PRO CHEM, INC. MATERIAL SAFETY DATA SHEET HEALTH 2
1475 BLUEGRASS LAKES PKWY.
CLEAN DIESEL / 2278
ALPHARETTA, GA 30004 FIRE 2
EMERGENCY/INFO # (800) 241-8180
DECEMBER 2009 REACTIVITY 0
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
PAGE 1 P.P.E. C
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
SECTION 1 ?Chemical and Company Identification SECTION 5 ?Fire Fighting Measures
FLASH POINT AND METHOD USED: n/ap
Abbreviations used on this Material Safety Data Sheet:
FLAMMABILITY: No
n/av. = not available n/ap. = not applicable ppm = parts per million TLV= Threshold Limit Value
PRODUCT USE: Fuel additive AUTOIGNITION TEMPERATURE: n/av
UPPER FLAMMABILITY LIMIT: n/ap LOWER FLAMMABILITY LIMIT: (% by volume) n/ap
SECTION 2 ?Composition on Ingredients METHOD OF EXTINCTION: Use means applicable to surrounding fire, such as carbon dioxide, dry chemical
powder, foam, or water spray.
LETHAL DOSE (50%) LETHAL
SPECIAL PROCEDURES: Fire fighters must wear self contained breathing apparatus and full protective
OF INGREDIENT CONCENTRATION (50%)
gear. Extreme heat may result in release of toxic gases.
(SPECIFY SPECIES AND
CAS# OF INGREDIENT (SPECIFY
HAZARDOUS INGREDIENTS CONCENTRATION ROUTE) HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon, nitrogen, and sulfur.
SPECIES AND ROUTE)
Disodium ethylenebis 15 142-59-6 n/av n/av EXPLOSION DATA: SENSITIVITY TO IMPACT: Not sensitive to impact.
(dithiocarbamate) (Nabam) SENSITIVITY TO STATIC DISCHARGE: Not sensitive to static charge.
Sodium 15 128-04-1 n/av n/av
SECTION 6 ?Accidental Release Measures
dimethyldithiocarbamate
Ethylene thiourea <1 96-45-7 n/av n/av
LEAK AND SPILL PROCEDURE: Soak up spills with absorbent material and scoop into drums. The floor
Ethylenediamine <0.75 107-15-3 n/av n/av
may be slippery. Use caution to avoid falls. Follow all local, state, and federal regulations for disposal. Do not
Dimethylamine <0.75 124-40-3 n/av n/av
contaminate water by cleaning of equipment or disposal of wastes. Do not discharge effluent containing this
product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the
SECTION 3 ?Hazards Information requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting
authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to
ROUTES OF ENTRY: Skin contact, skin absorption, eye contact, inhalation, ingestion
sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact
EFFECTS OF ACUTE EXPOSURE TO PRODUCT: Causes eye and skin irritation. Vapors may be irritating
your State Water Board or Regional Office of the EPA. Consult local and state regulations for additional
to the nose, throat and respiratory tract. Symptoms of overexposure can include headache, drowsiness,
waste disposal requirements.
dizziness, nausea, loss of coordination, and fatigue. Toxic - may be harmful if swallowed.
EFFECTS OF CHRONIC EXPOSURE TO PRODUCT: Prolonged or repeated skin contact can cause
SECTION 7 ?Handling and Storage
dermatitis. Sensitized persons may experience dermatitis after single exposure. Prolonged or repeated
inhalation may cause headaches, irritability, and depression. Sensitized persons may experience symptoms HANDLING PROCEDURES AND EQUIPMENT: Read and follow all label directions carefully. Wear
or cold, flu, mild hay fever or bronchial asthma. appropriate personal protective equipment. Follow normal hygienic practices for handling chemicals. It is a
IRRITANCY OF PRODUCT: Eye, skin and respiratory tract. violation of Federal Law to use this product in a manner inconsistent with its labeling.
SENSITIZATION TO PRODUCT: May cause skin sensitization reactions in some people. STORAGE REQUIREMENTS: Store in a cool, dry place away from all incompatible materials. Keep
CARCINOGENICITY: Ethylene thiourea has been identified as a carcinogen by NTP and IARC and is known container tightly closed when not in use. Keep away from children.
to the State of California to cause cancer.
SECTION 8 ?Exposure Controls/Personal Protection
TERATOGENICITY: Ethylene thiourea has caused birth defects in laboratory animals.
REPRODUCTIVE TOXICITY: Ethylene thiourea, carbon disulfide, disodium ethylenebis dithiocarbamate, PERSONAL PROTECTIVE EQUIPMENT:
and sodium dimethyldithiocarbamate are known to the State of California to cause birth defects or other GLOVES (SPECIFY): Chemical resistant. Rubber is recommended.
reproductive harm. RESPIRATOR (SPECIFY): None required where adequate ventilation exists. If airborne concentration is
MUTAGENICITY: Not identified. high, use NIOSH-approved Supplied Air Respirator (SAR) or Self Contained Breathing Apparatus (SCBA).
SYNERGISTIC PRODUCTS: None identified. EYE (SPECIFY): Use safety glasses with side shields. For splash protection use chemical goggles and face
shield.
FOOTWEAR (SPECIFY): Impervious boots.
SECTION 4 ?First Aid Measures
CLOTHING (SPECIFY): Chemical resistant apron or coveralls.
SKIN CONTACT: Remove contaminated clothing. Wash thoroughly with soap and water for 15 minutes.
ENGINEERING CONTROLS (SPECIFY VENTILATION. ENCLOSED PROCESS): Use of combination of
Launder clothing before reuse. Seek medical attention if irritation occurs.
local exhaust and dilution ventilation to keep exposure as low as possible.
EYE CONTACT: Flush eyes with running water for 15 minutes while retracting eyelids. If irritation or adverse
symptoms develop, seek medical attention. SECTION 9 ?Physical and Chemical Properties
INGESTION: If swallowed, dilute by drinking large amounts of water. Do not induce vomiting. Call a physician
PHYSICAL STATE: Liquid SPECIFIC GRAVITY: 1.176@20癈
immediately.
VAPOR PRESSURE: n/av VAPOR DENSITY: <1
INHALATION: Remove victim to fresh air. Use artificial respiration if victim has stopped breathing. Seek
COEFFICIENT OF MATERIAL DISTRIBUTION: Totally soluble in water
immediate medical attention.
EVAPORATION RATE: Approx. 1 ODOR THESHOLD: n/av
BOILING POINT: >100癈 FREEZING POINT: 0癈
APPEARANCE & ODOR: Yellow-green solution with sulfur odor pH: 10.5-12.4
THIS INFORMATION MUST BE ON ALL MSDS'S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
PRO CHEM, INC. MATERIAL SAFETY DATA SHEET HEALTH 2
1475 BLUEGRASS LAKES PKWY.
CLEAN DIESEL / 2278
ALPHARETTA, GA 30004 FIRE 2
EMERGENCY/INFO # (800) 241-8180
DECEMBER 2009 REACTIVITY 0
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
PAGE 2 P.P.E. C
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
SECTION 10 ?Stability and Reactivity
CHEMICAL STABILITY: Yes. Normally stable to moderate heat, sunlight, and air.
FLAMMABILITY: Acidification can release flammable gases. Thermal decomposition may release gases
such as amines and carbon disulfide.
INCOMPATIBILITY WITH OTHER SURFACES: Yes. Avoid contact with mineral acids such as nitric,
sulfuric, or hydrochloric acid.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon, nitrogen and sulfur. Amines. Carbon
disulfide.
SECTION 11 ?Toxicological Information
EXPOSURE LIMITS
ACGIH TLV-TWA=5 ppm for Dimethylamine.
ACGIH-TLV=10 ppm for ethylenediamine.
OSHA PEL 8-hr TWA =10ppm for ethylenediamine and dimethyl amine.
SECTION 12 ?Ecological Information
This pesticide is toxic to fish. See Section 3.
SECTION 13 ?Disposal Consideration
WASTE DISPOSAL METHODS: This pesticide is toxic to fish. Improper disposal of excess pesticide or
rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label
instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste
Representative at the nearest EPA Regional Office for guidance.
SECTION 14 ?Transport Information
SPECIAL SHIPPING INFORMATION: Consumer Commodity exemption may apply. See TDG Regulations.
TDG UN NUMBER: n/ap
SECTION 15 ?Regulatory Information
NFPA Hazard Rating: 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = None
WHMIS HAZARD: B-3,D-1B
SECTION 16 ?Other Information
This information was compiled from current manufacturer's MSDS's of the component parts of the product.
Disclaimer: The Manufacturer believes that the information contained in the Material Safety Data Sheet is accurate.
The suggested procedures are based on experience as of the date of publication. They are not necessarily all
inclusive nor fully adequate in every circumstance. Also, the suggestions should not be confused with, nor followed in
violation of applicable laws, regulations, rules or insurance requirements.
THIS INFORMATION MUST BE ON ALL MSDS'S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
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