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MSDS Material Safety Data Sheet
CAS

111-76-2 7930-01-3

File Name: 111-76-2_7930-01-3.asp

                                 Simple Green?All-Purpose Cleaner
Material Safety Data Sheet:
Simple Green?Scrubbing Pad
ANSI-Z400.1-2003 Format
Version No. 1300509A Date of Issue: January 2009
Section 1: PRODUCT & COMPANY IDENTIFICATION
Simple Green?All-Purpose Cleaner
Product Name:
Simple Green?Scrubbing Pad
Simple Green?Concentrated Cleaner/Degreaser/Deodorizer
Additional Name:
Manufacturer's Product Code Numbers: *Please refer to page 4
Company: Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 562-795-6000
Telephone: Fax: 562-592-3830
Emergency Phone: Chem-Tel 24-Hour Emergency Service: 800-255-3924
Use of Product: An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures.
Scrubbing pad is used with water for manual scrubbing applications. Both are for cleaning water-safe
surfaces.

Section 2: HAZARDS IDENTIFICATION
Emergency Overview: CAUTION. Mild eye irritant.
Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle.
HMIS Rating:
0
Health = 1 = slight
0
1 Fire = 0
0 Reactivity, and Special = 0 = minimal

Mild Eye Irritant.
Eye Contact:
No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under
Skin Contact:
this condition, use of gloves or skin moisturizer after washing may be indicated.
May cause stomach or intestinal upset if swallowed (due to detersive properties.)
Ingestion:
No adverse effects expected under typical use conditions. Adequate ventilation should be present when
Inhalation:
using Simple Green?over a prolonged period of time. Open windows or ventilate via fan or other air-
moving equipment if necessary.
No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.
Carcinogens:
No medical conditions are known to be aggravated by exposure to Simple Green? Dermal-
Medical Conditions:
sensitive users may experience mild but reversible reactions.
Not Required Non-hazardous
UN Number: Dangerous Goods Class:
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
The only ingredient of Simple Green?with established exposure limits is undiluted 2-butoxyethanol (<4%) (Butyl
Cellosolve; CAS No. 111-76-2) [1% for Scrubbing Pad]: the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon
chemical analysis, Simple Green?contains no known EPA priority pollutants, heavy metals or chemicals listed under
RCRA, CERCLA, or CWA. Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed
no toxic organic or inorganic constituents.
All components of Simple Green?are listed on the TSCA Chemical Substance Inventory.
This product does not contain any ingredients covered by the provisions of 29 CFR 1910.1200.




Material Safety Data Sheet: SIMPLE GREEN?ALL-PURPOSE CLEANER & SCRUBBING PAD 1 of 4
Simple Green?All-Purpose Cleaner
Material Safety Data Sheet:
Simple Green?Scrubbing Pad
ANSI-Z400.1-2003 Format
Version No. 1300509A Date of Issue: January 2009
Section 4: FIRST AID MEASURES
Eye Contact: Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15
minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper
and lower lids during rinsing. Get medical attention if irritation persists.
Skin Contact: Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible
reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if
reaction persists.
Swallowing; Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset
occurs, consult physician.
Inhalation: Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh
air. Get medical attention if irritation persists.
Section 5: FIRE FIGHTING MEASURES
Simple Green?is stable, not flammable, and will not burn. No special procedures required.
Flash Point/Auto-Ignition: Not flammable. Extinguishing Media: Not flammable/non-explosive.
Flammability Limits: Not flammable. Special Fire Fighting Procedures: None required.

Section 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for
dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak.
Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop.
If necessary, unrecoverable material may be washed to drain with large quantities of water.

Section 7: HANDLING AND STORAGE
No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S.
Department of Transportation Regulations. Simple Green?requires no special labeling or placarding to meet U.S.
Department of Transportation requirements.
Not Required Non-hazardous
UN Number: Dangerous Goods Class:
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
The Simple Green?formulation presents no health hazards to the user when used according to label
Exposure Limits:
directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact
and Skin contact in section IV.) No special precautionary measures required under normal use
conditions.
Ventilation: No special ventilation, precautions or respiratory protection is required during normal use. Large-
scale use indoors should provide an increased rate of air exchange.
Adverse effects on human health are not expected from Simple Green? based on 20 years of use of
Human Health
Simple Green?without reported adverse health incidence in diverse population groups, including
Effects or Risks
From Exposure: extensive use by inmates of U.S. Federal prisons in cleaning operations.
Simple Green?is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye
Eye protection:
protection not generally required. Wash hands after using wipes.
Simple Green?is not likely to irritate the skin in the majority of users. Repeated daily application to
Skin protection:
the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible,
irritation. Rinse completely from skin after contact.

Material Safety Data Sheet: SIMPLE GREEN?ALL-PURPOSE CLEANER & SCRUBBING PAD 2 of 4
Simple Green?All-Purpose Cleaner
Material Safety Data Sheet:
Simple Green?Scrubbing Pad
ANSI-Z400.1-2003 Format
Version No. 1300509A Date of Issue: January 2009
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ?continued ?br> General hygiene There are no known hazards associated with this material when used as recommended.
conditions: The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor.
18 mm Hg @ 20oC; 23.5 mmHg @ 26oC
1.010 ?0.010
Specific Gravity: Vapor Pressure:
>1 (butyl acetate = 1) 1.3 (air = 1)
Evaporation: Vapor Density:
100% 8.5 lbs/gallon
Water Solubility: Density:
100.6oC (212oF) 9.5 ?0.3
Boiling Point: pH:
o
At 600 F: 1.86% by weight
Ash Content: Nutrient Content:
Phosphorus: 0.3% by formula
o o
Approx -9 C (16 F)
Freezing Point:
Nitrogen <1.0% by weight (fusion and qualitative test for ammonia)
If product freezes, it will reconstitute without loss of efficacy when
Sulfur: 0.6% by weight (barium chloride precipitation method)
brought back to room temperature and agitated.
o
VOC Composite Partial Pressure: 0.006 mmHg @ 20 C
Volatile Organic Compounds (VOCs): Cleaner meets CARB & BAAQMD regulations. Cleaner must be diluted 1:1
CARB Method 310 3.8% with water to Meet SCAQMD Rule 1171 & Rule 1122 VOC requirements for
solvent cleaning operations. [Scrubber VOCs = 3.3% prior to dilution w/water]
SCAQMD Method 313 2.8%

Section 10: STABILITY AND REACTIVITY
Stability: Stable
Materials to Avoid: None known
Hazardous Decomposition Products: None expected

Section 11: TOXICOLOGICAL INFORMATION
Toxicology information is based on chemical profile of ingredients and extrapolation of data from similar formulas.
*Calculation from OECD series on testing and
Acute Toxicity: Oral LD50 (rat) >5 g/kg body weight*
assessment number 33, Chapter 3.2
Dermal LD50 (rabbit) >2 g/kg body weight

Eye Irritation: Moderate/Mild reversible eye irritation may occur based on relevant laboratory studies. This
potential is reduced by immediate rinsing of eyes in case of eye contact.
Dermal Irritation: Mild, reversible skin irritation may occur based on relevant laboratory studies. A 6-hour exposure
to human skin under a patch did not produce irritation
Repeat Exposure Based on relevant laboratory studies, no toxic effects are expected to be associated with daily skin
Via Skin Contact: exposures (with up to 2 g/kg/day tested for 13 weeks on rabbits). Skin irritation may, however,
occur with repeated or prolonged exposures.
Reproductive Based on relevant laboratory studies (CD-1 mouse 18-week fertility assessment continuous
Effects Assessment: breeding), no adverse effects on reproduction, fertility, or health of offspring are expected.


Material Safety Data Sheet: SIMPLE GREEN?ALL-PURPOSE CLEANER & SCRUBBING PAD 3 of 4
Simple Green?All-Purpose Cleaner
Material Safety Data Sheet:
Simple Green?Scrubbing Pad
ANSI-Z400.1-2003 Format
Version No. 1300509A Date of Issue: January 2009
Section 12: ECOLOGICAL INFORMATION
Hazard to wild animals & aquatic organisms: Low, based on toxicological profile.
Biodegradability: Readily biodegradable based on biodegradation profile,
PRO/FT CBT-AC 014-7 "Ready Biodegradability: Closed Bottle Test" OECD, and OECD 302B laboratory tests
Environmental Toxicity Information: It is important not to allow the runoff from cleaning into closed systems such as
decorative ponds. Always protect closed systems with tarps or dikes if necessary.
Section 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty
containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used
degreasing rinsates into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
This product is non-hazardous for transport according to the U.S. Department of Transportation Services
UN Number: Not required Dangerous Goods Class: Non-hazardous
Section 15: REGULATORY INFORMATION
*Reportable components:
All components are listed on: EINECS and TSCA Inventory
No components listed under: Clean Air Act Section 112
This material contains 2-Butoxyethanol, < 4%, (CAS# 111-76-2) which is subject to the reporting
SARA: requirements of Section 313 of SARA Title III and 49 CFR Part 373.
RCRA Status: Not a hazardous waste. CERCLA Status: No components listed
TSCA TRI Reporting: Not required / Not listed CA PROP. 65 Status: No components listed

Section 16: OTHER INFORMATION
Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. ?TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Email:
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri] Fax: 562/592-3830
infoweb@simplegreen.com
CAGE CODE 1Z575
GSA/FSS - CONTRACT NO. GS-07F-0065J
National Stock Numbers & Industrial Part Numbers: Retail Numbers:
Simple Green Part Number NSN Size Part Number Size
13012 7930-01-342-5315 24 oz spray (12/case) 13002 16 oz Trigger (12/case)
13005 7930-01-306-8369 1 Gallon (6/case) 13005 1 Gallon (6/case)
13006 7930-01-342-5316 5 Gallon 13013 24 oz Trigger (12/case)
13016 7930-01-342-5317 15 Gallon 13014 67 oz / 2 L (6/case)
13008 7930-01-342-4145 55 Gallon 13033 32 oz Trigger (12/case)
Scrubbing Pad Part Number NSN Size * part number is for both industrial and retail
10224 7930-01-346-9148 Each (24/case) **International Part Numbers May Differ.

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel handling this
material must make independent determinations of the suitability and completeness of information from all sources to assure proper use and disposal
of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes no additional liability or responsibility
resulting from the use of, or reliance on this information.




Material Safety Data Sheet: SIMPLE GREEN?ALL-PURPOSE CLEANER & SCRUBBING PAD 4 of 4

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64742-95-6_67-56-1_111-76.asp 64742-95-6 67-56-1 111-76-2
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111-76-2_1310-73-2_141-43-5.asp 111-76-2 1310-73-2 141-43-5
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111-76-2_1310-58-3.asp 111-76-2 1310-58-3
64741-44-2_64742-53-6_111-76.asp 64741-44-2 64742-53-6 111-76-2
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111-76-2.asp 111-76-2
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111-76.asp 111-76-2
64742-47-8_67-64-1_111-76-2_124-38-9.asp 64742-47-8 67-64-1 111-76-2 124-38-9
111-76-2_64-02-8_68424-85-1_127087-87-0.asp 111-76-2 64-02-8 68424-85-1 127087-87-0
67-63-0_111-76.asp 67-63-0 111-76-2
25085-99-8_28064-14-4_106-89-8_122-60-1_111-76-2.asp 25085-99-8 28064-14-4 106-89-8 122-60-1 111-76-2
64741-89-5_111-76-2.asp 64741-89-5 111-76-2
1310-73-2_27177-77-1_68603-25-8_111-76-2.asp 1310-73-2 27177-77-1 68603-25-8 111-76-2
111-76-2_5989-27-5_74-98-6.asp 111-76-2 5989-27-5 74-98-6
9016-45-9_111-76.asp 9016-45-9 111-76-2
5989-27-5_111-76-2.asp 5989-27-5 111-76-2
64742-95-6_111-76-2_95-63-6_123-86-4_71-36-3_1330-20-7_8052-41.asp 64742-95-6 111-76-2 95-63-6 123-86-4 71-36-3 1330-20-7 8052-41-3 98-82-8 67-63-0 100-41-4 91-20-3
111-76-2_67-63-0_497-19.asp 111-76-2 67-63-0 497-19-8
63148-62-9_61702-78-1_111-76-2_73398-64-8.asp 63148-62-9 61702-78-1 111-76-2 73398-64-8
111-76-2_7930-01-3.asp 111-76-2 7930-01-3


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