GHS SAFETY DATA SHEET
Date Revised: SEP 2009
WELD-ON 729?Low VOC Cement for CPVC Plastic Pipe Supersedes: JUN 2009
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
WELD-ON 729?Low VOC Cement for CPVC Plastic Pipe
PRODUCT NAME:
PRODUCT USE: Low VOC Solvent Cement for CPVC Plastic Pipe
SUPPLIER: MANUFACTURER: IPS Corporation
17109 South Main Street, Carson, CA 90248-3127
P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
EMERGENCY: Transportation: Tel. 800.424.9300, 703.527.3887 CHEMTREC (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
SECTION 2 - HAZARDS IDENTIFICATION
GHS CLASSIFICATION:
Health Environmental Physical
Acute Toxicity: Category 4 Acute Toxicity: None Known Flammable Liquid Category 2
Skin Irritation: Category 3 Chronic Toxicity: None Known
Skin Sensitization: NO
Eye: Category 2B
GHS LABEL: Signal Word: CLASS B, DIVISION 2
WHMIS CLASSIFICATION:
Danger
Hazard Statements Precautionary Statements
H225: Highly flammable liquid and vapor P210: Keep away from heat/sparks/open flames/hot surfaces ?No smoking
H319: Causes serious eye irritation P261: Avoid breathing dust/fume/gas/mist/vapors/spray
H335: May cause respiratory irritation P280: Wear protective gloves/protective clothing/eye protection/face protection
H336: May cause drowsiness or dizziness P337+P313: Get medical advice/attention
EUH019: May form explosive peroxides P403+P233: Store in a well ventilated place. Keep container tightly closed
P501: Dispose of contents/container in accordance with local regulation
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
CAS# EINECS # REACH CONCENTRATION
Pre-registration Number % by Weight
Tetrahydrofuran (THF) 109-99-9 203-726-8 05-2116297729-22-0000 50 - 70
Methyl Ethyl Ketone (MEK) 78-93-3 201-159-0 05-2116297728-24-0000 2 - 10
Cyclohexanone 108-94-1 203-631-1 05-2116297718-25-0000 5 - 15
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
SECTION 4 - FIRST AID MEASURES
Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
SECTION 5 - FIREFIGHTING MEASURES
Suitable Extinguishing Media: Dry chemical powder, carbon dioxide gas, foam, Halon, water fog. HMIS NFPA 0-Minimal
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks. 4-Severe
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat; drink or smoke while handling.
Storage: Store in ventilated room or shade below 27癈 (80癋) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION
EXPOSURE LIMITS: Component ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
Cyclohexanone 20 ppm 50 ppm 50 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,
etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local
exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Gray, extra heavy syrupy liquid
Odor: Ketone Odor Threshold: 0.88 ppm (Cyclohexanone)
pH Not Applicable
Melting/Freezing Point: -108癈 (-162癋) Based on first melting component: THF Boiling Range: 66癈 (151癋) to 156癈 (313癋)
Boiling Point: 67癈 (151癋) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -14癈 (7癋) TCC based on THF Flammability: Category 2
Specific Gravity 1.0 @23癈 ( 73癋) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 11.8% based on THF
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20癈 (68癋)based on THF
Auto-ignition Temperature: 321癈 (609.8癋) based on THF Vapor Density: <2 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Extra heavy bodied
When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 490 g/l.
VOC Content :
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATION
Likely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
Chronic (long-term) effects: None known to humans
LD50 LC50
Toxicity:
Inhalation 3 hrs. 21,000 mg/m3 (rat)
Tetrahydrofuran (THF) Oral: 2842 mg/kg (rat)
3
Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit) Inhalation 8 hrs. 23,500 mg/m (rat)
Methyl Ethyl Ketone (MEK)
Cyclohexanone Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit) Inhalation 4 hrs. 8,000 PPM (rat)
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: None Known
In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 490 g/l.
Mobility:
Degradability: Biodegradable
Bioaccumulation: Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Follow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION
Proper Shipping Name: Adhesives
Hazard Class: 3 EXCEPTION for Ground Shipping
Secondary Risk None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quanties may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid TDG INFORMATION
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION
Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S2: Keep out of the reach of children S25: Avoid contact with eyes.
S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
SECTION 16 - OTHER INFORMATION
Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
e-mail address: Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 9/30/09 / Updated GHS Standard Format
Intended Use of Product: Solvent Cement for CPVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
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