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MSDS Material Safety Data Sheet
CAS

108-94-1 78-59-1

File Name: 108-94-1_78-59-1.asp

                                               MATERIAL SAFETY DATA SHEET
MSDS ID#: 100005 Date Prepared: October 19, 1995
Revision: February 25, 2004

1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: M-149 OFFSET INK Product Code: I0006
Colors Covered: Resin Solution; Black; Blue; Green; White; UV Readable; Standard Grey; NL Red; NL Yellow; NL Orange; NL Brown; FR
Black; Silver; Purple; Process Blue; Spectra Blue; NL Red/Orange; Deep Red; Copper; Black Low Odor; SP Orange, PMS 9U/10U Grey; SP
Green
Supplier Name: Matthews International Corporation Address: 101 Fairview Avenue
City: Pittsburgh State/Zip: Pennsylvania, USA, 15238
Phone: (412)665-2500 Fax: (412)828-4545 24 Hour Emergency Phone: (412)456-7499

2. COMPOSITION/INFORMATION ON INGREDIENTS
[ ] Substance [ X ] Mixture
Hazardous Components Percent CAS No. TLV Carcinogen R-Phrase S-Phrases
Cyclohexanone 11-17 108-94-1 25 ppm No R10, R20 S25
Isophorone 35-60 78-59-1 5 ppm No R21/22, R36/37, R40 S13, S23,
S36/37/39, S46

3. HAZARDS IDENTIFICATION
Most Important Hazards: Severe eye irritant. Flammable liquid.
Main Symptoms of Overexposure: EYES- Causes severe irritation, experienced as discomfort or pain, excess blinking, marked redness and
swelling of the conjunctiva. may cause chemical burns or the cornea; SKIN- Moderate skin irritation. Prolonged contact may cause
chemical burns, seen as marked redness or swelling; INHALATION- May cause irritation of the respiratory tract, experienced as nasal
discomfort and discharge, with chest pain, coughing, headache, nausea, vomiting, dizziness, drowsiness, disturbed vision and
unconsciousness. Repeated or prolonged exposures to high concentrations may cause kidney and liver damage. INGESTION- May cause
nausea, vomiting, burning sensation in mouth and throat, and abdominal discomfort. HMIS: H-2, F-3, R-0

4. FIRST AID MEASURES
Inhalation: Move to fresh air. Aid in breathing, if necessary, and get immediate medical attention.
Skin Contact: Remove contaminated clothing. Wash skin with soap and water. Get medical attention if irritation persists. Wash clothing
before reuse.
Eye Contact: Immediately flush eyes with water for at least 15 minutes raising upper and lower eyelids occasionally. Get immediate medical
attention.
Ingestion: DO NOT induce vomiting. Keep person warm and quiet and get medical attention. Aspiration of the material into the lungs due
to vomiting can cause chemical pneumonitis which can be fatal.


5. FIRE-FIGHTING MEASURES
Extinguishing media: Water spray, dry chemical, carbon dioxide, and alcohol foam.

Specific Hazards: Flammable liquid. Do not pressurize, cut, weld or expose containers to flame or other sources of ignition. Vapors are
heavier than air and may travel along the ground or be moved by ventilation and be ignited by heat, pilot lights or other flames.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Eliminate all ignition sources.

Environmental precautions: Prevent runoff from entering drains, sewers or streams. May be toxic to fish

Methods of cleaning up: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Small spills
should be flushed with large amounts of water. Larger spills should be collected for disposal.

7. HANDLING AND STORAGE
Handling-Precautions: May cause eye burns. Harmful if absorbed through the skin. Wash thoroughly after handling.
Safe handling Advice: Keep away from heat, sparks and flames.
Storage-Conditions: Avoid excessive heat and sources of ignition. Store in a cool, clean, well ventilated non-smoking area in a sealed
grounded container.
Incompatible Products: Keep from contact with strong oxidizing agents.


Page 1 of 2
MSDS ID#: 100005 Date Prepared: October 19, 1995
Revision: February 25, 2004
Product Code: I0006
Product Name: M-149 OFFSET INK

8. EXPOSURE CONTROL/PERSONAL PROTECTION
Engineering Measures: Good general ventilation should be used. Use local exhaust ventilation or other engineering controls to maintain
airborne levels below recommended exposure limits.
Personal Protective Equipment: Eliminate all ignition sources.
Respiratory Protection: If engineering controls do not maintain concentrations below recommended exposure limits, an approved
respirator should be used. Type: organic vapor.
Hand Protection: Where prolonged or repeated skin contact will occur, impervious gloves should be worn. Type: butyl
Eye Protection: Wear safety glasses with side shield or goggles.
Skin and Body Protection: Recommended Decontamination facilities: eye bath, safety shower, washing facilities.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Various Odor: Characteristic ketone odor
Flashpoint: 43-50E C (110-122E F) Autoignition temperature: N/A pH: N/A
Density: 1.00-1.22 Vapor Pressure: N/A
Vapor Density: >3.0 Solubility in Water: negligible
Boiling Point: 157E C (314E F) for Cyclohexanone Freezing Point: N/A
V.O.C.: 642-734 Evaporation rate(Butyl Acetate=1): .38 for Cyclohexanone

10. STABILITY AND REACTIVITY
Stable: Yes Conditions to avoid: Avoid heat, sparks and open flames.
Materials to avoid: Avoid strong oxidizing agents.
Hazardous decomposition products: Carbon dioxide, carbon monoxide

11. TOXICOLOGICAL INFORMATION
Acute toxicity: Oral LD50 (rat, for Cyclohexanone)- 1.9 g/kg ;Dermal LD50 (rat, for Cyclohexanone)- 3.2 g/kg
Chronic Toxicity: Isophorone, when administered by stomach tube in corn oil at dosage levels of 250 or 500 mg/kg, of body weight, was associated with a
slightly increased incidence of renal and preputial tumors in male rats and of liver tumors in male mice but did not exhibit similar potential in either female
rates or mice Guinea pigs exposed to 4000 ppm of Cyclohexanone for a 6 hr period showed signs of CNS depression, lacrimation, salivation, depression of
body temperature and respiratory heart rate and opacity of the cornea. Liver and kidney damage reported in monkeys and rabbits (190 ppm) and rats (105.2
mg/m 3 ) due to Cyclohexanone.
Target Organs: Eyes, skin, respiratory system, central nervous system, liver, kidneys
Sensitization: No Specific Effects: May aggravate an existing condition of dermatitis.

12. ECOLOGICAL INFORMATION
Possible Environmental Effects: This product may be toxic to fish. Avoid discharge to natural waters. Do not discharge into sewers or
drains without the proper authority.
13. DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose of in accordance with all local, state and federal regulations.
14. TRANSPORT INFORMATION
Land: (DOT)- regulated, Flammable liquid, Class 3, packaging group III, Proper Shipping Name: Printing Ink, UN 1210
Inland Waterways: (ADR)- N/A
Sea: (IMDG)- regulated, Flammable liquid, Class 3.3, packaging group III, Proper Shipping Name: Printing Ink, UN 1210
Air: (IATA)- regulated, Flammable liquid, Class 3, packaging group III, Proper Shipping Name: Printing Ink, UN 1210

15. REGULATORY INFORMATION
Hazard and Safety Information: CA Prop 65- none; PA hazardous substance list- Cyclohexanone, listed; SARA 313- none; SARA 311,312- Immediate
health hazard, Delayed health hazard, Fire hazard (from Cyclohexanone and Isophorone) ; TSCA- all components listed; EINECS- Cyclohexanone: #203-631-
1, Isophorone: #201-126-0; Cyclohexanone: R10- Flammable, R20- Harmful by inhalation, S25- Avoid contact with eyes; Isophorone: R21/22- Harmful in
contact with skin and if swallowed, R36/37- Irritating to eyes and respiratory system, R40- Limited evidence of a carcinogenic effect, S13- Keep away from
food, drink and animal feedingstuffs, S23- Do not breathe vapor, S36/37/39- Wear suitable protective clothing, gloves and eye/face protection, S46- If
swallowed, seek medical advice immediately and show container/label
Ozone Depleting Chemicals Present: None
16. OTHER INFORMATION
Containers of this material may be hazardous when emptied, all hazard precautions given in the data sheet must be observed. The information contained herein
is based upon what we believe to be reliable data. However, we make no warranty or guarantees, expressed or implied, concerning the accuracy of such
information and disclaim all liability from reliance thereon. You should evaluate the information through your own sources prior to use.
Reference ISO 11014-1


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