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MSDS Material Safety Data Sheet
CAS

91-80-2 124-18-5

File Name: 91-80-2_124-18.asp

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DECANE
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SECTION 1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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MSDS Name:
DECANE

Synonyms : decyl hydride; n-decane; decane 99+%
CAS No. : 124-18-5
Molecular Weight : 142.29
Chemical Formula : CH3(CH2)8CH3
Product Codes : Un Listed
J.T. Baker : G143
Mallinckrodt : 2353

Company Information:
LEONID CHEMICALS
62/A-2 1st Stage, Yeshwanthpur Industrial Suburb
Ashokpuram School Road
Bangalore-560 022, Karnataka, INDIA
Ph: +91-80-2337 8354, Fax: +91-80-2357 4827
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SECTION 2- COMPOSITION, INFORMATION ON INGREDIENTS
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Ingredient : Decane
CAS No. : 124-18-5
% : 90 - 100 %
Hazardous : Yes
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SECTION 3- HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
DANGER! FLAMMABLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED.
HARMFUL IF INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
AFFECTS CENTRAL NERVOUS SYSTEM. HAS NARCOTIC EFFECT.

J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)

Health Rating : 1 - Slight
Flammability Rating : 2 - Moderate
Reactivity Rating : 1 - Slight
Contact Rating : 1 - Slight
Lab Protective Equip : GOGGLES; LAB COAT; VENT HOOD; PROPER
GLOVES; CLASS B EXTINGUISHER
Storage Color Code : Red (Flammable)

Potential Health Effects
Inhalation:
Moderately irritating to the respiratory tract, especially in high concentrations.
Coughing, mild inflammation and possible dizziness or other narcotic effects can be
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expected.

Ingestion:
Mildly irritating to the gastro-intestinal tract, causing abdominal spasms, nausea,
vomiting (aspiration hazard!) and diarrhea.

Skin Contact:
Mild irritant and may cause inflammation and skin cracking due to defatting action.

Eye Contact:
Mild irritant, especially if splashed into the eye. Inflammation, tearing, pain can result.

Chronic Exposure:
Continued or repeated skin contact may cause dermatitis.

Aggravation of Pre-existing Conditions:
No information found.
-------------------------------------------------------------------------------------------------------
SECTION 4- FIRST AID MEASURES
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Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Call a physician.

Ingestion:
Aspiration hazard. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of
water. Never give anything by mouth to an unconscious person. Get medical attention
immediately. If vomiting occurs, keep head below hips to prevent aspiration into lungs.

Skin Contact:
Remove any contaminated clothing. Wash skin with soap or mild detergent and water for
at least 15 minutes. Wash clothes before reuse. Get medical attention if irritation
develops or persists.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and
upper eyelids occasionally. Get medical attention immediately.
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SECTION 5- FIRE FIGHTING MEASURES
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Fire:
Flash point : 46C (115F) CC
Autoignition temperature : 210C (410F)
Flammable limits in air % by volume:
lel: 0.8; uel: 5.4
Flammable Liquid and Vapor!

Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above.
Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to
static discharge.

Fire Extinguishing Media:
Dry chemical, alcohol foam or carbon dioxide. Do not use a solid stream of water, since
the stream will scatter and spread the fire. Water spray may be used to keep fire exposed
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containers cool.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with full facepiece operated in the pressure demand or other
positive pressure mode.
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SECTION 6- ACCIDENTAL RELEASE MEASURES
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Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal
protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary
and unprotected personnel from entering. Contain and recover liquid when possible. Use
non-sparking tools and equipment. Collect liquid in an appropriate container or absorb
with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste
container. Do not use combustible materials, such as saw dust. Do not flush to sewer! If a
leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel
attempting to stop leak, and to flush spills away from exposures.
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SECTION 7 - HANDLING and STORAGE
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Protect against physical damage. Store in a cool, dry well-ventilated location, away from
any area where the fire hazard may be acute. Outside or detached storage is preferred.
Separate from incompatibles. Containers should be bonded and grounded for transfers to
avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking
type tools and equipment, including explosion proof ventilation. Containers of this
material may be hazardous when empty since they retain product residues (vapors,
liquid); observe all warnings and precautions listed for the product.
--------------------------------------------------------------------------------------------------------
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
---------------------------------------------------------------------------------------------------------
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
500 ppm (TWA) for (Petroleum Distillates)
NIOSH (REL) 10Hr.TWA, 350mg/m3, 1800 mg/m3 15min. Ceiling for (Refined
Petroleum Distillates)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures
below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred
because it can control the emissions of the contaminant at its source, preventing
dispersion of it into the general work area. Please refer to the ACGIH document,
Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for
details.

Personal Respirators (NIOSH Approved):
For conditions of use where exposure to the substance is apparent and engineering
controls are not feasble, consult an industrial hygienist. For emergencies, or instances
where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-
deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or
coveralls, as appropriate, to prevent skin contact.

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Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in
work area.
---------------------------------------------------------------------------------------------------------
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Appearance : Clear, colorless liquid.
Odor : Gasoline-like odor.
Solubility : Insoluble in water.
Density : 0.73 @ 20/4C
pH : No information found.
% Volatiles by volume @ 21C (70F) : 100
Boiling Point : 174C (345F)
Melting Point : -30C (-22F)
Vapor Density (Air=1) : 4.9
Vapor Pressure (mm Hg) : 1.4 @ 25C (77F)
Evaporation Rate (BuAc=1) : No information found.
---------------------------------------------------------------------------------------------------------
SECTION 10 - STABILITY AND REACTIVITY
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Stability:
Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.

Hazardous Polymerization:
Will not occur.

Incompatibilities:
Strong oxidizers.

Conditions to Avoid:
Heat, flames, ignition sources and incompatibles.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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Inhalation mouse LC50: 72300 mg/m3/2H; Investigated as a tumorigen.

NTP Carcinogen
Ingredient : Decane (124-18-5)
Known : No
Anticipated : No
IARC Category : None
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SECTION 12 - ECOLOGICAL INFORMATION
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Environmental Fate:
When released into the soil, this material may biodegrade to a moderate extent. When
released into the soil, this material is not expected to leach into groundwater. When
released into the soil, this material is expected to quickly evaporate. When released into
water, this material may biodegrade to a moderate extent. When released to water, this
material is expected to quickly evaporate. This material has an estimated
bioconcentration factor (BCF) of greater than 100. This material has a log octanol-water
partition coefficient of greater than 3.0. This material may bioaccumulate to some
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extent. When released into the air, this material is expected to be readily degraded by
reaction with photochemically produced hydroxyl radicals. When released into the air,
this material is not expected to be degraded by photolysis. When released into the air, this
material is expected to have a half-life between 1 and 10 days.

Environmental Toxicity:
No information found.
--------------------------------------------------------------------------------------------------------
SECTION 13 - DISPOSAL CONSIDERATIONS
---------------------------------------------------------------------------------------------------------
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste
and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility.
Processing, use or contamination of this product may change the waste management
options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local
requirements.
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SECTION 14 - TRANSPORT INFORMATION
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Domestic (Land, D.O.T.)

Proper Shipping Name : N-DECANE
Hazard Class : 3
UN/NA : Un2247
Packing Group : III
Information reported for product/size : 500ML

International (Water, I.M.O.)

Proper Shipping Name : NORMAL-DECANE
Hazard Class : 3
UN/NA : Un2247
Packing Group : III
Information reported for product/size : 500ML

International (Air, I.C.A.O.)

Proper Shipping Name : NORMAL-DECANE
Hazard Class : 3
UN/NA : Un2247
Packing Group : III
Information reported for product/size : 500ML
--------------------------------------------------------------------------------------------------------
SECTION 15 - REGULATORY INFORMATION
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Chemical Inventory Status - Part 1
Ingredient : Decane (124-18-5)
TSCA : Yes
EC : Yes
Japan : Yes
Australia : Yes

Chemical Inventory Status - Part 2
Ingredient : Decane (124-18-5)


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Canada
Korea : Yes
DSL : Yes
NDSL : No
Phil : Yes

Federal, State & International Regulations - Part 1
Ingredient : Decane (124-18-5)

SARA 302
RQ : No
TPQ : No

SARA 313
List : No
Chemical Catg : No
Federal, State & International Regulations - Part 2
Ingredient : Decane (124-18-5)
CERCLA : No

RCRA
261.33 : No

TSCA
8(d) : No

Chemical Weapons Convention : No TSCA 12(b): No CDTA: No
SARA 311/312 : Acute: Yes Chronic: Yes Fire: Yes Pressure: No
Reactivity : No (Pure / Liquid)

Australian Hazchem Code : 3[Y]
Poison Schedule : None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
--------------------------------------------------------------------------------------------------------------------
SECTION 16 - OTHER INFORMATION
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NFPA Ratings: Health: 0 Flammability: 2 Reactivity: 0

Label Hazard Warning:
DANGER! FLAMMABLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF
INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL
NERVOUS SYSTEM. HAS NARCOTIC EFFECT

Label Precautions:
Avoid breathing vapor or mist.
Avoid contact with eyes, skin and clothing.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Keep away from heat, sparks and flame.

Label First Aid:
Aspiration hazard. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of
water. Never give anything by mouth to an unconscious person. If vomiting occurs, keep
TM


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head below hips to prevent aspiration into lungs. If inhaled, remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of
contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. In all
cases call a physician.

Product Use:
Laboratory Reagent.

Revision Information:
No Changes.
-------------------------------------------------------------------------------------------------------------------
DISCLAIMER:
--------------------------------------------------------------------------------------------------------------------
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by a
properly trained person using this product. Individuals receiving the information must
exercise their independent judgment in determining its appropriateness for a particular
purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES,
EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE
INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES
RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.




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