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MSDS Material Safety Data Sheet
CAS

106-97-8 108-94-1 95-63-6 74-98-6 1330-20-7

File Name: 106-97-8_108-94-1_95-63-6_74-98-6_1330-20.asp

                                      MATERIAL SAFETY DATA SHEET

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1. Product and Company Identification
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957-004
Product number
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Product name Instant Screen Opener
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28-Dec-2009
Effective date
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Sprayway, Inc.
Claire Manufacturing Co.
Company information
500 Vista Ave.
484
Addison, IL 60101 United States
United States
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General Assistance 630-543-7600
Company phone
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800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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06
Version #
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18-Mar-2009
Supersedes date
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2. Hazards Identification
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FLAMMABLE
Emergency overview
CONTENTS UNDER PRESSURE. Aerosol. Will be easily ignited by heat, spark or
flames.
Harmful in contact with eyes. Irritating to skin. Irritating to respiratory system. Prolonged
exposure may cause chronic effects.
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Potential health effects
Inhalation. Ingestion. Skin contact. Eye contact.
Routes of exposure
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Contact may irritate or burn eyes. Eye contact may result in corneal injury.
Eyes
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Irritating to skin. Prolonged or repeated contact can result in defatting and drying of the
Skin
skin which may result in skin irritation and dermatitis (rash).
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
Irritating to respiratory system. Prolonged inhalation may be harmful.
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Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage.
Ingestion
Components of the product may be absorbed into the body by ingestion.
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Kidney. Blood. Central nervous system. Liver. Lungs.
Target organs
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Unconsciousness. Conjunctiva. Liver injury may occur. Kidney injury may occur. May
Chronic effects
cause central nervous system disorder (e.g., narcosis involving a loss of coordination,
weakness, fatigue, mental confusion, and blurred vision) and/or damage. May cause
delayed lung damage.
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Discomfort in the chest. Corneal damage. Narcosis. Cyanosis. Liver enlargement.
Signs and symptoms
Jaundice. Conjunctivitis. Defatting of the skin. Irritation.
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3. Composition / Information on Ingredients
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Components CAS # Percent
n-Butane 106-97-8 20 - 30
Cyclohexanone 108-94-1 15 - 20
1,2,4-Trimethyl Benzene 95-63-6 15 - 20
Propane 74-98-6 8 - 10
Xylene 1330-20-7 1-3
Non-hazardous and other components below reportable levels 20 - 40
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
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Remove and isolate contaminated clothing and shoes. Wash off with warm water and
Skin contact
soap. Get medical attention if irritation develops or persists.
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Product #: 957-004
Instant Screen Opener 28-DEC-2009
Revision date: Print date: 28-DEC-2009
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Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth
Inhalation
method if victim inhaled the substance. Induce artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device.
Get medical attention immediately.
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If material is ingested, immediately contact a poison control center. Have victim rinse
Ingestion
mouth thoroughly with water. Do not induce vomiting without advice from poison control
center. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.
Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
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5. Fire Fighting Measures
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Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may
Flammable properties
cause fire or explosion hazard.
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Extinguishing media
Foam. Dry chemical. Carbon dioxide (CO2). Do not use water jet.
Suitable extinguishing media
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Protection of firefighters
Fire may produce irritating, corrosive and/or toxic gases.
Specific hazards arising from
the chemical
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In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing,
Protective equipment and
including helmet, self-contained positive pressure or pressure demand breathing
precautions for firefighters
apparatus, protective clothing and face mask. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire, use unmanned hose holders or
monitor nozzles; if this is impossible, withdraw from area and let fire burn.
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6. Accidental Release Measures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable. Stop the flow of material, if this is without risk. Prevent entry into
waterways, sewers, basements or confined areas.
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Should not be released into the environment. Use a non-combustible material like
Methods for cleaning up
vermiculite, sand or earth to soak up the product and place into a container for later
disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
Handling
an open flame, heat or other sources of ignition. Do not use if spray button is missing or
defective. Use only with adequate ventilation. Do not get this material in contact with
eyes. Do not get this material in contact with skin. Avoid prolonged exposure.
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Level 3 Aerosol.
Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Keep away from heat, sparks, and
flame. Avoid exposure to long periods of sunlight. Store in cool place. Keep in an area
equipped with sprinklers. Keep out of the reach of children. Do not store, incinerate, or
heat this material above 120 degrees Fahrenheit.
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
n-Butane 106-97-8 1000 ppm Not established Not established
Cyclohexanone 108-94-1 20 ppm 50 ppm Not established
1,2,4-Trimethyl Benzene 95-63-6 25 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
Xylene 1330-20-7 100 ppm 150 ppm Not established
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Product #: 957-004
Instant Screen Opener 28-DEC-2009
Revision date: Print date: 28-DEC-2009
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OSHA
Components CAS # TWA STEL Ceiling
Cyclohexanone 108-94-1 50 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
Xylene 1330-20-7 100 ppm Not established Not established
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant
Skin protection
clothing.
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Wear positive pressure self-contained breathing apparatus (SCBA). If permissible levels
Respiratory protection
are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied
respirator.
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9. Physical & Chemical Properties
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Not available
Appearance
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186.8 癋 (86.1 癈) estimated
Boiling point
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Colorless.
Color
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43.1279 kJ/g estimated
Flammability (HOC)
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Yes
Flash back
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-156 癋 (-104.4 癈) Propellant
Flash point
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Aerosol.
Form
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Solvent.
Odor
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Not applicable
pH
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Liquid.
Physical state
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50 - 65 psig @ 70F
Pressure
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None
Solubility
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0.7456 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Risk of ignition.
Chemical stability
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Heat, flames and sparks.
Conditions to avoid
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Hazardous decomposition products No hazardous decomposition products are known.
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11. Toxicological Information
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Acute LD50: 2473 mg/kg estimated, Rat, Dermal
Acute effects
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
1,2,4-Trimethyl Benzene 95-63-6 Inhalation LC50 Rat 18 g/m3 4 h; Oral LD50 Rat 3400 mg/kg; Dermal LD50 Rabbit
>3160 mg/kg
Cyclohexanone 108-94-1 Inhalation LC50 Rat 10.7 mg/L 4 h; Inhalation LC50 Rat 8000 ppm 4 h; Oral LD50
Rat 800 mg/kg; Dermal LD50 Rabbit 948 mg/kg
n-Butane 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h
Propane 74-98-6 Inhalation LC50 Rat 658 mg/L 4 h
Xylene 1330-20-7 Inhalation LC50 Rat 5000 ppm 4 h; Inhalation LC50 Rat 47635 mg/L 4 h; Oral LD50
Rat 4300 mg/kg; Dermal LD50 Rabbit >1700 mg/kg
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Not expected to be hazardous by OSHA criteria.
Sensitization
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Components in this product have been shown to cause birth defects and reproductive
Reproductive effects
disorders in laboratory animals.
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Not expected to be hazardous by OSHA criteria. Components in this product have been
Teratogenicity
shown to cause birth defects and reproductive disorders in laboratory animals.




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Product #: 957-004
Instant Screen Opener 28-DEC-2009
Revision date: Print date: 28-DEC-2009
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12. Ecological Information
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Components of this product are hazardous to aquatic life.
Ecotoxicity

LC50 17.16 mg/L, Fish, 96.00 Hours,
EC50 12.48 mg/L, Daphnia, 48.00 Hours,
IC50 392 mg/L, Algae, 72.00 Hours,
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13. Disposal Considerations
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D001: Waste Flammable material with a flash point <140 F
Waste codes
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Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material
Disposal instructions
and its container at hazardous or special waste collection point. Do not allow this material
to drain into sewers/water supplies. If discarded, this product is considered a RCRA
ignitable waste, D001. Dispose in accordance with all applicable regulations.
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
5F
Item
None
Labels required
2
Transport Category
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IATA
Basic shipping requirements:
Aerosols, flammable
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1
Labels required


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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
1,2,4-Trimethyl Benzene 95-63-6 1.0 % de minimis concentration
Xylene 1330-20-7 1.0 % de minimis concentration
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical


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Product #: 957-004
Instant Screen Opener 28-DEC-2009
Revision date: Print date: 28-DEC-2009
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CERCLA (Superfund) reportable quantity
Cyclohexanone: 5000.0000
Xylene: 100.0000
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of New and Existing Chemicals (EINECS) No
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
1,2,4-Trimethyl Benzene 95-63-6 Environmental hazard
Cyclohexanone 108-94-1 Environmental hazard
n-Butane 106-97-8 Present
Propane 74-98-6 Present
Xylene 1330-20-7 Environmental hazard
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16. Other Information
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HMIS?is a registered trade and service mark of the NPCA.
Further information
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Health: 2*
HMIS?ratings
Flammability: 4
Physical hazard: 0
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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This document has undergone significant changes and should be reviewed in its entirety.
MSDS sections updated
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Regulatory Compliance
Prepared by




Product name: Instant Screen Opener MSDS US
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Product #: 957-004
Instant Screen Opener 28-DEC-2009
Revision date: Print date: 28-DEC-2009

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NAMECAS
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