Material Safety Data Sheet U.S. Department of Labor
Occupational Safety and Health
May be used to comply with Administration
OSHA's Hazard Communication Standard, (Non-Mandatory Form)
29 CFR 1910.1200. Standard must be Form Approved
consulted for specific requirements. OMB No. 1218-0072
IDENTITY: Product Description: Water based cleaner and
Citro PPE Soak and Wash solvent
Section I
Manufacturer's Name: Emco Industries Inc. Emergency Telephone Number: 800.424.9300
Address: 3800 Oceanic Dr. Suite 109 Telephone Number for Information:
760.721.3654
Date Prepared: April 12, 2009
City, State: Oceanside, CA
Preparer:
Postal Code: 92056
Section II - Hazardous Ingredients/Identity Information
CAS
Hazardous Components: ACGIH TLV-TWA, TLA:
OSHA PEL- Number:
d-Limonene %: --
N.e., N.e.
TWS 5989-27-5
2-butoxyethanol 25ppm (skin), N.e.
N.e. 50ppm 111-76-2
Section III - Physical/Chemical Characteristics
Boiling Point/Freezing Point: Specific Gravity (H2O = 1)
196F/32F 0.98
Vapor Pressure (mm Hg) Melting Point
N.e.
None
Vapor Density (AIR = 1) Evaporation Rate
>1 (Butyl Acetate = 1) <1
Solubility in Water pH: 8.5
Completely soluble in water.
Appearance and Odor: Physical State: Liquid
Thin opaque liquid with strong citrus odor.
Section IV - Fire and Explosion Hazard Data
Flash Point (Method Used) Flammable Limits: LEL: UEL:
N.D. @ 212F? No, this product is classified N.e. N.e
combustible only. (29CFR
1910.1200)
Special Fire Fighting Procedures:
Use water spray to cool containers below the flash point or to disperse vapor. Fire crews
should wear self-contained breathing apparatus.
Means of Extinction: Use dry chemical, carbon dioxide, or alcohol foam
Auto-ignition Temperature: Hazardous Combustion Products:
711F? Oxides of Carbon
Sensitivity to Impact: No Sensitivity to Static Discharge: No
Section V - Reactivity Data
Incompatibility (Materials to Avoid): Avoid strong oxidizing agents due to increased risk of
fire or explosion.
Hazardous Decomposition or Byproducts: None Reported
Chemical Stability: Normally stable. May oxidize under prolonged exposure to air.
Hazardous polymerization does not occur.
Reactivity, and under what conditions? Not reactive under normal conditions.
Section VI - Health Hazard Data
Route(s) of Entry: Inhalation? Skin? Ingestion? Eye?
Major Major Minor Major
Effects of Acute Exposure to Product: Irritation can result from liquid, mist or vapor contact
respiratory tract, eyes and skin. Absorption through skin or inhalation of vapor at normal
temperatures poses minimal hazard. Ingestion of large amounts will cause diarrhea.
Aspiration can damage lungs and cause death.
Effects of Chronic Exposure to Product: Prolonged or repeated exposure can de-fat skin and
lead to dermatitis. May cause allergic skin response in some persons. Intense long-term
exposure may cause kidney problems.
Exposure Limits: Irritancy of Sensitization to Carcinogenicity:
ACGHI-TLV-TWA Product: Product: Not reported by
Is 25 ppm for As above. d-Limonene is OSHA, IARC, NTP, ACGIH
2-but ox ethanol. sensitizer
"skin" notation
Reproductive
Teratogenicity: Mutagenicity: Synergistic Products:
toxicity:
Not Reported. Not Reported. Not Reported.
Not Reported.
Section VII - Precautions for Safe Handling and Use
Steps to Be Taken in Case Material is Released or Spilled:
Soak up small spills with absorbent materials. Prevent run-off from reaching sewers, storm
drains or natural water bodies. No Reportable Quantity according to 40 CFR 302.
Waste Disposal Method:
Dispose of according to federal, state, and local laws.
Precautions to Be taken in Handling and Storing:
Avoid generating mists. Keep containers closed when not in use. Do not freeze. Ground
containers to avoid static accumulation. Empty containers may contain a hazardous residue.
Store in cool, well ventilated area away from incompatible materials and ignition sources.
Engineering Controls (Specify, ventilation enclosed process):
Mechanical ventilation, both dilution and local exhaust may be utilized to keep exposure
below the exposure limit. Extra ventilation should be provided in enclosed spaces and in hot
weather.
TDG Un Number:
Special Shipping information:
Non-regulated as packaged USA D.O.T
Combustible Liquid (29CFR 1910.1200)
(16CFR 172.101)
Section VIII - Control Measures and First Aid
Inhalation: Remove victim to fresh air. If breathing has stopped, a trained person should
perform artificial respiration. Seek medical care.
Ingestion: Do not induce vomiting. If conscious, give victim cold water. Never give anything
by mouth to an unconscious person. Seek medical attention.
Eye Contact: Flush eye for 15 minutes with water while retracting eyelids. Seek medical
attention.
Skin contract: Remove contaminated clothing. Wash affected area with soap and water.
Launder clothing before reuse. Seek medical attention if irritation persists.
Protective Gloves: Neoprene, Nitrile, Butyl Eye Protection: Chemical safety goggles
rubber or Polyvinyl alcohol are recommended. recommended. A face shield may be
warranted in some applications.
Respiratory Protection: No respiratory protection is required under normal conditions of use.
Consider the use of respiratory protection in confined spaces or at elevated temperatures.
Other Protective Clothing or Equipment: Coveralls or other suitable protective clothing.
Impervious boots using same as for gloves.
Other: Emergency eye-wash and shower should be available.
* U.S.G.P.O.: 1986 - 491 - 529/45775
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