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MSDS Material Safety Data Sheet
CAS

112-59-4 112-25-4 112-34-5 111-76-2 7732-18-5 143-22-6

File Name: 112-59-4_112-25-4_112-34-5_111-76-2_7732-18-5_143-22-6.asp

UNION CARBIDE -- HEXYL CARBITOL SOLVENT - INHIBITOR,ICING,FUEL SYSTEM
MATERIAL SAFETY DATA SHEET
NSN: 685000D003001
Manufacturer's CAGE: 61637
Part No. Indicator: A
Part Number/Trade Name: HEXYL CARBITOL SOLVENT
===========================================================================
General Information
===========================================================================
Item Name: INHIBITOR,ICING,FUEL SYSTEM
Company's Name: UNION CARBIDE CORP., INDUSTRIAL CHEMICALS DIVISION
Company's Street: 39 OLD RIDGEBURY ROAD
Company's City: DANBURY
Company's State: CT
Company's Country: US
Company's Zip Code: 06817-0001
Company's Emerg Ph #: 800-822-4357/PATRICIA CODY AT 203
Company's Info Ph #: 800-822-4357/ 203-794-3451
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SE
Date MSDS Prepared: 06JUN91
Safety Data Review Date: 21APR93
Supply Item Manager: CX
MSDS Serial Number: BQKWG
Specification Number: MIL-I-85470
Hazard Characteristic Code: T6
Unit Of Issue: NK
Unit Of Issue Container Qty: UNKNOWN
Type Of Container: UNKNOWN
Net Unit Weight: UNKNOWN
===========================================================================
Ingredients/Identity Information
===========================================================================
Proprietary: NO
Ingredient: ETHANOL, 2-(2-(HEXYLOXY)ETHOXY)-/HEXYL CARBITOL
Ingredient Sequence Number: 01
Percent: 96.400
NIOSH (RTECS) Number: KL2625000
CAS Number: 112-59-4
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: ETHANOL,2-(HEXYLOXY)/HEXYL CELLOSOLVE
Ingredient Sequence Number: 02
Percent: 1.400
NIOSH (RTECS) Number: KL2450000
CAS Number: 112-25-4
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: DIETHYLENE GLYCOL MONOBUTYL ETHER/BUTYL CARBITOL
Ingredient Sequence Number: 03
Percent: 0.370
NIOSH (RTECS) Number: KJ9100000
CAS Number: 112-34-5
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: 2-BUTOXYETHANOL/BUTYL CELLOSOLVE
Ingredient Sequence Number: 04
Percent: 0.002
NIOSH (RTECS) Number: KJ8575000
CAS Number: 111-76-2
OSHA PEL: S, 50 PPM
ACGIH TLV: S, 25 PPM; 9293
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: OCTYL CELLOSOLVE
Ingredient Sequence Number: 05
Percent: 0.027
NIOSH (RTECS) Number: 1009454OC
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: GLYCOLS (TYPE NOT SPECIFIED)
Ingredient Sequence Number: 06
Percent: 0.474
NIOSH (RTECS) Number: 1001317GL
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: ALCOHOLS (TYPE NOT SPECIFIED)
Ingredient Sequence Number: 07
Percent: 0.203
NIOSH (RTECS) Number: 1001307AA
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: WATER
Ingredient Sequence Number: 08
Percent: 0.050
NIOSH (RTECS) Number: ZC0110000
CAS Number: 7732-18-5
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: ETHANOL, 2-(2-(2-BUTOXYETHOXY)ETHOXY)-/BUTOXY TRIGLYCOL
Ingredient Sequence Number: 09
Percent: 0.259
NIOSH (RTECS) Number: KJ9450000
CAS Number: 143-22-6
OSHA PEL: NOT ESTABLISHED.
ACGIH TLV: NOT ESTABLISHED.
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: UNKNOWNS
Ingredient Sequence Number: 10
Percent: BALANCE
NIOSH (RTECS) Number: 1009455UN
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
===========================================================================
Physical/Chemical Characteristics
===========================================================================
Appearance And Odor: WATER-WHITE LIQUID - SWEETISH ODOR
Boiling Point: 498F,259C
Melting Point: -40F,-40C
Vapor Pressure (MM Hg/70 F): <0.001@20C
Vapor Density (Air=1): 6.6
Specific Gravity: 0.935
Decomposition Temperature: UNKNOWN
Evaporation Rate And Ref: <0.01 (N-BUTYL ACETATE=1)
Solubility In Water: SOLUBLE
Percent Volatiles By Volume: NIL
Corrosion Rate (IPY): UNKNOWN
===========================================================================
Fire and Explosion Hazard Data
===========================================================================
Flash Point: 271F,133C
Flash Point Method: PMCC
Lower Explosive Limit: 0.7
Upper Explosive Limit: 13.0
Extinguishing Media: USE ALCOHOL-/ALL-PURPOSE-TYPE FOAM BY MANUFACTURER'S
RECOMMENDED TEACHNIQUES (LARGE FIRE), CO2/DRY CHEMICAL (SMALL FIRE)
Special Fire Fighting Proc: WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OPERATED IN THE POSITIVE PRESSURE MODE.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire And Expl Hazrds: THIS MATERIAL MAY PRODUCE A FLOATING FIRE
HAZARD. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.
===========================================================================
Reactivity Data
===========================================================================
Stability: YES
Cond To Avoid (Stability): EXCESSIVE HEAT
Materials To Avoid: NONE
Hazardous Decomp Products: CARBON MONOXIDE, CARBON DIOXIDE
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
===========================================================================
Health Hazard Data
===========================================================================
LD50-LC50 Mixture: TLV (BUTYL CELLOSOLVE) 25 PPM SKIN(MSDS)
Route Of Entry - Inhalation: NO
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: NO
Health Haz Acute And Chronic: ACUTE-EYES:MAY CAUSE PAIN,TEARING,BLINKING &
CORNEAL INJURY.SKIN:MAY CAUSE ITCHING,REDNESS & SWELLING.MAY BE ABSORBED IN
TOXIC AMOUNTS.INHALED:NO SHORT-TERM ADVERSE HEALTH EFFECTS AT AMBIENT
TEMPERATURE.ORAL:MODERATELY TOXIC.MAY CAUSE IRRITATION,VOMITING,DIARRHEA,
DIZZINESS,LOSS OF CONSCIOUSNESS.CHRONIC-DERMATITIS.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Signs/Symptoms Of Overexp: MAY CAUSE EYE PAIN,TEARING,BLINKING & CORNEAL
INJURY.MAY CAUSE SKIN ITCHING,REDNESS & SWELLING.MAY BE ABSORBED IN TOXIC
AMOUNTS THROUGH SKIN.NO SHORT-TERM ADVERSE HEALTH EFFECTS BY INHALATION,AT
AMBIENT TEMPERATURE.MODERATELY TOXIC IF INGESTED.MAY CAUSE
IRRITATION,VOMITING,DIARRHEA,DIZZINESS & LOSS OF CONSCIOUSNESS.
Med Cond Aggravated By Exp: PRE-EXISTING SKIN DISORDERS MAY BE MORE
SUSCEPTIBLE TO THIS MATERIAL.
FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP
& WATER. INHALED:NO EMERGENCY CARE ANTICIPATED. ORAL:DO NOT INDUCE
VOMITING. IF CONSCIOUS, DRINK TWO GLASSES OF WATER. CONTACT PHYSICIAN. NOTE
TO PHYSICIAN:MODERATE ACUTE SYSTEMIC TOXICITY BY INGESTION & SUSTAINED SKIN
CONTACT. GASTRIC LAVAGE WITH ENDOTRACHEAL INTUBATION SUGGESTED.
===========================================================================
Precautions for Safe Handling and Use
===========================================================================
Steps If Matl Released/Spill: WEAR PROTECTIVE EQUIPMENT, ESPECIALLY EYE
PROTECTION. SMALL SPILLS COULD BE FLUSHED WITH LARGE AMOUNT OF WATER INTO
SEWERS IF PERMITTED. LARGER SPILLS SHOULD BE COLLECTED FOR DISPOSAL.
Waste Disposal Method: INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE LOCAL, STATE AND FEDERAL REGULATIONS.
Precautions-Handling/Storing: STORAGE- KEEP CONTAINER TIGHTLY CLOSED.
DANGER; CAUSE EYE BURNS. HARMFUL IF ABSORBED THROUGH SKIN OR IF INGESTED.
Other Precautions: WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. KEEP OUT OF REACH OF CHILDREN. DO NOT SWALLOW. FOR
INDUSTRIAL USE ONLY. USE WITH ADEQUATE VENTILATION.
===========================================================================
Control Measures
===========================================================================
Respiratory Protection: NOT REQUIRED FOR USE AT NORMAL TEMPERATURES.
Ventilation: GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE
SATISFACTORY.
Protective Gloves: BUTYL
Eye Protection: MONOGOGGLES
Other Protective Equipment: EYE BATH, SAFETY SHOWER AND CHEMICAL RESISTANT
APRON
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Suppl. Safety & Health Data: WARNING: SUDDEN RELEASE OF HOT ORGANIC
CHEMICAL VAPORS OR MISTS FROM PROCESS EQUIPMENT OPERATING AT ELEVATED
TEMPERATURE AND PRESSURE MAY RESULT IN IGNITIONS WITHOUT PRESENCE OF
OBVIOUS IGNITION SOURCES.
===========================================================================
Transportation Data
===========================================================================
Trans Data Review Date: 93111
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
AFI PSN Code: ZZZ
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
===========================================================================
Disposal Data
===========================================================================
===========================================================================
Label Data
===========================================================================
Label Required: YES
Technical Review Date: 21APR93
MFR Label Number: NOT APPLICABLE
Label Status: F
Common Name: HEXYL CARBITOL SOLVENT
Signal Word: WARNING!
Acute Health Hazard-Moderate: X
Contact Hazard-Moderate: X
Fire Hazard-Slight: X
Reactivity Hazard-None: X
Special Hazard Precautions: ACUTE-EYES:MAY CAUSE PAIN,TEARING,BLINKING &
CORNEAL INJURY.SKIN:MAY CAUSE ITCHING,REDNESS & SWELLING.MAY BE ABSORBED IN
TOXIC AMOUNTS.INHALED:NO SHORT-TERM ADVERSE HEALTH EFFECTS AT NORMAL
TEMPERATURE.ORAL:MODERATELY TOXIC.MAY CAUSE IRRITATION,VOMITING,DIARRHEA,
DIZZINESS,LOSS OF CONSCIOUSNESS.CHRONIC-DERMATITIS.STORAGE-KEEP CONTAINER
TIGHTLY CLOSED.DANGER;CAUSE EYE BURNS.FIRST AID- CONSULT PHYSICIAN IF
SYMPTOMS PERSIST. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS
OPEN. SKIN:WASH WITH SOAP & WATER. INHALED:NO EMERGENCY CARE ANTICIPATED.
ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK TWO GLASSES OF WATER.
CONTACT PHYSICIAN.
Protect Eye: Y
Protect Skin: Y
Label Name: UNION CARBIDE CORP., INDUSTRIAL CHEMICALS
DIVISION
Label Street: 39 OLD RIDGEBURY ROAD
Label City: DANBURY
Label State: CT
Label Zip Code: 06817-0001
Label Country: US
Label Emergency Number: 800-822-4357/PATRICIA CODY AT 203

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