Material Safety Data Sheet MSDS #23-C
Date Printed 09/26/02
Product: HAVAFLEX TA-117 Q.C. (PART "B")
1. Chemical Product and Company Identification
Trade Name Havaflex TA-117 Q.C. (Part "B")
Synonyms None
Manufacturer
AMETEK, INC., CHEMICAL PRODUCTS DIVISION
HAVEG SITE
900 Greenbank Road 24 HOUR EMERGENCY ASSISTANCE: CHEMTREC
Wilmington, DELAWARE 19808 (800) 424-9300
Phone Product Information (302) 995-0400
Date September 26, 2002
Description
No Hazard Rating is available for this Product
2. Composition and Information on Ingredients
Ingredient(s) CAS Number Percent (W/W)
Phenolic Resin 9003-85-4 Proprietary Information
Phenol (Free) 108-95-2 <4.3
Formaldehyde (Free) 50-00-0 0.17
Ethyl Alcohol 64-17-5 Proprietary Information
Amidoamine Resin 64754990 Proprietary Information
Cycloaliphatic Amine Mixture Proprietary Information
Polythioether Polymer Not Assigned Proprietary Information
Antimony Trioxide 1309-64-4 Proprietary Information
Treated Amorphous Fumed Silica 67762-90-7 Proprietary Information
Potassium Alumina Silicate 12001-26-2 Proprietary Information
Cyclohexanone 108-94-1 <1
Isophoronediamine 2855-13-2 Proprietary Information
Diethylene Triamine 111-40-1 Proprietary Information
Aminoethylpiperazine 140-31-8 Proprietary Information
Arsenic 7440-38-2 <0.01
Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
Lead 7439-92-1 <0.02
Crystalline Silica 14808-6-7 3.6 ?4.8
Thiodiglycol 000111-48-8 Proprietary Information
Carbon Black 1333-86-4 <1
3. Hazard Identification
Emergency Overview:
Gray-colored, viscous, but pourable material, slight odor. Keep container tightly sealed
when not in use and do not breathe vapors unnecessarily.
Effects of Overexposure:
Eye Contact: May cause slight eye irritation.
Skin Contact: Prolonged or repeated exposure may cause skin irritation.
Inhalation: Excessive exposure may cause irritation to the upper respiratory tract.
Ingestion: Not expected to be a source of exposure in normal industrial use.
Primary routes of entry:
Skin contact, inhalation, ingestion & eye contact.
Carcinogenicity Information:
This product contains crystalline silica which is listed by IARC and NTP as a carcinogen, but it is
not regulated by OSHA. See Section 11 for additional details.
4. First Aid Information
Eye Contact: Flush eyes immediately with large amounts of water for at least 15 minutes holding eyelids open
while flushing. Seek medical attention immediately.
Skin Contact: Remove contaminated clothing. Wash contaminated skin in flowing water or shower.
Inhalation: Remove person from source of exposure to fresh air and then seek medical attention immediately.
Ingestion: Seek medical attention immediately.
5. Fire Fighting Measures
Flash Point: 188篎, ASTM Method, D 92, Cleveland Open Cup
Lower Explosive Limit (%): N.D.
Upper Explosive Limit (%): N.D.
Autoignition Temperature: N.D.
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Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
Extinguishing Media: Foam, carbon dioxide or dry chemical.
Unusual Fire & Explosion Hazards: Under fire conditions polymers decompose. The smoke may contain
unidentified toxic and/or irritating compounds. Hazardous combustion products may include and are
not limited to: carbon monoxide, carbon dioxide.
Fire Fighting Instructions: Wear full fire fighting protective equipment including self-contained breathing
apparatus.
6. Accidental Release Measures
Steps to be taken in case material is released or spilled:
Use appropriate safety equipment. Absorb spills with sand or other non-combustible absorbent and
place in waste containers.
Dispose of all waste materials according to federal, state, and local environmental regulations.
7. Handling and Storage
Handling
Avoid unnecessary skin contact. Handle with care.
Handle in well-ventilated area.
Use safety glasses with sideshields and impervious gloves whenever handling this
material.
Allow material to come to room temperature for 24 hours before mixing.
Storage
Store material in tightly closed containers at 40篎 or lower.
8. Exposure Controls and Personal Protection
ENGINEERING CONTROLS:
Ventilation:
Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be
necessary for some operations.
Respiratory Protection:
If respiratory irritation is experienced, use a NIOSH approved air-purifying respirator.
Eye Protection:
Wear safety glasses with side shields or chemical safety goggles.
Protective Clothing:
Use protective clothing and gloves impervious to this material.
Other Protective Equipment:
Eye wash fountain, safety shower.
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Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
Hygienic Practices:
Use good personal hygiene practices.
EXPOSURE LIMITS:
Phenolic Resin
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Phenol (Free)
PEL (OSHA) 5 ppm (skin)
TLV (ACGIH) 5 ppm (skin)
Formaldehyde (Free)
PEL (OSHA) 0.75 ppm
STEL 2 ppm
TLV (ACGIH) (C) 0.3 ppm
Ethyl Alcohol
PEL (OSHA) 1,000 ppm
TLV (ACGIH) 1,000 ppm
Amidoamine Resin
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Cycloaliphatic Amine
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Polythioether Polymer
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Antimony Trioxide
PEL (OSHA) 0.5 mg/m3
PEL as Sb
TLV (ACGIH) 0.5 mg/m3 as Sb
Treated Amorphous Fumed Silica
PEL (OSHA) 20 mppcf
TLV (ACGIH) 10mg/m3
Potassium Alumina Silicate
PEL (OSHA) 20 mppcf
TLV (ACGIH) 3 mg/m3
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Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
Cyclohexanone
PEL (OSHA) 25 ppm (skin)
TLV (ACGIH) 25 ppm (skin)
NOTATION A4
Isophoronediamine
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Diethylene Triamine
PEL (OSHA) None
TLV (ACGIH) 1 ppm (skin)
TLV (ACGIH) NIOSH 1 ppm
4 mg/m3 (skin)
Aminoethylpiperazine
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Arsenic
PEL (OSHA) 10 microg/m3
TLV (ACGIH) 0.2 mg/m3
NOTATION Action Limit OSHA 5 microg/m3
Lead
PEL (OSHA) 50 microg/m3
TLV (ACGIH) 0.15 mg/m3
NOTATION Action Limit OSHA 30 microg/m3
Crystalline Silica
PEL (OSHA) 10 mg/m3 ?% SiO2 + 2
TLV (ACGIH) 0.05 mg/m3 (respirable)
Thiodiglycol
PEL (OSHA) N.E.
TLV (ACGIH) N.E.
Carbon Black
PEL (OSHA) 3.5 mg/m3
TLV (ACGIH) 3.5 mg/m3
NOTATION A4
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Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
9. Physical and Chemical Properties
PHYSICAL DATA:
Boiling Point: N.A.
Melting Point: N.A.
Solubility in Water: Insoluble
Vapor Pressure: N.A.
Vapor Density: N.A.
Specific Gravity: 1.158
Color: Gray
Odor: Slight odor
Physical State: Highly viscous, but pourable material
10. Stability and Reactivity
Chemical Stability ?Product is stable at normal temperature and storage conditions, however,
excessive heating over long periods of time will degrade the resin.
Incompatibilities ?Mineral acids and strong oxidizing agents.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Hazardous Decomposition Products: Under fire conditions polymers decompose. The smoke may contain
unidentified toxic and/or irritating compounds. Hazardous combustion products may include and are
not limited to: carbon monoxide, carbon dioxide.
11. Toxicological Information
Crystalline Silica
IARC evaluation was that crystalline silica inhaled in the form of quartz from occupational sources
is carcinogenic to humans (Group 1). NTP also concluded that crystalline silica (respirable) may
reasonably be anticipated to be a carcinogen, based on sufficient evidence in experimental animals
and limited evidence in humans. Crystalline silica is not regulated by OSHA.
Antimony Trioxide
IARC concluded that evidence for the carcinogenicity of antimony trioxide in humans is inadequate,
based on limited epidemiological studies among antimony workers. However, based on short- and
long-term dosing of laboratory animals with antimony trioxide, tumors were observed in the lungs
of female rats. Based on this evidence, IARC classified antimony trioxide as "possibly carcinogenic
to humans" (Class 2B).
Lead, a minor contaminant (<0.4%) of antimony trioxide, is also classified by IARC as "possibly
carcinogenic to humans."
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Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
Arsenic, also a minor contaminant (<0.4%) of antimony trioxide, is listed as a substance that is
"known to be carcinogenic" by NTP, is classified as "carcinogenic to humans" by IARC, and is
regulated by OSHA as a carcinogen.
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The materials listed above are completely encapsulated in resin, and therefore, do not present a
potential dust inhalation problem unless the product itself is altered by some mechanical means.
12. Ecological Information
No information is available.
13. Disposal Considerations
Dispose of all waste material including containers in accordance with applicable federal, state, and
local environmental regulations.
14. Transportation Information
DOT Proper Shipping Name: Havaflex TA-117 Q.C. (Part B)
DOT Hazardous Class: None
DOT UN/NA Number: None
Emergency Response Guide Number: None
15. Regulatory Information
U.S. Federal Regulations as Follows:
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372:
Phenol, Formaldehyde, Lead, Antimony
TSCA:
The chemical substances in this product are on the TSCA Section 8 Inventory.
EXPORT NOTIFICATION:
This product contains the following chemical substances subject to the reporting requirements of
TSCA 12(B) if exported from the United States:
None
INTERNATIONAL REGULATIONS: AS FOLLOWS:
Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations
except for the use of the 16 headings.
Canadian WHMIS CLASS: Not Regulated.
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Material Safety Data Sheet MSDS #23-C
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Product: Havaflex TA-117 Q.C. (Part "B")
DSL:
The chemical substances in this product are listed on the Domestic Substances List (DSL).
16. Other Information
This Material Safety Data Sheet was revised in its entirety in March 2001.
ABBREVIATIONS:
1) ACGIH ?American Conference of Governmental Industrial Hygienists
2) OSHA ?Occupational Safety and Health Administration
3) NIOSH ?National Institute for Occupational Safety and Health
4) IARC ?International Agency for Research on Cancer
5) NTP ?National Toxicology Program
6) TLV ?Threshold Limit Value
7) PEL ?Permissible Exposure Limit
8) TWA ?Time Weighted Average
9) STEL ?Short Term Exposure Limit
10) IDLH ?Immediately Dangerous to Life or Health
11) N.A. ?Not Applicable
12) N.D. ?Not Determined
13) N.E. ?Not Established
14) DSL ?Domestic Substances List
THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE BASED ON THE MOST CURRENT DATA
AVAILABLE. AMETEK MAKES NO WARRANTY, EITHER EXPRESSED OR IMPLIED, WITH RESPECT TO
SUCH INFORMATION, AND ASSUMES NO LIABILITY RESULTING FROM ITS USE. USERS ARE ADVISED
TO CONDUCT THEIR OWN TESTS TO DETERMINE THE SAFETY AND SUITABILITY OF EACH PRODUCT
OR PRODUCT COMBINATION FOR THEIR OWN PURPOSES. AMETEK SHALL NOT BE LIABLE FOR ANY
CLAIMS, LOSSES, OR DAMAGES OF ANY THIRD PARTY OR FOR LOST PROFITS OR INCIDENTAL OR
CONSEQUENTIAL DAMAGES, HOWSOEVER ARISING EVEN IF AMETEK HAS BEEN ADVISED OF THE
POSSIBILITY OF SUCH DAMAGES.
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