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MSDS Material Safety Data Sheet
CAS

111-76-2 141-43-5 9016-45-9

File Name: 111-76-2_141-43-5_9016-45.asp

                          MATERIAL SAFETY DATA SHEET
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name/Use: SPEEDBALL Original Fragrance Power Cleaner

MANUFACTURER
Butcher Telephone Number: 800-225-9475
The Butcher Company
Emergency T elephone (24 hours): 800-228-5635
67 Forest Street
CHEMTREC (U.S./Can.): 800-424-9300
Marlborough, MA 01752-3012
CHEMTREC (Int'l): +1 703-527-3887


2. COMPOSITION / INFORMATION ON INGREDIENTS

INGREDIENT(S) CAS NO. % BY WEIGHT
2-Butoxyethanol 111-76-2 5?
Ethanolamine 141-43-5 1?
Nonyl phenol ethoxylate 9016-45-9 1 ?1.5

See Section 8 for Exposure Limits NA - Not Applicable

OSHA REGULATORY STATUS: This product is classified as hazardous under OSHA regulations.
WHMIS CLASS: Class D- Division 2B

3. HAZARDS IDENTIFICATION


EMERGENCY OVERVIEW
Clear, Green Liquid. Mint Odor. Causes Eye Irritation.


POTENTIAL HEALTH EFFECTS (See Section 11 for Toxicological Information)
PRIMARY ROUTE(s) OF EXPOSURE: X Eye X Skin Contact X Skin Absorption
X Inhalation X Ingestion

EFFECTS OF ACUTE EXPOSURE
EYES:
Causes eye irritation. Symptoms may include redness and pain.

SKIN:
May cause mild skin irritation. Symptoms may include redness.

INHALATION:
High concentrations of vapor or mist may cause nose, throat and respiratory tract irritation. Symptoms may
include coughing.




MSDS No: 4043 Page: 1 of 7
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner


INGESTION:
May cause mouth, throat and stomach irritation. Symptoms may include nausea, vomiting and diarrhea. May
also cause central nervous system effects including headache, dizziness and weakness.

EFFECTS OF CHRONIC EXPOSURE:
Prolonged or repeated contact may cause skin irritation.

MEDICAL CONDITIONS AGGRAVATED:
May aggravate pre-existing eye, skin and respiratory conditions.


4. FIRST AID MEASURES

EYES:
Flush eyes with plenty of water while holding eyelids apart. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Do not put any medication in the victim's eyes unless instructed by a
physician. Get medical attention.

SKIN:
Flush with water, then wash with soap and water. Remove saturated clothing. Get medical attention if irritation
develops.

INHALATION:
Remove to fresh air. If not breathing, give respiration; if breathing is difficult, give oxygen (by trained personnel
only). Get medical attention if symptoms persist.

INGESTION:
Do not induce vomiting. Drink large quantities of water. Get immediate medical attention. Never give anything
by mouth to an unconscious person.


5. FIRE FIGHTING MEASURES

FLASH POINT AND METHOD: >200癋 93癈 TCC

FLAMMABLE LIMITS:
Not applicable.

AUTOIGNITION TEMPERATURE: Not applicable.

EXTINGUISHING MEDIA:
Use extinguishing media appropriate for surrounding fire.

HAZARDOUS COMBUSTION PRODUCTS:
Normal products of combustion (carbon monoxide and carbon dioxide).

FIRE AND EXPLOSION HAZARDS:
None known.




MSDS No: 4043 Page: 2 of 7
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner


FIRE FIGHTING INSTRUCTIONS:
This product is not flammable. As in any fire, MSHA/NIOSH approved self-contained breathing apparatus
(SCBA) and full protective gear should be worn.


6. ACCIDENTAL RELEASE MEASURES

See Section 8, Exposure Controls/Personal Protection and Section 3, Hazard Identification. Floors may be
slippery. Use care to avoid falling. Contain and isolate spill. Keep non-essential personnel from entering spill
area. Use mop, absorbent, or wet vacuum to collect material for proper disposal. Rinse area with water.


7. HANDLING AND STORAGE

HANDLING:
Follow label use directions. Do not mix with other chemicals unless instructed by label directions. Avoid contact
with eyes and skin. Wash thoroughly after handling. Remove saturated clothing. Wash clothing and equipment
before reuse.

STORAGE:
Keep container closed when not in use. Store away from incompatible materials. (See Section 10, Stability and
Reactivity).


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

PERSONAL PROTECTIVE EQUIPMENT (PPE)
EYE:
Where eye contact is possible, wear safety glasses with side shields or chemical splash goggles (ANSI Z87.1
approved).

SKIN:
Where prolonged or repeated contact is possible, chemical-resistant clothing (e.g., gloves) is recommended.

RESPIRATORY:
No respiratory protection is required if ventilation is adequate.

ENGINEERING CONTROLS:
Good general room ventilation is expected to be adequate. If user operations generate vapor or mist, ventilation
should be used to keep airborne concentrations below exposure limits.




MSDS No: 4043 Page: 3 of 7
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner


EXPOSURE LIMITS:
INGREDIENT(S) OSHA PEL/STEL ACGIH TLV/STEL
2-Butoxyethanol 25 ppm (120 mg/m3)/ 25 ppm (121 mg/m3)/
(Skin) (Skin)
Ethanolamine 3 ppm (8 mg/m3)/ 3 ppm (7.5 mg/m3)/
6 ppm (15 mg/m3) 6 ppm (15 mg/m3)
Nonyl phenol ethoxylate NA NA

NA - Not Available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mint
APPEARANCE: Clear, Green
pH: 11.9 to 12.7
PERCENT VOLATILE BY WEIGHT 98:
VAPOR PRESSURE: Not Available
VAPOR DENSITY: Not Available
BOILING POINT Not Available
:
FREEZING/MELTING POINT Not Available
:
SOLUBILITY IN WATER: Complete
EVAPORATION RATE: Not Available
SPECIFIC GRAVITY: 1.00
VISCOSITY: Water Thin
OCTANOL/WATER PARTITION COEFFICIENT Not Available
:
ODOR THRESHOLD: Not Available

10. STABILITY AND REACTIVITY
STABILITY (CONDITIONS TO AVOID):
Stable.

POLYMERIZATION:
Will not occur.

HAZARDOUS DECOMPOSITION:
None known.

INCOMPATIBLE MATERIALS:
Strong acids (e.g., hydrochloric) and oxidizers (e.g., bleach).

11. TOXICOLOGICAL INFORMATION
ACUTE DATA:
This product is a moderate to severe eye irritant and a mild skin irritant. Based on acute toxicity testing, it is not
considered to be toxic by inhalation, ingestion, or skin absorption. Acute overexposure to high concentrations
of 2-butoxyethanol by skin absorption, ingestion and inhalation has caused blood, liver and kidney effects in
laboratory animals. The following additional data are available for this product and its ingredients:



MSDS No: 4043 Page: 4 of 7
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner


PRODUCT/INGREDIENT ORAL LD50 (rat) DERMAL LD50 (rabbit) INHALATION LC50 (rat)
>5000 mg/kg >1000 mg/kg >200 mg/L (1-hr)
SPEEDBALL Original Fragrance Power
Cleaner
2-Butoxyethanol 470 mg/kg 220 mg/kg 450 ppm (4-hr)
Ethanolamine 1720 mg/kg 1018 mg/kg Not Available
Nonyl phenol ethoxylate 2000?000 mg/kg 1000?000 mg/kg Not Available


SENSITIZATION DATA:
No data available.

CHRONIC DATA:
Prolonged overexposure to high concentrations of ethanolamine by inhalation and ingestion has caused liver
and kidney effects in laboratory animals. Prolonged overexposure to high concentrations of 2-butoxyethanol by
skin absorption, ingestion and inhalation has caused blood, liver and kidney effects in laboratory animals.

REPRODUCTIVE/TERATOGENIC DATA:
No data available.

CARCINOGENIC/MUTAGENIC DATA:
Not listed as carcinogenic by NTP IARC, or ACGIH or regulated as a carcinogen by OSHA.
,

SYNERGISTIC MATERIALS:
No data available.


12. ECOLOGICAL INFORMATION

This product is made with all biodegradable detergents. No other data available.


13. DISPOSAL CONSIDERATIONS

Disposal of this material should be in accordance with local, state or provincial and federal regulations. The
unused product, as manufactured, is a RCRA hazardous waste (Corrosive-D002) in accordance with 40 CFR
261. The product has not been evaluated by the T oxicity Characteristic Leachate Procedure (TCLP). According
to RCRA, it is the responsibility of the waste generator to ensure proper disposal.


14. TRANSPORT INFORMATION

DOT/TDG HAZARDOUS MATERIAL DESCRIPTION: Not regulated


15. REGULATORY INFORMATION

Not meant to be all-inclusive--selected regulations represented.




MSDS No: 4043 Page: 5 of 7
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner


UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Under 40 CFR 370.2, this product meets the following hazard categories:
Immediate, Delayed.
313 REPORTABLE INGREDIENTS: 2-Butoxyethanol is subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 under the
chemical category Glycol Ethers.

CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: None of the ingredients in this product are reportable under CERCLA.

TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: This product complies with all TSCA inventory requirements.

USDA (U.S. DEPARTMENT OF AGRICULTURE):
This product is authorized for use in federally inspected meat and poultry plants.

MASSACHUSETTS, NEW JERSEY PENNSYLVANIA RIGHT-TO-KNOW:
,
INGREDIENT(S) CAS NO. STATE LISTING
Water 7732-18-5 Not Listed
2-Butoxyethanol 111-76-2 MA, NJ, PA
Ethanolamine 141-43-5 MA, NJ, PA
Nonyl phenol ethoxylate 9016-45-9 Not Listed

NA - Not Applicable

CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Class D-Division 2B, eye irritant; Class D-Division 2B, chronic toxic effects. This product has been classified
in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.


16. OTHER INFORMATION

HMIS RATING NFPA RATING
FIRE
HEALTH * 2
FLAMMABILITY 0
0
REACTIVITY 0
0
HEALTH 1 REACTIVITY
PERSONAL PROTECTION -
--

SPECIAL




MSDS No: 4043 Page: 6 of 7
SPEEDBALL Original Fragrance Power Date Prepared: 05/17/2000
Date Revised: 05/24/2000
Cleaner


MSDS STATUS
Revision #: 2

This MSDS replaces the June 27, 1997 MSDS. Any changes in information are as follows:
In Section 1
Date Prepared [ ] Print CHEMTREC Phone Number

In Section 3
Potential Health Effects - Skin Absorption (text)

In Section 9
(Group Field) for Vapor Pressure (Group Field) for Vapor Pressure Density Odor Threshold (text) (Group Field)
for Boiling Point (Group Field) for Freezing Point (Group Field) for Evaporation Rate Coeff Oil/Water (text)

In Section 11
Toxicological (text)

In Section 15
OSHA Hazard Comm. Rule (text) WHMIS Class


APPROVED BY: EH&S/Regulatory Affairs
APPROVAL DATE: 05/24/2000

The information on this data sheet represents our current data and best opinion as to the proper use in handling
of the product under normal foreseeable conditions. Any use of this product which is not in conformance with
this data sheet or product label, or which involves using the product in combination with any other product or
any other process is the responsibility of the user.




MSDS No: 4043 Page: 7 of 7

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NAMECAS
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6834-92-0_111-76-2_1336-21-6.asp 6834-92-0 111-76-2 1336-21-6
64-17-5_111-76-2_13463-67-7.asp 64-17-5 111-76-2 13463-67-7
67-63-0_111-76-2_1336-21-6.asp 67-63-0 111-76-2 1336-21-6
111-76-2_34590-94-8_78-96.asp 111-76-2 34590-94-8 78-96-6
111-76-2_9016-45.asp 111-76-2 9016-45-9
67-63-0_111-76-2.asp 67-63-0 111-76-2
111-76-2_25155-30-0.asp 111-76-2 25155-30-0
111-76-2_107-21-1.asp 111-76-2 107-21-1
7732-18-5_111-76-2_577-11-7_64-17-5_104-76-7_67-64-1_05-30.asp 7732-18-5 111-76-2 577-11-7 64-17-5 104-76-7 67-64-1 05-30-0
7732-18-5_67-63-0.asp 7732-18-5 67-63-0
64-17-5_111-76-2_74-98-6_106-97.asp 64-17-5 111-76-2 74-98-6 106-97-8
64742-95-6_67-56-1_111-76.asp 64742-95-6 67-56-1 111-76-2
111-76.asp 111-76-2
111-76-2_1310-58-3.asp 111-76-2 1310-58-3
111-76-2_7732-18-5.asp 111-76-2 7732-18-5
111-76-2_141-43-5_67-63-0.asp 111-76-2 141-43-5 67-63-0
7647-01-0_111-76-2.asp 7647-01-0 111-76-2
111-76-2_7732-18-5.asp 111-76-2 7732-18-5
67-63-0_111-76-2_03-03-2.asp 67-63-0 111-76-2 03-03-2
111-76-2_7664-41-7_106-97-8_74-98-6_7732-18-5.asp 111-76-2 7664-41-7 106-97-8 74-98-6 7732-18-5
111-76-2_75-28-5_74-98-6.asp 111-76-2 75-28-5 74-98-6
111-76-2.asp 111-76-2
111-76-2_1310-73-2_141-43-5.asp 111-76-2 1310-73-2 141-43-5
111-76-2_1310-73-2_64-02-8_1344-09-8.asp 111-76-2 1310-73-2 64-02-8 1344-09-8
111-76-2_1310-58-3.asp 111-76-2 1310-58-3
64741-44-2_64742-53-6_111-76.asp 64741-44-2 64742-53-6 111-76-2
1310-73-2_111-76-2_12-06-0.asp 1310-73-2 111-76-2 12-06-0
7320-34-5_111-76-2_7758-29-4_1310-58-3.asp 7320-34-5 111-76-2 7758-29-4 1310-58-3
6196-95-8_9016-45-9_111-76.asp 6196-95-8 9016-45-9 111-76-2
111-76-2_141-43-5_9016-45.asp 111-76-2 141-43-5 9016-45-9
111-76-2_68476-86-8.asp 111-76-2 68476-86-8
75-09-2_111-76-2_67-63-0.asp 75-09-2 111-76-2 67-63-0
111-76-2.asp 111-76-2
111-76-2_64-17-5.asp 111-76-2 64-17-5
112-59-4_112-25-4_112-34-5_111-76-2_7732-18-5_143-22-6.asp 112-59-4 112-25-4 112-34-5 111-76-2 7732-18-5 143-22-6
111-76.asp 111-76-2
64742-47-8_67-64-1_111-76-2_124-38-9.asp 64742-47-8 67-64-1 111-76-2 124-38-9
111-76-2_64-02-8_68424-85-1_127087-87-0.asp 111-76-2 64-02-8 68424-85-1 127087-87-0
67-63-0_111-76.asp 67-63-0 111-76-2
25085-99-8_28064-14-4_106-89-8_122-60-1_111-76-2.asp 25085-99-8 28064-14-4 106-89-8 122-60-1 111-76-2
64741-89-5_111-76-2.asp 64741-89-5 111-76-2
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111-76-2_5989-27-5_74-98-6.asp 111-76-2 5989-27-5 74-98-6
9016-45-9_111-76.asp 9016-45-9 111-76-2
5989-27-5_111-76-2.asp 5989-27-5 111-76-2
64742-95-6_111-76-2_95-63-6_123-86-4_71-36-3_1330-20-7_8052-41.asp 64742-95-6 111-76-2 95-63-6 123-86-4 71-36-3 1330-20-7 8052-41-3 98-82-8 67-63-0 100-41-4 91-20-3
111-76-2_67-63-0_497-19.asp 111-76-2 67-63-0 497-19-8
63148-62-9_61702-78-1_111-76-2_73398-64-8.asp 63148-62-9 61702-78-1 111-76-2 73398-64-8
111-76-2_7930-01-3.asp 111-76-2 7930-01-3


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