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MSDS Material Safety Data Sheet
CAS

64741-44-2 64742-53-6 111-76-2

File Name: 64741-44-2_64742-53-6_111-76.asp

                                                                                       Page: 1
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND
(1-800-274-5263)

Product name PYROIL?PENETRATING OIL
Product code PYAP16
Product Use Description No data

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance: liquid
Combustible Liquid, Toxic by inhalation, Toxic by ingestion, Toxic by skin absorption,
Moderate skin irritant, Moderate eye irritant, Carcinogen.

Potential Health Effects

Routes of exposure
Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion

Eye contact
Can cause eye irritation. Symptoms include stinging, tearing, redness, and
swelling of eyes.

Skin contact
Can cause skin irritation. Prolonged or repeated contact may dry the skin.
Symptoms may include redness, burning, and drying and cracking of skin, burns and
other skin damage. Additional symptoms of skin contact may include: skin blistering
acne Passage of this material into the body through the skin is possible, and skin contact
may be harmful.

Ingestion
Swallowing small amounts of this material during normal handling is not likely to
cause harmful effects. Swallowing large amounts may be harmful. This material can get
into the lungs during swallowing or vomiting. This results in lung inflammation and
other lung injury.



Page 1 / 9
Page: 2
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

Inhalation
It is possible to breathe this material under certain conditions of handling and use
(for example, during heating, spraying, or stirring). Breathing this material may be
harmful. Symptoms are not expected at air concentrations below the recommended
exposure limits, if applicable (see Section 8.).

Aggravated Medical Condition
Preexisting disorders of the following organs (or organ systems) may be
aggravated by exposure to this material:, skin, lung (for example, asthma-like
conditions), liver, kidney, blood-forming system, Individuals with preexisting heart
disorders maybe more susceptible to arrhythmias (irregular heartbeats) if exposed to high
concentrations of this material.

Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:, stomach or intestinal upset
(nausea, vomiting, diarrhea), irritation (nose, throat, airways), lung irritation, central
nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache,
unconsciousness), loss of coordination, confusion, difficult breathing, irregular heartbeat,
blood in the urine, blood abnormalities (breakage of red blood cells), narcosis (dazed or
sluggish feeling), kidney damage, liver damage, convulsions, coma, and death

Target Organs
Acute lethal exposure to ethylene glycol monobutyl ether in animal studies has
resulted in congestion of organs including kidney, spleen, and lung., Exposure to this
material (or a component) has been found to cause kidney damage in male rats. The
mechanism by which this toxicity occurs is specific to the male rat and the kidney effects
are not expected to occur in humans., Overexposure to this material (or its components)
has been suggested as a cause of the following effects in laboratory animals:, blood
abnormalities

Carcinogenicity
This material is not listed as a carcinogen by the International Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP), or the
Occupational Safety and Health Administration (OSHA)., This product (or a component)
is a petroleum-derived material. Similar materials and certain compounds occurring
naturally in petroleum oils have been shown to cause skin cancer in laboratory animals
following repeated exposure without washing or removal.

Reproductive hazard.
No data



Page 2 / 9
Page: 3
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

Other information
No data


3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Concentration
MINERAL SEAL OIL 64741-44-2 >=80-<90%
DISTILLATES (PETROLEUM), 64742-53-6 >=5-<10%
HYDROTREATED LIGHT NAPHT
ETHYLENE GLYCOL MONOBUTYL 111-76-2 >=1.5-<5%
ETHER

4. FIRST AID MEASURES

Eyes
If symptoms develop, immediately move individual away from exposure and into
fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids
apart; seek immediate medical attention.

Skin
Immediately flush skin with water for at least 15 minutes while removing
contaminated clothing and shoes. Seek immediate medical attention. Wash clothing
before reuse and decontaminate or discard contaminated shoes. Remove contaminated
clothing. Flush exposed area with large amounts of water. If skin is damaged, seek
immediate medical attention. If skin is not damaged and symptoms persist, seek medical
attention. Launder clothing before reuse.

Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give
anything by mouth; place individual on the left side with the head down. Contact a
physician, medical facility, or poison control center for advice about whether to induce
vomiting. If possible, do not leave individual unattended.

Inhalation
If symptoms develop, immediately move individual away from exposure and into
fresh air. Seek immediate medical attention; keep person warm and quiet. If person is
not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.

Notes to physician
Hazards: Inhalation of high concentrations of this material, as could occur in
enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias.


Page 3 / 9
Page: 4
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this
material. This material is an aspiration hazard. Potential danger from aspiration must be
weighed against possible oral toxicity (See Section 2 - Swallowing) when deciding
whether to induce vomiting. Acute aspiration of large amounts of oil-laden material may
produce a serious aspiration pneumonia. Patients who aspirate these oils should be
followed for the development of long-term sequelae. Repeated aspiration of small
quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid
pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and
radiological changes appear worse than clinical abnormalities. Occasionally, persistent
cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever,
and bloody sputum occur. Inhalation exposure to oil mists below current workplace
exposure limits is unlikely to cause pulmonary abnormalities.
Treatment: No information available.


5. FIRE-FIGHTING MEASURES

Suitable extinguishing media
Water mist, carbon dioxide (CO2), dry chemical

Hazardous combustion products
May form:, carbon dioxide and carbon monoxide, various hydrocarbons

Precautions for fire-fighting
Material is volatile and readily gives off vapors which may travel along the
ground or be moved by ventilation and ignited by pilot lights, flames, sparks, heaters,
smoking, electric motors, static discharge or other ignition sources at locations near the
material handling point.Wear full firefighting turn-out gear (full Bunker gear), and
respiratory protection (SCBA). Use water spray to cool fire exposed containers and
structures until fire is out if it can be done with minimal risk. Avoid spreading burning
liquid with water used for cooling purposes.
Flammability Class for Flammable Liquids
Combustible Liquid Class IIIA

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
For personal protection see section 8. Persons not wearing protective equipment
should be excluded from area of spill until clean-up has been completed.

Environmental precautions



Page 4 / 9
Page: 5
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

Prevent run-off to sewers, streams or other bodies of water. If run-off occurs,
notify proper authorities as required, that a spill has occurred.

Methods for cleaning up
Absorb liquid on vermiculite, floor absorbent or other absorbent material.

7. HANDLING AND STORAGE

Handling
Containers of this material may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard precautions
given in the data sheet must be observed. Avoid prolonged or repeated contact. Under
oxidation conditions, peroxides may be formed. If they become concentrated, these
peroxides may present an explosion hazard.

Storage
Do not store near extreme heat, open flame, or sources of ignition.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines

DISTILLATES (PETROLEUM), 64742-53-6
HYDROTREATED LIGHT NAPHT
OSHA Z1 Permissible exposure limit 500 ppm
OSHA Z1 Permissible exposure limit 2,000 mg/m3
OSHA Z1A time weighted average 400 ppm
OSHA Z1A time weighted average 1,600 mg/m3
US CA OEL Time Weighted Average (TWA) 400 ppm
Permissible Exposure Limit (PEL):
US CA OEL Time Weighted Average (TWA) 1,600 mg/m3
Permissible Exposure Limit (PEL):
ACGIH time weighted average 5 mg/m3 Mist.
ACGIH Short term exposure limit 10 mg/m3 Mist.
ACGIH NIC time weighted average 0.2 mg/m3 Inhalable fraction.
ETHYLENE GLYCOL MONOBUTYL 111-76-2
ETHER
ACGIH time weighted average 20 ppm
NIOSH Recommended exposure limit 5 ppm
(REL):
NIOSH Recommended exposure limit 24 mg/m3
(REL):
OSHA Z1 Permissible exposure limit 50 ppm
OSHA Z1 Permissible exposure limit 240 mg/m3


Page 5 / 9
Page: 6
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16


General advice
These recommendations provide general guidance for handling this product.
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical
concentrations and ventilation. It is ultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.

Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below TLV(s).

Eye protection
Chemical splash goggles in compliance with OSHA regulations are advised;
however, OSHA regulations also permit other type safety glasses. Consult your safety
representative.

Skin and body protection
Wear resistant gloves (consult your safety equipment supplier).
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Respiratory protection
If workplace exposure limit(s) of product or any component is exceeded (see
exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of
proper environmental control. OSHA regulations also permit other NIOSH respirators
(negative pressure type) under specified conditions (see your industrial hygienist).
Engineering or administrative controls should be implemented to reduce exposure.


9. PHYSICAL AND CHEMICAL PROPERTIES

liquid
Physical state
aerosol,
Form
No data
Colour
No data
Odour
No data
Boiling point/range
No data
pH
160 癋 / 71 癈
Flash point
No data
Evaporation rate
No data
Explosion limits
No data
Vapour pressure
No data
Vapour density


Page 6 / 9
Page: 7
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

0.819 g/cm3 @ 60.00 癋 / 15.56 癈
Density
8 lb/gal @ 60.00 癋 / 15.56 癈
No data
Solubility
No data
Partition coefficient (n-
octanol/water)
No data
Autoignition temperature


10. STABILITY AND REACTIVITY

Stability
Stable.

Conditions to avoid
None known.

Incompatible products
Avoid contact with:, strong acids, strong alkalis, strong oxidizing agents

Hazardous decomposition products
May form:, carbon dioxide and carbon monoxide, various hydrocarbons

Hazardous reactions
Product will not undergo hazardous polymerization.

Thermal decomposition
No data


11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
MINERAL SEAL OIL LD 50 Rat: 5 g/kg

DISTILLATES (PETROLEUM), LD 50 Rat: 5 g/kg
HYDROTREATED LIGHT NAPHT
ETHYLENE GLYCOL MONOBUTYL LD 50 Rat: 470 mg/kg
ETHER

Acute inhalation toxicity

MINERAL SEAL OIL LC 50 Rat: 1,700 mg/m3, 4 h




Page 7 / 9
Page: 8
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16

ETHYLENE GLYCOL MONOBUTYL LC 50 Rat: 450 ppm, 4 h
ETHER

Acute dermal toxicity


MINERAL SEAL OIL LD 50 Rabbit: 2 g/kg


DISTILLATES (PETROLEUM), LD 50 Rabbit: 2 g/kg
HYDROTREATED LIGHT NAPHT

ETHYLENE GLYCOL MONOBUTYL LD 50 Rabbit: 220 mg/kg
ETHER



12. ECOLOGICAL INFORMATION

Aquatic toxicity

Acute and Prolonged Toxicity to Fish
No data

Acute Toxicity to Aquatic Invertebrates
No data

Environmental fate and pathways
No data

13. DISPOSAL CONSIDERATIONS

Waste disposal methods
Dispose of in accordance with all applicable local, state and federal regulations.


14. TRANSPORT INFORMATION


Dangerous goods descriptions may not reflect package size, quantity, end-use or region-
specific exceptions that can be applied to shipments. Consult shipping documents for
material-specific descriptions.

15. REGULATORY INFORMATION


Page 8 / 9
Page: 9
Revision Date: 02/21/2007
SAFETY DATA SHEET
Print Date: 9/21/2007
MSDS Number: R0240649
PYROIL?PENETRATING OIL Version: 1.2
PYAP16


California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer,
birth defects or any other harm.


Fire Hazard
SARA Hazard Classification
Acute Health Hazard
Chronic Health Hazard


SARA 313 Component(s)
ETHYLENE GLYCOL 111-76-2 2.77%
MONOBUTYL ETHER

Combustible Liquid
OSHA Hazards
Toxic by inhalation
Toxic by ingestion
Toxic by skin absorption
Moderate skin irritant
Moderate eye irritant
Carcinogen

Health Flammability Reactivity Other
1 3 0
HMIS
1 3 0
NFPA


16. OTHER INFORMATION

The information accumulated herein is believed to be accurate but is not warranted to be
whether originating with the company or not. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable to their circumstances.

This MSDS has been prepared by Ashland's Environmental Health and Safety Department
(1-800-325-3751).




Page 9 / 9

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NAMECAS
7732-18-5_75-28-5_111-90-0_111-76-2_64-02-8_74-98-6.asp 7732-18-5 75-28-5 111-90-0 111-76-2 64-02-8 74-98-6
6834-92-0_111-76-2_1336-21-6.asp 6834-92-0 111-76-2 1336-21-6
64-17-5_111-76-2_13463-67-7.asp 64-17-5 111-76-2 13463-67-7
67-63-0_111-76-2_1336-21-6.asp 67-63-0 111-76-2 1336-21-6
111-76-2_34590-94-8_78-96.asp 111-76-2 34590-94-8 78-96-6
111-76-2_9016-45.asp 111-76-2 9016-45-9
67-63-0_111-76-2.asp 67-63-0 111-76-2
111-76-2_25155-30-0.asp 111-76-2 25155-30-0
111-76-2_107-21-1.asp 111-76-2 107-21-1
7732-18-5_111-76-2_577-11-7_64-17-5_104-76-7_67-64-1_05-30.asp 7732-18-5 111-76-2 577-11-7 64-17-5 104-76-7 67-64-1 05-30-0
7732-18-5_67-63-0.asp 7732-18-5 67-63-0
64-17-5_111-76-2_74-98-6_106-97.asp 64-17-5 111-76-2 74-98-6 106-97-8
64742-95-6_67-56-1_111-76.asp 64742-95-6 67-56-1 111-76-2
111-76.asp 111-76-2
111-76-2_1310-58-3.asp 111-76-2 1310-58-3
111-76-2_7732-18-5.asp 111-76-2 7732-18-5
111-76-2_141-43-5_67-63-0.asp 111-76-2 141-43-5 67-63-0
7647-01-0_111-76-2.asp 7647-01-0 111-76-2
111-76-2_7732-18-5.asp 111-76-2 7732-18-5
67-63-0_111-76-2_03-03-2.asp 67-63-0 111-76-2 03-03-2
111-76-2_7664-41-7_106-97-8_74-98-6_7732-18-5.asp 111-76-2 7664-41-7 106-97-8 74-98-6 7732-18-5
111-76-2_75-28-5_74-98-6.asp 111-76-2 75-28-5 74-98-6
111-76-2.asp 111-76-2
111-76-2_1310-73-2_141-43-5.asp 111-76-2 1310-73-2 141-43-5
111-76-2_1310-73-2_64-02-8_1344-09-8.asp 111-76-2 1310-73-2 64-02-8 1344-09-8
111-76-2_1310-58-3.asp 111-76-2 1310-58-3
64741-44-2_64742-53-6_111-76.asp 64741-44-2 64742-53-6 111-76-2
1310-73-2_111-76-2_12-06-0.asp 1310-73-2 111-76-2 12-06-0
7320-34-5_111-76-2_7758-29-4_1310-58-3.asp 7320-34-5 111-76-2 7758-29-4 1310-58-3
6196-95-8_9016-45-9_111-76.asp 6196-95-8 9016-45-9 111-76-2
111-76-2_141-43-5_9016-45.asp 111-76-2 141-43-5 9016-45-9
111-76-2_68476-86-8.asp 111-76-2 68476-86-8
75-09-2_111-76-2_67-63-0.asp 75-09-2 111-76-2 67-63-0
111-76-2.asp 111-76-2
111-76-2_64-17-5.asp 111-76-2 64-17-5
112-59-4_112-25-4_112-34-5_111-76-2_7732-18-5_143-22-6.asp 112-59-4 112-25-4 112-34-5 111-76-2 7732-18-5 143-22-6
111-76.asp 111-76-2
64742-47-8_67-64-1_111-76-2_124-38-9.asp 64742-47-8 67-64-1 111-76-2 124-38-9
111-76-2_64-02-8_68424-85-1_127087-87-0.asp 111-76-2 64-02-8 68424-85-1 127087-87-0
67-63-0_111-76.asp 67-63-0 111-76-2
25085-99-8_28064-14-4_106-89-8_122-60-1_111-76-2.asp 25085-99-8 28064-14-4 106-89-8 122-60-1 111-76-2
64741-89-5_111-76-2.asp 64741-89-5 111-76-2
1310-73-2_27177-77-1_68603-25-8_111-76-2.asp 1310-73-2 27177-77-1 68603-25-8 111-76-2
111-76-2_5989-27-5_74-98-6.asp 111-76-2 5989-27-5 74-98-6
9016-45-9_111-76.asp 9016-45-9 111-76-2
5989-27-5_111-76-2.asp 5989-27-5 111-76-2
64742-95-6_111-76-2_95-63-6_123-86-4_71-36-3_1330-20-7_8052-41.asp 64742-95-6 111-76-2 95-63-6 123-86-4 71-36-3 1330-20-7 8052-41-3 98-82-8 67-63-0 100-41-4 91-20-3
111-76-2_67-63-0_497-19.asp 111-76-2 67-63-0 497-19-8
63148-62-9_61702-78-1_111-76-2_73398-64-8.asp 63148-62-9 61702-78-1 111-76-2 73398-64-8
111-76-2_7930-01-3.asp 111-76-2 7930-01-3


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