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MSDS Material Safety Data Sheet
CAS

108-94-1 68476-86-8 67-64-1 108-88-3

File Name: 108-94-1_68476-86-8_67-64-1_108-88.asp

                                                                                                             Page 1/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

1 Identification of substance
?Product details
?Trade name: 38403 Blenz In
?Article number: 38403
?Manufacturer/Supplier:
SEM Products Inc.
1685 Overview Drive
Rock Hill, SC 29730
803 207 8225
?Information department:
cust_care@semproducts.com : SEM Products,Inc. 1685 Overview Dr. Rock Hill, SC 29730 : phone 1-800-831-
1122, M - TH 7am - 4pm EDT
?Emergency information: 24 HR EMERGENCY CHEMTREC 1-800-424-9300


2 Composition/Data on components
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
108-94-1 cyclohexanone 40 - 60%
Warning: 2.6/3; 3.1.I/4
68476-86-8 Petroleum gases, liquefied, sweetened 13 - 30%
Danger: 2.2/1; 3.5/1B, 3.6/1A
Warning: 2.5/C
67-64-1 acetone 13 - 30%
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
108-88-3 toluene 1.5 - 5%
Danger: 2.6/2; 3.10/1, 3.7/2, 3.9/2
Warning: 3.2/2, 3.8/3
Polyester Plasticizer 1-1.5%
Warning: 3.2/2, 3.3/2A


3 Hazards identification
?Hazard description:

Harmful
Extremely flammable

?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Warning! Pressurized container.
Extremely flammable.
Harmful by inhalation.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Buildup of explosive mixtures possible without sufficient ventilation.
(Contd. on page 2)
USA




DR
Page 2/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 1)
Keep out of the reach of children.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 2
4 Fire = 4
2 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 4
FIRE 4
Reactivity = 0
REACTIVITY 0

?GHS label elements

Danger

2.3/1 - Extremely flammable aerosol.

Warning

3.1/4 - Harmful if inhaled.
?Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well-ventilated area.
?Response:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
?Storage:
Protect from sunlight. Do no expose to temperatures exceeding 50 癈/122 癋.


4 First aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
?After swallowing: If symptoms persist consult doctor.
USA
(Contd. on page 3)




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Page 3/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 2)


5 Fire fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: Mouth respiratory protective device.


6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents


7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
?Information about protection against explosions and fires:
Do not spray on a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
?Storage:
?Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurized containers.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Do not gas tight seal receptacle.
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.


8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
108-94-1 cyclohexanone
(Contd. on page 4)
USA




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Page 4/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 3)
PEL 200 mg/m? 50 ppm
REL 100 mg/m? 25 ppm
Skin
TLV 50 mg/m? 20 ppm
Skin
67-64-1 acetone
PEL 2400 mg/m? 1000 ppm
REL 590 mg/m? 250 ppm
TLV Short-term value: 1782 mg/m? 750 ppm
Long-term value: 1188 mg/m? 500 ppm
BEI
108-88-3 toluene
PEL Short-term value: C 300; 500* ppm
Long-term value: 200 ppm
*10-min peak per 8-hr shift
REL Short-term value: 560 mg/m? 150 ppm
Long-term value: 375 mg/m? 100 ppm
TLV 75 mg/m? 20 ppm
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:


Tightly sealed goggles




9 Physical and chemical properties
?General Information
Aerosol
Form:
(Contd. on page 5)
USA




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Page 5/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 4)

According to product specification
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: < -17癈 (< 1癋)
< -17癈 (< 1癋)
?Flash point:
420癈 (788癋)
?Ignition temperature:
Product is not selfigniting.
?Auto igniting:
In use, may form flammable/explosive vapour-air mixture.
?Danger of explosion:
?Explosion limits:
1.3 Vol %
Lower:
13.0 Vol %
Upper:
?Vapor pressure at 20癈 (68癋): 233 hPa (175 mm Hg)
0.772 g/cm?br> ?Density at 20癈 (68癋):
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
?Solvent content:
96.2 %
Organic solvents:
78.4 %
VOC content:
607.0 g/l / 5.07 lb/gl
3.8 %
?Solids content:



10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.


11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
108-94-1 cyclohexanone
Oral LD50 1535 mg/kg (rat)
Dermal LD50 948 mg/kg (rabbit)
Inhalative LC50/4 h 8000 mg/l (rat)
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
?Primary irritant effect:
?on the skin: No irritant effect.
(Contd. on page 6)
USA




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Page 6/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 5)
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful


12 Ecological information
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.


13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.


14 Transport information
?DOT regulations:




2.1
?Hazard class:
UN1950
?Identification number:
-
?Packing group:
?Proper shipping name (technical name): AEROSOLS, flammable
2.1
?Label
?Land transport TDG (Canada) and ADR/RID (Europe):




2 5F Gases
?Hazard class:
1950
?UN-Number:
-
?Packaging group:
2.1
?Label:
(Contd. on page 7)
USA




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Page 7/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 6)

1950 AEROSOLS
?Description of goods:
?Maritime transport IMDG:




2.1
?IMDG Class:
1950
?UN Number:
2.1
?Label
-
?Packaging group:
F-D,S-U
?EMS Number:
No
?Marine pollutant:
AEROSOLS
?Propper shipping name:
?Air transport ICAO-TI and IATA-DGR:




2.1
?ICAO/IATA Class:
1950
?UN/ID Number:
2.1
?Label
-
?Packaging group:
AEROSOLS, flammable
?Propper shipping name:
?UN "Model Regulation": UN1950, AEROSOLS, 2.1


15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
108-88-3 toluene
?TSCA (Toxic Substances Control Act):
108-94-1 cyclohexanone
68476-86-8 Petroleum gases, liquefied, sweetened
67-64-1 acetone
108-88-3 toluene
763-69-9 ethyl 3-ethoxypropionate
?Proposition 65
?Chemicals known to cause cancer:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 8)
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Page 8/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 7)
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
108-88-3 toluene
?Cancerogenity categories
?EPA (Environmental Protection Agency)
67-64-1 acetone I
108-88-3 toluene II
?IARC (International Agency for Research on Cancer)
108-94-1 cyclohexanone 3
108-88-3 toluene 3
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
108-94-1 cyclohexanone A3
67-64-1 acetone A4
108-88-3 toluene A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Harmful
Extremely flammable
?Hazard-determining components of labelling:
cyclohexanone
?Risk phrases:
Extremely flammable.
Harmful by inhalation.
?Safety phrases:
Keep in a cool place.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
Use only in well-ventilated areas.
This material and its container must be disposed of as hazardous waste.
?Special labeling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Buildup of explosive mixtures possible without sufficient ventilation.
Keep out of the reach of children.
USA
(Contd. on page 9)




DR
Page 9/9
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/18/2009 Reviewed on 08/17/2009

Trade name: 38403 Blenz In

(Contd. of page 8)


16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
USA




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NAMECAS
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23135-22-0_108-94.asp 23135-22-0 108-94-1
109-99-9_78-93-3_108-94-1.asp 109-99-9 78-93-3 108-94-1
60-51-5_108-94-1.asp 60-51-5 108-94-1
26225-79-6_1330-20-7_108-94-1_100-41.asp 26225-79-6 1330-20-7 108-94-1 100-41-4
109-99-9_108-94-1_9002-86-2_112945-52-5_78-93-3_67-64-1.asp 109-99-9 108-94-1 9002-86-2 112945-52-5 78-93-3 67-64-1
2698-41-1_108-94-1_64742-52-5.asp 2698-41-1 108-94-1 64742-52-5
108-94-1_95-50-1_8002-09-3_71-36-3_1330-20-7_100-41-4.asp 108-94-1 95-50-1 8002-09-3 71-36-3 1330-20-7 100-41-4
109-99-9_78-93-3_108-94-1_67-64-1.asp 109-99-9 78-93-3 108-94-1 67-64-1
107-98-2_123-42-2_108-94-1_8005-02-5.asp 107-98-2 123-42-2 108-94-1 8005-02-5
108-94-1_68476-86-8_67-64-1_108-88.asp 108-94-1 68476-86-8 67-64-1 108-88-3
109-99-9_78-93-3_108-94-1_9002-86-2.asp 109-99-9 78-93-3 108-94-1 9002-86-2
108-94-1_78-59-1.asp 108-94-1 78-59-1
95-47-6_123-86-4_108-65-6_108-94.asp 95-47-6 123-86-4 108-65-6 108-94-1
67-64-1_78-93-3_109-99-9_108-94-1_476-86-8.asp 67-64-1 78-93-3 109-99-9 108-94-1 476-86-8
109-99-9_78-93-3_108-94-1.asp 109-99-9 78-93-3 108-94-1
123-86-4_100-41-4_153519-43-8_1333-86-4_108-94-1_88917-22.asp 123-86-4 100-41-4 153519-43-8 1333-86-4 108-94-1 88917-22-0 64742-95-6 108-65-6 95-63-6
109-99-9_108-94-1_117-81-7_75-56-9.asp 109-99-9 108-94-1 117-81-7 75-56-9
108-88-3_78-93-3_1330-20-7_108-10-1_64-17-5_108-94.asp 108-88-3 78-93-3 1330-20-7 108-10-1 64-17-5 108-94-1
108-94-1.asp 108-94-1
141-78-6_12262-58-7_123-42-2_108-94-1_7722-84.asp 141-78-6 12262-58-7 123-42-2 108-94-1 7722-84-1
78-93-3_108-10-1_74-98-6_75-28-5_13463-67-7_108-94-1_67-64.asp 78-93-3 108-10-1 74-98-6 75-28-5 13463-67-7 108-94-1 67-64-1 108-88-3 25086-48-0 25086-15-1 108-65-6 85-68-7 8052-41-3 21645-51-2 112926-00-8 25068-38-6 63231-60-7 75-01-4
8006-64-2_8000-41-7_108-94-1_5593-70-4_141-78-6_8052-41.asp 8006-64-2 8000-41-7 108-94-1 5593-70-4 141-78-6 8052-41-3
109-99-9_78-93-3_108-94-1.asp 109-99-9 78-93-3 108-94-1
108-94.asp 108-94-1
78-93-3_108-10-1_74-98-6_108-94-1_75-28-5_67-64-1_13463-67.asp 78-93-3 108-10-1 74-98-6 108-94-1 75-28-5 67-64-1 13463-67-7 25086-48-0 108-88-3 25086-15-1 108-65-6 8052-41-3 21645-51-2 112926-00-8 25068-38-6 51274-00-1 63231-60-7 70892-90-9 1333-86-4 100-41-4 75-01-4
108-94-1_67-56-1_91-20-3_71-36-3_111-76-2_141-78-6_1330-20.asp 108-94-1 67-56-1 91-20-3 71-36-3 111-76-2 141-78-6 1330-20-7 108-88-3 67-63-0 123-86-4
109-99-9_67-64-1_108-94-1.asp 109-99-9 67-64-1 108-94-1
108-94-1_68476-86-8_67-64-1_108-88.asp 108-94-1 68476-86-8 67-64-1 108-88-3
76-22-2_108-94-1_95-50-1_8052-41-3.asp 76-22-2 108-94-1 95-50-1 8052-41-3
112-07-2_124-17-4_108-65-6_108-94.asp 112-07-2 124-17-4 108-65-6 108-94-1
78-93-3_67-64-1_108-94-1.asp 78-93-3 67-64-1 108-94-1
106-97-8_108-94-1_95-63-6_74-98-6_1330-20.asp 106-97-8 108-94-1 95-63-6 74-98-6 1330-20-7
64742-49-8_110-43-0_117-81-7_108-94-1_67-63-0_13463-67-7_9004-70.asp 64742-49-8 110-43-0 117-81-7 108-94-1 67-63-0 13463-67-7 9004-70-0 67-64-1 14807-96-6
108-94-1_112-07-2.asp 108-94-1 112-07-2
108-94-1_123-86.asp 108-94-1 123-86-4
108-94-1_112-07-2.asp 108-94-1 112-07-2
109-99-9_108-94-1.asp 109-99-9 108-94-1
108-94-1_1330-20-7_123-86-4_108-65-6.asp 108-94-1 1330-20-7 123-86-4 108-65-6
109-99-9_78-93-3_108-94-1_67-64-1.asp 109-99-9 78-93-3 108-94-1 67-64-1
78-93-3_109-99-9_108-94-1_9002-86-2_67-64-1_476-86-8.asp 78-93-3 109-99-9 108-94-1 9002-86-2 67-64-1 476-86-8
67-64-1_78-93-3_109-99-9_476-86-8_108-94.asp 67-64-1 78-93-3 109-99-9 476-86-8 108-94-1
109-99-9_78-93-3_108-94-1_67-64-1.asp 109-99-9 78-93-3 108-94-1 67-64-1
108-88-3_123-86-4_78-93-3_108-94-1_64-17-5_71-36-3_1330-20-7.asp 108-88-3 123-86-4 78-93-3 108-94-1 64-17-5 71-36-3 1330-20-7
115-10-6_64742-95-6_67-64-1_78-93-3_108-94-1.asp 115-10-6 64742-95-6 67-64-1 78-93-3 108-94-1
108-94-1_63782-90-1_1330-20-7.asp 108-94-1 63782-90-1 1330-20-7
108-94-1_7397-62-8_123-42-2_64742-95-6_95-63-6_25551-13-7.asp 108-94-1 7397-62-8 123-42-2 64742-95-6 95-63-6 25551-13-7
109-99-9_78-93-3_108-94-1_67-64-1.asp 109-99-9 78-93-3 108-94-1 67-64-1
108-94-1_010-00.asp 108-94-1 010-00-7
108-88-3_78-93-3_67-64-1_108-94-1_123-86-4_85-68.asp 108-88-3 78-93-3 67-64-1 108-94-1 123-86-4 85-68-7


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