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26225-79-6 1330-20-7 108-94-1 100-41-4

File Name: 26225-79-6_1330-20-7_108-94-1_100-41.asp

                                                                                    MSDS Number: 000000000136

PROGRASS?HERBICIDE MSDS Version 2.3



SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
?br> Product Name PROGRASS HERBICIDE
Chemical Name 2-ethoxy-2,3-dihydro-3,3-dimethyl-5- benzofuranyl methanesulfonate (active
ingredient)
Synonym CR 14080
MSDS Number 136
Chemical Family
Chemical Formulation Mixture (active ingredient: C13H18O5S)
EPA Registration No. 432-941
Canadian Registrat. No.

Bayer Environmental Science
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA

For MEDICAL, TRANSPORTATION or Other EMERGENCY call 1-800-334-7577 24 hours/day
For Product Information call 1-800-331-2867

Product Use Description Selective herbicide for use by professional applicators on ornamental turf only.


SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS

Component Name CAS No. Concentration % by Weight
Minimum Maximum
Ethofumesate 26225-79-6 19.0000
Inert ingredients,including: 81.0000
Xylene 1330-20-7 <60.0000
Cyclohexanone 108-94-1
Ethyl benzene 100-41-4

INERT INGREDIENTS (81.0%): Only the regulated ingredients are listed above. For additional information,
refer to Section 15 (Regulatory Information).




Page 1 of 11 Bayer Environmental Science
A Business Group of Bayer
CropScience
Material Safety Data Sheet
MSDS Number: 000000000136
? MSDS Version 2.3
PROGRASS HERBICIDE

SECTION 3. HAZARDS IDENTIFICATION

NOTE: Please refer to Section 11 for detailed toxicological information.
Emergency Overview Danger! Keep out of the reach of children. Hazard to humans and domestic
animals. Corrosive - causes irreversible eye damage. Do not get in eyes or on
clothing. Harmful if absorbed through the skin. Avoid contact with skin.

Physical State liquid

Odor Aromatic hydrocarbon odor

Appearance Straw-colored

Routes of Exposure Skin contact. Vapor/mist inhalation.

Immediate Effects
Have the product container or label with you when calling a poison control center
or doctor or going for treatment.

Eye Corrosive. Causes eye damage. The solvent vapor can be a mild eye irritant.
Use proper protective eyewear during handling/use (See Section 8).

Skin May be harmful if absorbed through skin. Repeated skin contact removes skin
oil, possibly leading to irritation and aggravation of an existing dermatitis.
Repeated contact may sensitize the skin, leading to allergic reactions.

Ingestion May be harmful if swallowed. No specific health effects are known for ingestion
of a small amount incidental to routine handling and use.

Inhalation Prolonged inhalation of high vapor concentrations may cause drowsiness and
dizziness.

Chronic or Delayed No component of this product is listed as a carcinogen by NTP, IARC, or OSHA.
Long-Term

Medical Conditions Repeated and prolonged skin contact can aggravate pre-existing dermititis
Aggravated by Exposure (irritating or/and inflammatory skin conditions).

Signs and Symptoms High concentrations of solvent vapor may cause dizziness, drowsiness,
weakness and incoordination.


SECTION 4. FIRST AID MEASURES

Eye Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a poison control center or doctor for treatment advice.

Skin Take off contaminated clothing. Rinse skin immediately with plenty of water for


Page 2 of 11
Material Safety Data Sheet
MSDS Number: 000000000136
? MSDS Version 2.3
PROGRASS HERBICIDE
15-20 minutes. Call a poison control center or doctor for treatment advice.

Ingestion Call a poison control center or doctor immediately for treatment advice. Have a
person sip a glass of water if able to swallow. Do not induce vomiting unless told
to do so by a poison control center or doctor. Do not give anything by mouth to
an unconscious person.

Note to Physician If swallowed, give gastric lavage. Avoid aspiration (contains xylene).


SECTION 5. FIRE FIGHTING MEASURES

Flash Point 29 癈 / 84 癋
(Flammable) P.M.C.C.
Flammability class: 1-C* (Classified by NFPA Standards)

Fire and Explosion Highly flammable liquid.
Hazards

Suitable Extinguishing dry chemical, foam, water
Media

Fire Fighting Wear self-contained breathing apparatus. Do not breathe fumes or vapor.
Instructions


SECTION 6. ACCIDENTAL RELEASE MEASURES

General and Disposal Use proper protective equipment to minimize personal exposure (see Section 8).
Take all necessary action to prevent and to remedy the effects of the spill.
Ensure that the disposal is in compliance with Federal or local disposal
regulations. Notify the appropriate authorities immediately.

(*Must refer to Section 15 for applicable Reportable Quantity (RQ) and other
federal or regulatory information; *Prograss contains CERCLA and RCRA
regulated inert ingredients).

Land Spill or Leaks Stop leak if it can be done without risk. Take up with sand or other non-
combustible material and place into a clean container for later disposal. Report
immediately to authorities if liquid enters watercourse or sewer.


SECTION 7. HANDLING AND STORAGE

Handling Procedures Danger! Flammable liquid. Corrosive. Causes eye damage. Do not get in eyes.
Avoid contact with skin.

Do not use, pour, spill or store near heat or open flame.

Storing Procedures Do not contaminate water, food, or feed by storage or disposal. Store in areas


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Material Safety Data Sheet
MSDS Number: 000000000136
? MSDS Version 2.3
PROGRASS HERBICIDE
designated for highly flammable liquids.

Work/Hygienic Wash hands before eating, drinking, chewing gum, using tobacco or using the
Procedures toilet.

Remove clothing immediately if pesticide gets inside. Then wash thoroughly and
put on clean clothing. Discard clothing and other absorbent materials that have
been drenched or heavily contaminated with this products concentrate.

Discard clothing and other absorbent materials that have been drenched or
heavily contaminated with this products concentrate. Do not reuse them. Follow
manufacturer's instructions for cleaning/maintaining Personal Protective
Equipment (PPE). If no such instructions for washables, use detergent and hot
water. Keep and wash PPE separately from other laundry.

Do not apply this product in a way that will contact workers or other persons,
either directly or through drift. Do not apply this product through any type of
irrigation system. Only protected handlers may be in the area during application.
For any requirements specific to your State or Tribe, consult the agency
responsible for pesticide regulation.

Do not enter or allow worker entry into treated areas during the restricted entry
interval (REI) of 12 hours.

Min/Max Storage 1 癈
Temperatures


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Control airborne concentrations below the exposure guidelines. Use with
adequate ventilation. Local exhaust ventilation may be necessary, when used in
a confined area.

When handlers used closed systems, enclosed cabs, or aircraft in a manner that
meets the requirements listed in the Worker Protection Standard (WPS) for
agricultural pesticides [(40 CFR 170.240(d) (4-6)], the handler PPE requirements
may be reduced or modified as specified in the WPS.

Eye/Face Protection goggles or face-shield

Body Protection Applicators and other handlers must wear: Long-sleeved shirt and long pants
Chemical resistant gloves, such as barrier laminate, or Vitron >/= 14 mils shoes
plus socks protective eyewear.

Respiratory Protection Ensure adequate ventilation. If not adequate, use a chemical cartridge-type
respirator approved by the National Institute of Occupational Health and Safety.

NOTE TO APPLICATORS AND HANDLERS:
For agricultural products which are within the scope of the EPA Worker


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Material Safety Data Sheet
MSDS Number: 000000000136
? MSDS Version 2.3
PROGRASS HERBICIDE
Protection Standards (WPS) (40 CFR Part 170), all users must refer to the
statement below or the Product Label for WPS-specified Personal Protective
Equipment (PPE), Restricted Entry Interval ( REI), and other Precautionary
Statements.

For non-agrucultural uses that are not within the scope of the Worker Protection
Standard for agricultural pesticides, the Personal Protection Equipment
recommendations are identical to that listed for WPS.

If you want more options to the PPE listed below, follow instructions for category
"G" on an EPA chemical-resistance category selection chart.

PERSONAL PROTECTIVE EQUIPMENT FOR APPLICATORS AND
HANDLERS: (FOR AGRICULTURAL AND NON-AGRICULTURAL USES.)

Applicators and handlers must wear:
Long-sleeve shirt and long pants.
Chemical-resistant gloves such as barrier laminate or Viton.
Shoes plus socks
Protective eyewear.

FOR AGRICULTURAL USES ONLY:

PERSONAL PROTECTIVE EQUIPMENT REQUIRED FOR EARLY ENTRY
INTO TREATED AREAS:
For entry into treated area during the restricted entry interval (REI) of 12 hours
that involves contact with anything that has been treated such as plants, soil, or
water, the PPE required is:

Coveralls over short-sleeved shirt and short pants.
Chemical-resistant gloves such as barrier laminate or viton.
Shoes plus socks.
Protective eyewear for overhead exposure.

Exposure Limits

Xylene 1330-20-7 OSHA Z1 PEL 100 ppm 435 mg/m3
OSHA Z1A TWA 100 ppm 435 mg/m3
OSHA Z1A STEL 150 ppm 655 mg/m3
US CA OEL TWA PEL 100 ppm 435 mg/m3
US CA OEL Ceiling 300 ppm
US CA OEL STEL 150 ppm 655 mg/m3
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 150 ppm 655 mg/m3
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 150 ppm 655 mg/m3
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 150 ppm 655 mg/m3
ACGIH TWA 100 ppm
ACGIH STEL 150 ppm


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Material Safety Data Sheet
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? MSDS Version 2.3
PROGRASS HERBICIDE
Cyclohexanone 108-94-1 ACGIH TWA 25 ppm
NIOSH REL 25 ppm 100 mg/m3
OSHA Z1 PEL 50 ppm 200 mg/m3
OSHA Z1A TWA 25 ppm 100 mg/m3
US CA OEL TWA PEL 25 ppm 100 mg/m3
ACGIH NIC TWA 20 ppm
ACGIH NIC STEL 50 ppm
Ethyl benzene 100-41-4 ACGIH TWA 100 ppm
ACGIH STEL 125 ppm
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 125 ppm 545 mg/m3
OSHA Z1 PEL 100 ppm 435 mg/m3
OSHA Z1A TWA 100 ppm 435 mg/m3
OSHA Z1A STEL 125 ppm 545 mg/m3
US CA OEL TWA PEL 100 ppm 435 mg/m3
US CA OEL STEL 125 ppm 545 mg/m3


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Straw-colored

Physical State liquid

Odor Aromatic hydrocarbon odor

Vapor Pressure Xylene (19 mmHg);
Cyclohexanone (3.95 mmHg)

Specific Gravity 0.95




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Material Safety Data Sheet
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? MSDS Version 2.3
PROGRASS HERBICIDE
Boiling Point 137 癈
(Xylene)


SECTION 10. STABILITY AND REACTIVITY

Chemical Stability Stable

Hazardous Will not occur.
Polymerization
(Conditions to avoid)


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Oral Toxicity Rat: LD50: 5,560 mg/kg
Low toxicity.

Acute Dermal Toxicity Rat: LD50: > 4,000 mg/kg
Low toxicity.

Acute Inhalation Toxicity No data is available for this formulated product.

However, the LC50 (mix) can be calculated from the available LC50 (rat) data for
the volatile solvents (xylene & cyclohexanone; inert ingredients).
The calculated LC50 (mix) for Prograss is estimated to be:
> 10.0 mg/L (low toxicity)

Skin Irritation Harmful if absorbed through the skin. A mild skin irritant on brief contact.
Prolonged contact removes skin oils and causes irritation. Repeated contacts
may sensitize the skin, leading to allergic reactions.

Eye Irritation Corrosive to eyes.
Causes irreversible eye damage when prolonged contact had occurred.

The studies reported below were carried out with Ethofumesate technical (97.4% ethofumesate), the active
ingredient of this product.

Sub-Chronic Toxicity Results from 90-day animal studies suggest no target organ effects under the
recommended conditions for normal handling and use.

Chronic Toxicity In two-year feeding studies with animals, adverse effects were only observed at
very high doses. These include: a reduced weight gain in males and increased
liver weight in females (rats, 5,000 ppm); an increased liver weight in females
(hamsters, 2,000 ppm); an increased liver weight in both males and females
(dogs, 20,000 ppm).

The inert ingredient cyclohexanone is listed by IARC as a Group 3 substance:
Not classifiable as human carcinogen (group 3); human evidence is no adequate
data; animal evidence is inadequate. Cyclohexanone is also listed as a NTP


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Material Safety Data Sheet
MSDS Number: 000000000136
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PROGRASS HERBICIDE
Testing Program substance.

Assessment Carcinogenicity

ACGIH
Xylene 1330-20-7 Group A4
Cyclohexanone 108-94-1 Group A4
Ethyl benzene 100-41-4 Group A3
NTP
None
IARC
Xylene 1330-20-7 3
Cyclohexanone 108-94-1 3
Ethyl benzene 100-41-4 2B
OSHA
None

Reproductive & Ethofumesate showed no adverse effects in a three-generation rat study.
Developmental Toxicity

Teratogenicity Ethofumesate had no teratogenic effects in rats at dose levels up to 80
mg/kg/day. In rabbits, no adverse effects of biological significance were
observed at the low dose (30 mg/kg/day); slight embryolethal effects were noted
at 300 mg/kg/day; severe maternal toxicity and moderate embryolethal effects
were observed at the highest dose (3,000 mg/kg/day). No malformation were
observed even at the highest dose.

Mutagenicity Ethofumesate was not mutagenic or genotoxic when tested in the Ames gene
mutation assay and in four other mutagenesis systems.


SECTION 12. ECOLOGICAL INFORMATION

Environmental For terrestrial uses, do not apply directly to water, or to areas where surface
Precautions water is present, or to intertidal areas below mean high water mark. Do not apply
when weather conditions favor drift from treated areas. Do not contaminate
water when disposing of equipment washwaters.




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Material Safety Data Sheet
MSDS Number: 000000000136
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PROGRASS HERBICIDE

SECTION 13. DISPOSAL CONSIDERATIONS

General Disposal Handling and disposal of pesticide wastes must be in accordance with the
Guidance requirements under the Resource and Recovery Act (RCRA) and applicable
state and local procedures. Please be advised that the state and local
requirements may be more restrictive or otherwise different from the federal
regulations

Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposal
of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If
these wastes cannot be disposed of by use according to label instructions,
contact your State Pesticide or Environmental Control Agency, or the Hazardous
Waste representative at the nearest EPA Regional Office for guidance.

Container Disposal Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture
and dispose of in a sanitary landfill, or by other procedures approved by state
and local authorities. Do not reuse empty container.

RCRA Classification 1330-20-7 Xylene

US. EPA Resource Conservation and Recovery Act (RCRA) U List of Hazardous
Wastes (40 CFR 261.33(f) and 40 CFR 302 [CERCLA]): U239



SECTION 14. TRANSPORT INFORMATION

PROPER SHIPPING NAME: Compound, weed killing, liquid (contains Cyclohexanone and Xylene), 3,
NA1993, PG III, * (* Insert net volume)

DOT SHIPPING LABEL: Flammable Liquid
FREIGHT CLASSIFICATION: Compound, weed killing, N.O.I.

NOTE: For the 4 x 1 gallon package, mark Limited Quantity.



SECTION 15. REGULATORY INFORMATION


US Federal Regulations
EPA Registration No. 432-941
TSCA list
Xylene 1330-20-7
Cyclohexanone 108-94-1
Ethyl benzene 100-41-4
TSCA 12b export notification
None
SARA Title III - section 302 - notification and information


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Material Safety Data Sheet
MSDS Number: 000000000136
? MSDS Version 2.3
PROGRASS HERBICIDE
None
SARA Title III - section 313 - toxic chemical release reporting
Xylene 1330-20-7 1.0%
Ethyl benzene 100-41-4 1.0%
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive
harm.


US State right-to-know ingredients
Xylene 1330-20-7 CA, CT, IL, MI, MN, NJ, PA, RI
Cyclohexanone 108-94-1 CA, CT, IL, MN, NJ, PA, RI
Ethyl benzene 100-41-4 CA, CT, IL, MN, NJ, PA, RI


Canadian Regulations
Canadian Registrat. No.
Canadian Domestic Substance List
Xylene 1330-20-7
Cyclohexanone 108-94-1
Ethyl benzene 100-41-4

Environmental
CERCLA
Xylene 1330-20-7 100 lbs
Cyclohexanone 108-94-1 5,000 lbs
Ethyl benzene 100-41-4 1,000 lbs
Clean Water Section 307 Priority Pollutants
Ethyl benzene 100-41-4
Safe Drinking Water Act Maximum Contaminant Levels
Xylene 1330-20-7
Ethyl benzene 100-41-4

International Regulations
EU Classification
Ethofumesate 26225-79-6 Dangerous for the environment
R Phrases Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
S Phrases Avoid release to the environment. Refer to special
instructions/safety data sheets.
Xylene 1330-20-7 Harmful
R Phrases Flammable. Harmful by inhalation and in contact with skin.
Irritating to skin.
S Phrases Keep out of the reach of children. Avoid contact with the
eyes.
European Inventory of Existing Commercial Substances (EINECS)
Ethofumesate 26225-79-6


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Material Safety Data Sheet
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PROGRASS HERBICIDE
Xylene 1330-20-7
Cyclohexanone 108-94-1
Ethyl benzene 100-41-4


SECTION 16. OTHER INFORMATION

Health Flammability Reactivity Others
HMIS 3 3 0 H
NFPA 3 3 0 none

REVISED SECTIONS:
MSDS REVISION INDICATOR: Company name change.

Print Date: 01/13/2005
Supersedes MSDS, which is older than: 01/23/2003

This information is provided in good faith but without express or implied warranty. Buyer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer AG. Bayer Environmental Science




Page 11 of 11

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