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MSDS Material Safety Data Sheet
CAS

64-17-5 111-76-2 74-98-6 106-97-8

File Name: 64-17-5_111-76-2_74-98-6_106-97.asp

                                   MATERIAL SAFETY DATA SHEET

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1. Product and Company Identification
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050-002R
050-002
Product number
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GlemeCleaner
Glass Glass Cleaner
Product name
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23-Sep-2009
Effective date
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Sprayway, Inc.
Claire Manufacturing Co.
Company information
500 Vista Ave.
484
Addison, IL 60101 United States
United States
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General Assistance 800-424-9300
630-543-7600
Company phone
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1-703-527-3887
800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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16
Version #
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13-Mar-2009
Supersedes date
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2. Hazards Identification
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CONTENTS UNDER PRESSURE. Aerosol. Prolonged exposure may cause chronic
Emergency overview
effects. May be ignited by heat, sparks or flames.
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Potential health effects
Ingestion. Skin contact.
Routes of exposure
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Health injuries are not known or expected under normal use.
Eyes
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This product may be harmful if it is absorbed through the skin. Prolonged or repeated
Skin
contact can result in defatting and drying of the skin which may result in skin irritation and
dermatitis (rash).
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
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Exposure by ingestion of an aerosol is unlikely. Components of the product may be
Ingestion
absorbed into the body by ingestion.
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2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is
Target organs
repeated and prolonged and may cause blood damage. These effects have not been
observed in humans.
Blood.
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Unconsciousness. Liver injury may occur.
Chronic effects
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Cyanosis. Liver enlargement. Jaundice. Defatting of the skin. Irritation.
Signs and symptoms
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3. Composition / Information on Ingredients
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Components CAS # Percent
Ethyl Alcohol 64-17-5 1-3
2-Butoxyethanol 111-76-2 1-3
Propane 74-98-6 1-3
n-Butane 106-97-8 1-3
Non-hazardous and other components below reportable levels > 90
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation
develops or persists.
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Immediately take off all contaminated clothing. Wash off with warm water and soap. Get
Skin contact
medical attention if irritation develops or persists.
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If symptoms develop move victim to fresh air. If symptoms persist, get medical attention.
Inhalation
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Rinse mouth. If ingestion of a large amount does occur, call a poison control center
Ingestion
immediately.

trade_name Glass Cleaner MSDS US
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Product #: 050-002 Revision date: 23-SEP-2009 Print date: 23-SEP-2009
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5. Fire Fighting Measures
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Vapor or gas may spread to distant ignition sources and flash back.
Flammable properties
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Extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Suitable extinguishing media
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Protection of firefighters
Containers should be cooled with water to prevent vapor pressure build up.
Protective equipment and
precautions for firefighters
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6. Accidental Release Measures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable. Stop the flow of material, if this is without risk. Prevent entry into
waterways, sewers, basements or confined areas.
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Should not be released into the environment. Use a non-combustible material like
Methods for cleaning up
vermiculite, sand or earth to soak up the product and place into a container for later
disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
Handling
an open flame, heat or other sources of ignition. Use only in area provided with
appropriate exhaust ventilation. Do not use if spray button is missing or defective. Do not
get this material in contact with eyes. Do not get this material in contact with skin. Avoid
prolonged exposure.
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Level 1 Aerosol.
Storage
Contents under pressure. Do not puncture, incinerate or crush. Do not handle or store
near an open flame, heat or other sources of ignition. Do not expose to heat or store at
temperatures above 120癋/49癈 as can may burst. Avoid exposure to long periods of
sunlight. Keep out of the reach of children. Do not store, incinerate, or heat this material
above 120 degrees Fahrenheit.
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Ethyl Alcohol 64-17-5 1000 ppm Not established Not established
2-Butoxyethanol 111-76-2 20 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
n-Butane 106-97-8 1000 ppm Not established Not established
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OSHA
Components CAS # TWA STEL Ceiling
Ethyl Alcohol 64-17-5 1000 ppm Not established Not established
2-Butoxyethanol 111-76-2 50 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant
Skin protection
clothing.
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When workers are facing concentrations above the exposure limit they must use
Respiratory protection
appropriate certified respirators. If permissible levels are exceeded use NIOSH
mechanical filter / organic vapor cartridge or an air-supplied respirator.




trade_name Glass Cleaner MSDS US
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Product #: 050-002 Revision date: 23-SEP-2009 Print date: 23-SEP-2009
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9. Physical & Chemical Properties
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Compressed liquefied gas.
Appearance
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204.8 癋 (96.1 癈) estimated
Boiling point
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Colorless.
Color
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3.2733 kJ/g estimated
Flammability (HOC)
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No
Flash back
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-156 癋 (-104.4 癈) Propellant
Flash point
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Aerosol.
Form
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Butyl
Odor
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9.5 - 10.5
pH
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Liquid.
Physical state
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70 - 90 psig @ 70F
Pressure
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Completely
Solubility
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0.9605 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Stable at normal conditions.
Chemical stability
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Heat, flames and sparks.
Conditions to avoid
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None known.
Incompatible materials
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Hazardous decomposition products No hazardous decomposition products are known.
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11. Toxicological Information
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Acute LD50: 7571 mg/kg estimated, Rat, Dermal
Acute effects
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Not expected to be hazardous by OSHA criteria.
Sensitization
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Not expected to be hazardous by OSHA criteria.
Teratogenicity
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12. Ecological Information
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Components of this product have been identified as having potential environmental
Ecotoxicity
concerns.

LC50 36327 mg/L estimated, Fish, 96.00 Hours,
EC50 44247 mg/L estimated, Daphnia, 48.00 Hours,
IC50 11902 mg/L estimated, Algae, 72.00 Hours,
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13. Disposal Considerations
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D001: Waste Flammable material with a flash point <140 F
Waste codes
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Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material
Disposal instructions
and its container at hazardous or special waste collection point. Do not allow this material
to drain into sewers/water supplies. If discarded, this product is considered a RCRA
ignitable waste, D001. Dispose in accordance with all applicable regulations.
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk




trade_name Glass Cleaner MSDS US
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Product #: 050-002 Revision date: 23-SEP-2009 Print date: 23-SEP-2009
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
5F
Item
None
Labels required
2
Transport Category
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IATA
Basic shipping requirements:
Aerosols, flammable
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1
Labels required


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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
2-Butoxyethanol 111-76-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of New and Existing Chemicals (EINECS) Yes
Europe European List of Notified Chemical Substances (ELINCS) Yes
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
2-Butoxyethanol 111-76-2 Present
Ethyl Alcohol 64-17-5 Present
n-Butane 106-97-8 Present
Propane 74-98-6 Present

trade_name Glass Cleaner MSDS US
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Product #: 050-002 Revision date: 23-SEP-2009 Print date: 23-SEP-2009
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16. Other Information
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HMIS?is a registered trade and service mark of the NPCA.
Further information
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Health: 1
HMIS?ratings
Flammability: 2
Physical hazard: 0
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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Product and Company Identification: Alternate Trade Names
MSDS sections updated
Hazards Identification: Target organs
Physical & Chemical Properties: Physical & Chemical Properties
Transport Information: Product Shipping Name/Packing Group
Regulatory Information: United States
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Regulatory Compliance
Prepared by




trade_name Glass Cleaner MSDS US
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Product #: 050-002 Revision date: 23-SEP-2009 Print date: 23-SEP-2009

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ALL PAGES On Chemical Property IN THIS GROUP
NAMECAS
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