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109-99-9 78-93-3 108-94-1 67-64-1

File Name: 109-99-9_78-93-3_108-94-1_67-64-1.asp

                                                                                                                                                  Date Revised: DEC 2004
PARABOND MATERIAL SAFETY DATA SHEET
? Supersedes: DEC 2003
Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act and shall not be used for any other purpose.
Parabond urges the customers receiving this Material Safety Data Sheet to study it carefully to become aware of the hazards, if any, of the product involved. In the
interest of safety, you should notify your employees, agents and contractors of the information on this sheet.
SECTION I
MANUFACTURER'S NAME Transportation Emergencies:
PARABOND? CHEMTREC: (800) 424-9300
ADDRESS Medical Emergencies:
P. O. BOX 70013, SANTA ANA, CA, 92725-0013 3 E COMPANY (24 Hour No.) (800) 451-8346
Business: (310) 898-3300
CHEMICAL NAME and FAMILY TRADE NAME:
PVC/CPVC Primer PARABOND?C-60 Primer for PVC/CPVC
Mixture of Organic Solvents FORMULA: Proprietary

SECTION II - HAZARDOUS INGREDIENTS
None of the ingredients below are listed as DUPONT
carcinogens by IARC, NTP or OSHA CAS# APPROX % ACGIH-TLV ACGIH-STEL OSHA-PEL OSHA-STEL (A) AEL (B) STEL


Tetrahydrofuran (THF)** 109-99-9 15 - 25 200 PPM 250 PPM 200 PPM 250 PPM 50 PPM 75 PPM
Methyl Ethyl Ketone (MEK) 78-93-3 19 - 31* 200 PPM 300 PPM 200 PPM 300 PPM
Cyclohexanone 108-94-1 10 - 30 20 PPM Skin 50 PPM 50 PPM Skin
Acetone 67-64-1 25 - 35 750 PPM 1000 PPM 750 PPM 1000 PPM
All of the constituents of Parabond adhesive products are listed on the TSCA inventory of chemical substances maintained by the US EPA and/or the Canadian Domestic
Substance List (DSL), or are exempt from such listings.

* Title III Section 313 Supplier Notification: This product contains toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning
and Community Right-to-Know Act of 1986 and of 40CFR372. This information must be included in all MSDS's that are copied and distributed for this material.
(A) Dupont & BASF Mfg's Acceptable Exposure Limit (AEL) guidelines for 8 hour and 12 hour TWA, (B) Dupont/BASF recommended STEL for 15 minute TWA.
**Information found in a report from the National Toxicology Program (NTP) on an inhalation study in rats and mice suggests that Tetrahydrofuran (THF) can cause
tumors in animals. In the study the rats and mice were exposed to THF vapor levels up to 1800 PPM for two years (their lifetime), 6 hours/day, 5 days/week. Test
results showed evidence of liver tumors in female mice and kidney tumors in male rats. No evidence of tumors was seen in female rats and male mice. There is no
data linking Tetrahydrofuran exposure with cancer in humans.
BULK SHIPPING INFORMATION / CONTAINERS LARGER THAN ONE LITER SPECIAL HAZARD DESIGNATIONS
DOT Shipping Name: Flammable Liquid, n.o.s. (Contains: Tetrahydrofuran, HMIS NFPA HAZARD RATING
DOT Hazard Class: 3 Methyl, Ethyl, Ketone) HEALTH: 2 2 0 - MINIMAL
Identification Number: UN 1993 FLAMMABILITY: 3 3 1 - SLIGHT
Packaging Group: II REACTIVITY: 0 1 2 - MODERATE
Label Required: Flammable Liquid PROTECTIVE 3 - SERIOUS
EQUIPMENT: B-H 4 - SEVERE
SHIPPING INFORMATION FOR CONTAINERS LESS THAN ONE LITER B = Eye, Hand/Skin (for normal solvent-welding activities)
DOT Shipping Name: Consumer Commodity H = Eye, Hand/Skin, Respiratory Protection and Impermeable Apron (splash/
DOT Hazard Class: ORM-D immersion risks)

SECTION III - PHYSICAL DATA
APPEARANCE ODOR BOILING POINT (癋/癈)
Purple or Clear, thin liquid Ethereal 151癋 (67癈) Based on first boiling component: THF


SPECIFIC GRAVITY @ 73癋 ?3.6?(23癈 ?2? VAPOR PRESSURE (mm Hg.) PERCENT VOLATILE BY VOLUME (%)
Typical 0.830 ?0.040 143 mm Hg. based on first boiling 100 %
component, THF @ 68癋 (20癈)
VAPOR DENSITY (Air = 1) EVAPORATION RATE (BUAC = 1) SOLUBILITY IN WATER
2.49 > 1.0 Completely soluble in water.


VOC STATEMENT: VOC as manufactured: 830 Grams/Liter. Maximum VOC emission per SCAQMD Rule 1168, Test Method 316A: 570 Grams/Liter.

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT FLAMMABLE LIMITS LEL UEL
-4癋 (-20癈) T.C.C. Based on THF (PERCENT BY VOLUME) 2.0 11.8
FIRE EXTINGUISHING MEDIA
Ansul "Purple K" potassium bicarbonate dry chemical, any appropriately sized ABC dry chemical, carbon dioxide or foam extinguisher can be used for small fires. Use
of a water fog by trained personnel can extinguish small/large fires.

SPECIAL FIRE FIGHTING PROCEDURES
Evacuate enclosed areas. Stay upwind. Close quarters or confined spaces require self-contained breathing apparatus, positive pressure hose masks or airline masks.
Use of a water fog by trained personnel can extinguish small/large fires and avoid water flow or water streams/spray distributing burning material or contaminated water
over a large area or into sewers or storm drains. Use water spray to cool containers, to flush spills from source of ignition and to disperse vapors.

UNUSUAL FIRE AND EXPLOSION HAZARDS
Fire hazard because of low flash point and high volatility. Vapors are heavier than air and may travel to source(s) of ignition at or near ground or lower level(s) and may
flash back.
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SECTION V - HEALTH HAZARD DATA
PRIMARY ROUTES
OF ENTRY: X Inhalation X Skin Contact Eye Contact Ingestion

EFFECT OF OVEREXPOSURE
ACUTE:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Skin Contact: Skin irritant. Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Skin Absorption: Prolonged or widespread exposure may result in the absorption of harmful amounts of material.
Eye Contact: Overexposure may result in severe eye injury with corneal or conjuctival inflammation on contact with the liquid. Vapors slightly
uncomfortable.
Ingestion: Moderately toxic. May cause nausea, vomiting, diarrhea. May cause mental sluggishness.
CHRONIC: Symptoms of respiratory tract irritation and damage to respiratory epithelium were reported in rats exposed to 5000 ppm THF for 90 days.
Elevation of SGPT suggests a disturbance in liver function. The NOEL was reported to be 200 ppm.
REPRODUCTIVE EFFECTS TERATOGENICITY MUTAGENICITY EMBRYOTOXICITY SENSITIZATION TO PRODUCT SYNERGISTIC PRODUCTS
N. AP. N. AP. N. AP. N. AP. N. AP. N. AV.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing diseases of the eyes, skin or respiratory system may have increased
susceptibility to the toxicity of excessive exposures.
EMERGENCY AND FIRST AID PROCEDURES
Inhalation: If overcome by vapors, remove to fresh air and if breathing stopped, give artificial respiration. If breathing is difficult, give oxygen. Call
physician.
Eye Contact: Flush eyes with plenty of water for 15 minutes and call a physician.
Skin Contact: Remove contaminated clothing and shoes. Wash skin with plenty of soap and water for at least 15 minutes. If irritation develops, get
medical attention.
Ingestion: Give 1 or 2 glasses of water or milk. Do not induce vomiting. Call physician or poison control center immediately.

SECTION VI - REACTIVITY
STABILITY UNSTABLE CONDITIONS TO AVOID
STABLE X Keep away from heat, sparks, open flame and other sources of ignition.
INCOMPATIBILITY
(MATERIALS TO AVOID) Caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
HAZARDOUS DECOMPOSITION PRODUCTS
When forced to burn, this product gives out carbon monoxide, carbon dioxide, hydrogen chloride and smoke.
HAZARDOUS MAY OCCUR CONDITIONS TO AVOID
POLYMERIZATION WILL NOT OCCUR X Keep away from heat, sparks, open flame and other sources of ignition.

SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Eliminate all ignition sources. Avoid breathing of vapors. Keep liquid out of eyes. Flush with large amount of water. Contain liquid with sand or earth. Absorb with
sand or nonflammable absorbent material and transfer into steel drums for recovery or disposal. Prevent liquid from entering drains.

WASTE DISPOSAL METHOD
Follow local, State and Federal regulations. Consult disposal expert. Can be disposed of by incineration. Excessive quantities should not be permitted to enter
drains. Empty containers should be air dried before disposing. Hazardous Waste Code (CA): 214.

SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
Atmospheric levels should be maintained below established exposure limits contained in Section II. If airborne concentrations exceed those limits, use of a NIOSH
approved organic vapor cartridge respirator with full face-piece is recommended. The effectiveness of an air purifying respirator is limited. Use it only for a single
short-term exposure. For emergency and other conditions where short-term exposure guidelines may be exceeded, use an approved positive pressure
self-contained breathing apparatus.

VENTILATION
Use only with adequate ventilation. Do not use in close quarters or confined spaces. Open doors and/or windows to ensure airflow and air changes. Use local exhaust
ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed in Section II. Use only explosion-proof ventilation
equipment.

PROTECTIVE GLOVES PVA coated rubber gloves for frequent dipping/immersion. Use of latex/nitrile EYE PROTECTION Splashproof chemical goggles,
surgical gloves or solvent resistant barrier creme should provide adequate protection when normal solvent- face shield, safety glasses (spectacles) with brow
cement welding practices and procedures are used for solvent welding of plastic sheet/pipe joints. guards and side shields, etc. as appropriate for
exposure.
OTHER PROTECTIVE EQUIPMENT AND HYGIENIC PRACTICES
Impervious apron and a source of running water to flush or wash the eyes and skin in case of contact.

SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store in the shade between 40癋 - 110癋 (5癈 - 43.7癈). Keep away from heat, sparks, open flame and other sources of ignition. Avoid prolonged breathing of vapor.
Use with adequate ventilation. Avoid contact with eyes, skin and clothing. Train employees on all special handling procedures before they work with this product.

OTHER PRECAUTIONS
Follow all precautionary information given on container label, product bulletins and our solvent cementing literature. All material handling equipment should be
electrically grounded.
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from
the use thereof.
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