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MSDS Material Safety Data Sheet
CAS

108-94-1 67-56-1 91-20-3 71-36-3 111-76-2 141-78-6 1330-20-7 108-88-3 67-63-0 123-86-4

File Name: 108-94-1_67-56-1_91-20-3_71-36-3_111-76-2_141-78-6_1330-20.asp

                                          MATERIAL SAFETY DATA SHEET

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1. Product and Company Identification
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Product Name Glass Frost - AC010801
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Mixture
CAS #
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Treatment
Product Use
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Dynamic Paint Products Inc.
Manufacturer
7040 Financial Drive
Mississauga, ON L5N 7H5 CA
Phone: 1-905-812-9319
Emergency Phone: 1-613-996-6666 (CANUTEC)
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LEGEND Health * 2
3
HMIS/NFPA
Flammability 3
Severe 4
2 0
Serious 3
Physical Hazard 0
Moderate 2
Slight 1 Personal Protection
B
Minimal 0
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2. Hazards Identification
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DANGER
Emergency Overview
Flammable liquid - may release vapours that form flammable mixtures at or above the
flash point.
Containers may explode when heated.
EYE AND SKIN IRRITANT.
May cause sensitisation by skin contact.
May cause chronic toxic effects.
Contains a potential teratogen.
Contains material which may cause cancer.


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Potential short term health effects
Eye, Skin contact, Skin absorption, Inhalation, Ingestion.
Routes of exposure
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Can cause severe eye irritation.
Eyes
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Contact with skin can cause irritation and allergic reaction (sensitization) in some
Skin
individuals.
May be absorbed through the skin.
ACGIH - Threshold Limit Values - Skin Notations
Cyclohexanone 108-94-1 Skin - potential significant contribution to overall exposure by the cutaneous route
Methyl alcohol 67-56-1 Skin - potential significant contribution to overall exposure by the cutaneous route
Naphthalene 91-20-3 Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH - Pocket Guide - Skin Notations
Cyclohexanone 108-94-1 Potential for dermal absorption
Methyl alcohol 67-56-1 Potential for dermal absorption
N-Butyl alcohol 71-36-3 Potential for dermal absorption
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation
nervous system effects (headache, dizziness).
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Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Ingestion
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Blood. Eyes. Kidney. Liver. Respiratory system. Skin.
Target organs
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Prolonged or repeated exposure can cause drying, defatting and dermatitis.
Chronic effects
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Symptoms may include redness, oedema, drying, defatting and cracking of the skin.
Signs and symptoms
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.




#13773 Page 1 of 9 Issue date 11-Aug-2009
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3. Composition/Information on Ingredients
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Ingredient(s) CAS # Percent
Ethylene glycol monobutyl ether 111-76-2 0.5 - 1.5
Methyl alcohol 67-56-1 1-5
Naphthalene 91-20-3 10 - 30
Ethylacetate 141-78-6 10 - 30
Cyclohexanone 108-94-1 10 - 30
Xylene 1330-20-7 15 - 40
Toluene 108-88-3 15 - 40
N-Butyl alcohol 71-36-3 3-7
Isopropanol 67-63-0 3-7
N-Butyl acetate 123-86-4 7 - 13
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4. First Aid Measures
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First aid procedures
Immediately flush with cool water. Remove contact lenses, if applicable, and continue
Eye contact
flushing for 15 minutes. Obtain medical attention immediately.
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Flush with cool water. Wash with soap and water. Obtain medical attention if irritation
Skin contact
persists.
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If symptoms develop move victim to fresh air. If symptoms persist, obtain medical
Inhalation
attention.
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Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is
Ingestion
convulsing. Obtain medical attention.
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Symptoms may be delayed.
Notes to physician
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Keep away from sources of ignition. No smoking. If you feel unwell, seek medical advice
General advice
(show the label where possible). Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of
children.
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5. Fire-fighting Measures
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Flammable by WHMIS criteria.
Flammable properties
Vapours may travel to a source of ignition and flash back.
Containers may explode when heated.
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Extinguishing media
Dry chemical. Foam. Carbon dioxide.
Suitable extinguishing media
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Unsuitable extinguishing media Not available
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Protection of firefighters
Not available
Specific hazards arising from
the chemical
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Firefighters should wear full protective clothing including self contained breathing
Protective equipment for
apparatus.
firefighers
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May include and are not limited to: Oxides of carbon.
Hazardous combustion products
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Explosion data
Not available
Sensitivity to mechanical
impact
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Not available
Sensitivity to static discharge
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6. Accidental Release Measures
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Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
Personal precautions
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.

#13773 Page 2 of 9 Issue date 11-Aug-2009
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Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
Methods for containment
basements or confined areas.
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Remove sources of ignition. Before attempting clean up, refer to hazard data given
Methods for cleaning up
above. Small spills may be absorbed with non-reactive absorbent and placed in
suitable, covered, labelled containers. Prevent large spills from entering sewers or
waterways. Contact emergency services and supplier for advice. Never return spills in
original containers for re-use.
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7. Handling and Storage
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Use according to package label instructions. Avoid breathing vapours or mists of this
Handling
product.
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Keep out of reach of children. Store in a closed container away from incompatible
Storage
materials. Keep away from heat, open flames or other sources of ignition.
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8. Exposure Controls / Personal Protection
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Exposure limit values
Ingredient(s) Exposure limit values

Cyclohexanone ACGIH-TLV
TWA: 20 ppm
STEL: 50 ppm

Ethylacetate ACGIH-TLV
TWA: 400 ppm

Ethylene glycol monobutyl ether ACGIH-TLV
TWA: 20 ppm

Isopropanol ACGIH-TLV
TWA: 200 ppm
STEL: 400 ppm

Methyl alcohol ACGIH-TLV
TWA: 200 ppm
STEL: 250 ppm

Naphthalene ACGIH-TLV
TWA: 10 ppm
STEL: 15 ppm

N-Butyl acetate ACGIH-TLV
TWA: 150 ppm
STEL: 200 ppm

N-Butyl alcohol ACGIH-TLV
TWA: 20 ppm

Toluene ACGIH-TLV
TWA: 20 ppm
Skin: 50 ppm
Xylene ACGIH-TLV
TWA: 100 ppm
STEL: 150 ppm
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Use only under good ventilation conditions or with respiratory protection.
Engineering controls
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Personal protective equipment
Wear safety glasses with side shields.
Eye/Face protection
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Rubber gloves. Confirm with a reputable supplier first.
Hand protection
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As required by employer code.
Skin and body protection

#13773 Page 3 of 9 Issue date 11-Aug-2009
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Not normally required if good ventilation is maintained and exposure guidelines are not
Respiratory protection
exceeded. Where exposure guideline levels may be exceeded, use an approved NIOSH
respirator.
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General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands before breaks and immediately after handling the product.
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9. Physical and Chemical Properties
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Liquid
Appearance
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Milky.
Colour
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Liquid
Form
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Hydrocarbon
Odour
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Not available
Odour threshold
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Liquid
Physical state
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Not available
pH
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Not available
Freezing point
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110 癈 (230.00 癋)
Boiling point
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Not available
Pour point
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6 癈 (42.80 癋) TCC
Flash point
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> 1 (Ether = 1)
Evaporation Rate
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1.3
Flammability limits in air, lower, %
by volume
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Flammability Limits in Air, Upper, % 6.7
by Volume
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7.6 mmHg
Vapour pressure
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> 1 (Air = 1)
Vapour density
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1.22 (H2O = 1)
Specific gravity
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Not available
Octanol/water coefficient
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Negligible
Solubility (H2O)
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Not available
Auto-ignition temperature
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100
VOC (Weight %)
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Water thin
Viscosity
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10. Stability and Reactivity
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Stable under recommended storage conditions.
Chemical stability
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Do not mix with other chemicals. Avoid high temperatures.
Conditions to avoid
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Caustics. Acids. Oxidizers. Metals.
Incompatible materials
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Hazardous decomposition products May include and are not limited to: Oxides of carbon.
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Hazardous polymerisation does not occur.
Possibility of hazardous reactions




#13773 Page 4 of 9 Issue date 11-Aug-2009
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11. Toxicological Information
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Component analysis - LC50
Ingredient(s) LC50

Cyclohexanone 2639 ppm rat; 10.7 mg/l/4h rat
Ethylacetate Not available
Ethylene glycol monobutyl ether 2.21 mg/l/4h rat
Isopropanol 16970 mg/l/4h rat
Methyl alcohol 83.2 mg/l/4h rat
Naphthalene Not available
N-Butyl acetate 2000 ppm rat; 2000 mg/l/4h rat
N-Butyl alcohol 17.7 mg/l/4h rat
Toluene 12.5 mg/l/4h rat
Xylene 5000 mg/l/4h rat
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Component analysis - Oral LD50
Ingredient(s) LD50

Cyclohexanone 800 mg/kg rat
Ethylacetate 5620 mg/kg rat; 4100 mg/kg mouse; 4935 mg/kg rabbit; 5500
mg/kg guinea pig
Ethylene glycol monobutyl ether 470 mg/kg rat; 320 mg/kg rabbit
Isopropanol 4396 mg/kg rat
Methyl alcohol 5628 mg/kg rat; 7300 mg/kg mouse; 14200 mg/kg rabbit; 7600
mg/kg Monkey
Naphthalene 490 mg/kg rat; 533 mg/kg mouse; 1200 mg/day guinea pig
N-Butyl acetate 10770 mg/kg rat; 7100 mg/kg mouse; 7400 mg/kg rabbit
N-Butyl alcohol 790 mg/kg rat
Toluene 636 mg/kg rat
Xylene 4300 mg/kg rat
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Effects of acute exposure
Can cause severe eye irritation.
Eye
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Contact with skin can cause irritation and allergic reaction (sensitization) in some
Skin
individuals.
May be absorbed through the skin.
ACGIH - Threshold Limit Values - Skin Notations
Cyclohexanone 108-94-1 Skin - potential significant contribution to overall exposure by the cutaneous route
Methyl alcohol 67-56-1 Skin - potential significant contribution to overall exposure by the cutaneous route
Naphthalene 91-20-3 Skin - potential significant contribution to overall exposure by the cutaneous route
NIOSH - Pocket Guide - Skin Notations
Cyclohexanone 108-94-1 Potential for dermal absorption
Methyl alcohol 67-56-1 Potential for dermal absorption
N-Butyl alcohol 71-36-3 Potential for dermal absorption
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation
nervous system effects (headache, dizziness).
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Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Ingestion
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Contains a potential skin sensitizer.
Sensitisation
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Ethylene glycol monobutyl ether may be absorbed through the skin in toxic amounts if
Chronic effects
contact is repeated and prolonged; may cause blood damage based on published data.
These effects have not been observed in humans.




#13773 Page 5 of 9 Issue date 11-Aug-2009
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Contains a potential carcinogen.
Carcinogenicity
ACGIH - Threshold Limit Values - Carcinogens
Cyclohexanone 108-94-1 A3 - Confirmed animal carcinogen with unknown relevance to humans.
Isopropanol 67-63-0 A4 - Not Classifiable as a Human Carcinogen
Naphthalene 91-20-3 A4 - Not Classifiable as a Human Carcinogen
Toluene 108-88-3 A4 - Not Classifiable as a Human Carcinogen
Xylene 1330-20-7 A4 - Not Classifiable as a Human Carcinogen
IARC - Group 2B (Possibly Carcinogenic to Humans)
Naphthalene 91-20-3 Monograph 82 [2002]
IARC - Group 3 (Not Classifiable)
Cyclohexanone 108-94-1 Monograph 71 [1999], Monograph 47 [1989]
Isopropanol 67-63-0 Monograph 71 [1999], Supplement 7 [1987], Monograph 15 [1977]
Toluene 108-88-3 Monograph 71 [1999], Monograph 47 [1989]
Xylene 1330-20-7 Monograph 71 [1999], Monograph 47 [1989]
U.S. - California - Proposition 65 - Carcinogens List
Naphthalene 91-20-3 carcinogen, initial date 4/19/02
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Non-hazardous by WHMIS criteria.
Mutagenicity
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Non-hazardous by WHMIS criteria.
Reproductive effects
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Contains potential teratogens.
Teratogenicity
Methanol has produced teratogenic effects in mice exposed by inhalation to high
concentrations that did not produce significant maternal toxicity.
Toluene (benzene, methyl-) has caused fetotoxicity (reduced fetal weight), behavioural
effects (effects on learning and memory) and hearing loss (in males). These effects
have been observed in the offspring of rats exposed by inhalation to 1200 or 1800 ppm
toluene. These effects were observed in the absence of maternal toxicity.
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Not available
Synergistic Materials


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12. Ecological Information




#13773 Page 6 of 9 Issue date 11-Aug-2009
Components of this product have been identified as having potential environmental
Ecotoxicity
concerns.
Ecotoxicity - Freshwater Algae Data
Cyclohexanone 108-94-1 96 Hr EC50 Chlorella vulgaris: 20 mg/L
Ethylacetate 141-78-6 48 Hr EC50 Scenedesmus subspicatus: 3300 mg/L
Isopropanol 67-63-0 96 Hr EC50 Scenedesmus subspicatus: >1000 mg/L; 72 Hr EC50 Scenedesmus
subspicatus: >1000 mg/L
Naphthalene 91-20-3 96 Hr EC50 Skeletonema costatum: 0.4 mg/L
N-Butyl acetate 123-86-4 96 Hr EC50 Scenedesmus subspicatus: 320 mg/L; 72 Hr EC50 Scenedesmus
subspicatus: 674.7 mg/L
N-Butyl alcohol 71-36-3 96 Hr EC50 Scenedesmus subspicatus: >500 mg/L; 72 Hr EC50 Scenedesmus
subspicatus: >500 mg/L
Toluene 108-88-3 96 Hr EC50 Selenastrum capricornutum: >433 mg/L
Ecotoxicity - Freshwater Fish Species Data
Cyclohexanone 108-94-1 96 Hr LC50 Pimephales promelas: 481-578 mg/L [flow-through]; 96 Hr LC50 Pimephales
promelas:8.9 mg/L
Ethylacetate 141-78-6 96 Hr LC50 Pimephales promelas: 220-250 mg/L [flow-through]; 96 Hr LC50
Oncorhynchus mykiss:484 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus
mykiss:352-500 mg/L [semi-static]
Isopropanol 67-63-0 96 Hr LC50 Pimephales promelas: 9640 mg/L [flow-through]; 96 Hr LC50 Pimephales
promelas:11130 mg/L [static]; 96 Hr LC50 Lepomis macrochirus:>1400000 g/L
Methyl alcohol 67-56-1 96 Hr LC50 Pimephales promelas: 28200 mg/L [flow-through]; 96 Hr LC50 Pimephales
promelas:>100 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss:19500-20700 mg/L
[flow-through]; 96 Hr LC50 Oncorhynchus mykiss:18-20 ml/L [static]; 96 Hr LC50
Lepomis macrochirus:13500-17600 mg/L [flow-through]
Naphthalene 91-20-3 96 Hr LC50 Pimephales promelas: 5.74-6.44 mg/L [flow-through]; 96 Hr LC50
Oncorhynchus mykiss:1.6 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus
mykiss:0.91-2.82 mg/L [static]; 96 Hr LC50 Pimephales promelas:1.99 mg/L [static]; 96
Hr LC50 Lepomis macrochirus:31.0265 mg/L [static]
N-Butyl acetate 123-86-4 96 Hr LC50 Pimephales promelas: 17-19 mg/L [flow-through]; 96 Hr LC50 Lepomis
macrochirus:100 mg/L [static]; 96 Hr LC50 Leuciscus idus:62 mg/L [static]
N-Butyl alcohol 71-36-3 96 Hr LC50 Pimephales promelas: 1730-1910 mg/L [static]; 96 Hr LC50 Pimephales
promelas:1740 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus:100000-500000
g/L [static]; 96 Hr LC50 Pimephales promelas:1910000 g/L [static]
Toluene 108-88-3 96 Hr LC50 Pimephales promelas: 15.22-19.05 mg/L [flow-through] (1 day old); 96 Hr
LC50 Pimephales promelas:12.6 mg/L [static]; 96 Hr LC50 Oncorhynchus
mykiss:5.89-7.81 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:14.1-17.16
mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss:5.8 mg/L [semi-static]; 96 Hr LC50
Lepomis macrochirus:11.0-15.0 mg/L [static]; 96 Hr LC50 Oryzias latipes:54 mg/L
[static]; 96 Hr LC50 Poecilia reticulata:28.2 mg/L [semi-static]; 96 Hr LC50 Poecilia
reticulata:50.87-70.
Xylene 1330-20-7 96 Hr LC50 Pimephales promelas: 13.4 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus
mykiss:2.661-4.093 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss:13.5-17.3 mg/L; 96
Hr LC50 Lepomis macrochirus:13.1-16.5 mg/L [flow-through]; 96 Hr LC50 Lepomis
macrochirus:19 mg/L; 96 Hr LC50 Lepomis macrochirus:7.711-9.591 mg/L [static]; 96 Hr
LC50 Pimephales promelas:23.53-29.97 mg/L [static]; 96 Hr LC50 Cyprinus carpio:780
mg/L [semi-static]; 96 Hr LC50 Cyprinus carpio:>780 mg/L; 96 Hr LC50 Poecilia
reticulata:30.26-40.
Ecotoxicity - Microtox Data
Cyclohexanone 108-94-1 5 min EC50 Photobacterium phosphoreum: 25 mg/L; 10 min EC50 Photobacterium
phosphoreum: 21.3 mg/L; 5 min EC50 Photobacterium phosphoreum: 18.5 mg/L
Ethylacetate 141-78-6 5 min EC50 Photobacterium phosphoreum: 1180 mg/L; 15 min EC50 Photobacterium
phosphoreum: 5870 mg/L; 2 Hr EC50 Pseudomonas fluorescens: 7400 mg/L; 15 min
EC50 Pseudomonas fluorescens: 1500 mg/L
Isopropanol 67-63-0 5 min EC50 Photobacterium phosphoreum: 35390 mg/L
Methyl alcohol 67-56-1 5 min EC50 Photobacterium phosphoreum: 43000 mg/L; 15 min EC50 Photobacterium
phosphoreum: 40000 mg/L; 25 min EC50 Photobacterium phosphoreum: 39000 mg/L
Naphthalene 91-20-3 30 min EC50 Photobacterium phosphoreum: 0.93 mg/L; 18 Hr EC50 Pseudomonas
putida: >20 mg/L
N-Butyl acetate 123-86-4 5 min EC50 Photobacterium phosphoreum: 70.0 mg/L; 15 min EC50 Photobacterium
phosphoreum: 82.2 mg/L; 30 min EC50 Photobacterium phosphoreum: 98.9 mg/L; 18 Hr
EC50 Pseudomonas putida: 959 mg/L
N-Butyl alcohol 71-36-3 5 min EC50 Photobacterium phosphoreum: 2041.4 mg/L; 30 min EC50 Photobacterium
phosphoreum: 2186 mg/L; 17 Hr EC50 Pseudomonas putida: 4400 mg/L; 24 Hr EC50
Aerobic heterotroph: 3980 mg/L
Toluene 108-88-3 30 min EC50 Photobacterium phosphoreum: 19.7 mg/L
Xylene 1330-20-7 24 hr EC50 Photobacterium phosphoreum: 0.0084 mg/L
Ecotoxicity - Water Flea Data
Cyclohexanone 108-94-1 48 Hr EC50 water flea: 820 mg/L; 48 Hr EC50 Daphnia magna: 800 mg/L
Ethylacetate 141-78-6 48 Hr EC50 Daphnia magna: 717 mg/L
Isopropanol 67-63-0 48 Hr EC50 Daphnia magna: 13299 mg/L
Naphthalene 91-20-3 48 Hr EC50 water flea: 2.16 mg/L
N-Butyl acetate 123-86-4 48 Hr EC50 water flea: 44 mg/L
N-Butyl alcohol 71-36-3 48 Hr EC50 Daphnia magna: 1983 mg/L



#13773 Page 7 of 9 Issue date 11-Aug-2009
Toluene 108-88-3 48 Hr EC50 water flea: 11.3 mg/L; 48 Hr EC50 water flea: 310 mg/L; 48 Hr EC50
Daphnia magna: 11.3 mg/L
Xylene 1330-20-7 48 Hr EC50 water flea: 3.82 mg/L; 48 Hr LC50 Gammarus lacustris: 0.6 mg/L
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Harmful to aquatic life.
Environmental effects
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Not available
Aquatic toxicity
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Not available
Persistence and degradability
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Not available
Bioaccumulation/accumulation
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Not available
Partition coefficient
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Not available
Mobility in environmental media
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Not available
Chemical fate information
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Not available
Other adverse effects
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13. Disposal Considerations
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Not available
Waste codes
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Review federal, provincial, and local government requirements prior to disposal.
Disposal instructions
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Not available
Waste from residues / unused
products
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Not available
Contaminated packaging
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14. Transport Information
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Transportation of Dangerous Goods (TDG - Canada)
Basic shipping requirements:
PAINT
Proper shipping name
3
Hazard class
1263
UN number
II
Packing group
Additional information:
59
Special provisions




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15. Regulatory Information
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This product has been classified in accordance with the hazard criteria of the Controlled
Canadian federal regulations
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - CEPA - High Priority Chemicals as Identified by DSL Categorization
Naphthalene 91-20-3 Batch 1, published February 3, 2007
Canada - CEPA - Schedule I - List of Toxic Substances
Naphthalene 91-20-3 [SOR/2000-109]
Canada - WHMIS - Ingredient Disclosure List
Cyclohexanone 108-94-1 0.1 %
Ethylacetate 141-78-6 1%
Isopropanol 67-63-0 1%
Methyl alcohol 67-56-1 1%
Naphthalene 91-20-3 1%
N-Butyl acetate 123-86-4 1%
N-Butyl alcohol 71-36-3 1%
Toluene 108-88-3 1%
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Class B - Division 2 - Flammable Liquid, Class D - Division 2A, 2B
WHMIS classification
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Controlled
WHMIS status




#13773 Page 8 of 9 Issue date 11-Aug-2009
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WHMIS labeling




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Inventory Status
Country(s) or region Inventory Name On Inventory (Yes/No)*
Canada Domestic Substances List (DSL) Yes
Non-Domestic Substances List (NDSL) No
Canada
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing
country(s)
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16. Other Information
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Information contained herein was obtained from sources considered technically accurate
Disclaimer
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
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11-Aug-2009
Issue date
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15-Aug-2009
Effective Date
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15-Aug-2012
Expiry Date
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Dell Tech Laboratories Ltd. (519) 858-5021
Prepared by
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For an updated MSDS, please contact the supplier/manufacturer listed on the first
Other Information
page of the document.




#13773 Page 9 of 9 Issue date 11-Aug-2009

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NAMECAS
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