemical Name: 2-Propanol, 2-methyl-
Common Name: Tert-butyl alcohol
CASRN: 75-65-0
Chemical Name: Water
Common Name: Water
CASRN: 7732-18-5
Chemical Name: .beta.-Alanine, N-(2-carboxyethyl)-N-dodecyl-, disodium salt
Common Name: Anionic surfactant
CASRN: 3655-00-3
Chemical Name: Fluorochemical anionic surfactant
NJ Registry #: 29943300001-6626P
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: Water
Common Name: Water
CASRN: 7732-18-5
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: .beta.-Alanine, N-(2-carboxyethyl)-N-dodecyl-, disodium salt
Common Name: Anionic surfactant
CASRN: 3655-00-3
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Fluorochemical anionic surfactant
CASRN: Confidential
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Thiols, C8-20, .gamma.-.omega.-perfluoro, telomers with acrylamide
Common Name: Perfluoro telomer
CASRN: 70969-47-0
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2,4-Pentanediol, 2-methyl-
Common Name: Hexylene glycol
CASRN: 107-41-5
Comment: Hazardous Substance
Chemical Name: Fluorochemical cationic surfactant
CASRN: Confidential
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Acetic acid, sodium salt
Common Name: Sodium acetate
CASRN: 127-09-3
Comment: Not on Pennsylvania Hazardous Substance List
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Effective Date: 4/30/02 LODYNE S-152B Ciba Specialty Chemicals Corporation
Chemical Name: 2-Propanol, 2-methyl-
Common Name: Tert-butyl alcohol
CASRN: 75-65-0
Comment: Environmental Hazardous Substance
16. OTHER INFORMATION
37
MSDS No:
Deleted Package Size
Reason Issued:
Frances E. Knight
Approved By:
Manager, Product Registration
Title:
04/30/02
Approved Date:
03/08/01
Supersedes Date:
Revision Summary: Changes in Section(s): 1
Disclaimer: For further information, please contact: Phone: (336) 801-2373
Product Stewardship Team: Fax: (336) 801-2056
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or
warranty of any kind expressed or implied is made with respect to the information contained herein. This material safety data
sheet was prepared to comply with the OSHA Hazard Communication standard (29 CFR 1910.1200) and with the Workplace
Hazardous Materials Information System (WHMIS).
This supersedes any previous information.
Printed: 7/17/02 Page 9 of 9
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