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MSDS Material Safety Data Sheet
CAS

24937-78-8 7732-18-5 107-21-1 108-05-4

File Name: 24937-78-8_7732-18-5_107-21-1_108-05-4.asp

MSDS                                         SHEP WELD PLUS
Material Safety Data Sheet




1. ProDUct anD comPany iDEntification

Company : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
Trade name :Lab White 5gl PL
Product code : TL6505505001
Product Use: Coating

2. HazarDS iDEntification

Emergency Overview
Off-White to White. Liquid. No serious effects anticipated under normal conditions of use. Leave area to breathe fresh air. Avoid
further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation : No serious effects anticipated under normal conditions of use.
Eyes : Direct contact may cause mild irritation.
Ingestion : May cause gastrointestinal irritation, nausea, and vomiting.
Skin : May cause mild irritation.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects : In animal studies, prolonged or repeated exposure to ethylene glycol (or its components) has been sug-
gested as a cause of reproductive effects and kidney and liver damage. It has caused birth defect in animal studies at high oral
doses. Prolonged and repeated to ethylene glycol (or its components) has been suggested as a cause of kidney and liver damage
in humans. Ethylene glycol is not expected to cause cancer in humans, since it did not cause cancer in laboratory animals and
is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP),
or the Occupational Safety and Health Administration (OSHA). Long term inhalation exposure to vinyl acetate at high levels (600
ppm) caused nasal tumors in laboratory animals, some of which were shown to be carcinomas. However, there is no evidence that
vinyl acetate may cause cancer in humans. Fillers are encapsulated and not expected to be released from product under normal
conditions of use.

3. ProDUct comPoSition

chemical name caS-no. Weight %
Ethylene-Vinyl Acetate Copolymer 24937-78-8 40.0 - 70.0
Water 7732-18-5 40.0 - 70.0
Ethylene glycol 107-21-1 3.0 - 7.0
Vinyl acetate 108-05-4 - <1.0
4. firSt aiD mEaSUrES

Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other disorders develop, get medical
attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.

5. firE figHting mEaSUrES

Flash point : Not available.
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : This product is not expected to burn under normal conditions of use. Use that which is appropriate to the
surroundings.
Hazardous combustion : Carbon monoxide and carbon dioxide can form. Smoke, fumes.
Protective equipment for firefighters: Use accepted fire fighting techniques. Wear full firefighting protective clothing including self
contained breathing apparatus.
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.

6. acciDEntaL rELEaSE mEaSUrES

Transfer to appropriate container for disposal. Stop flow. Contain spill. Keep out of water courses. Absorb spill in sand, earth or
other suitable material. Transfer to appropriate container for disposal. Use appropriate protective equipment. Avoid contact with
material.

7. HanDLing anD StoragE

Handle in compliance with common hygienic practices. Clean hands thoroughly after handling. Keep from freezing. Do not use in
confined or poorly ventilated areas. Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container
closed when not in use. Precautions also apply to emptied containers. Store in sealed containers in a dry, ventilated warehouse
location above freezing.


8. ExPoSUrE controLS/PErSonaL ProtEction

Respiratory protection : Not required under normal conditions of use.Wear appropriate, NIOSH/MSHA approved respirator with
combination particulate filter and vapor/gas removing cartridge when the ventilation is not adequate or if it is necessary to
abrade or grind surfaces coated with this product.
Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face shield to prevent eye contact. Do not
wear contact lenses. Do not touch eyes with contaminated body parts or materials. Have eye washing facilities readily available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Other equipment not normally required. Use professional judgment in the selection, care, and use.
Engineering measures : Not required under normal conditions of use. Use local exhaust when the general ventilation is inad-
equate.
Exposure Limits
chemical name caS number regulation Limit form
Vinyl acetate 108-05-4 ACGIH TWA: 10 ppm
ACGIH STEL: 15 ppm


9. PHySicaL anD cHEmicaL ProPErtiES

Form : Liquid
Color : Off-White to White
Odor : Acrylic
pH : 9 - 10
Vapor pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : 32 癋, 0 癈
Boiling point/range : Not available.
Water solubility : Soluble
Specific Gravity : 1.098
% Volatile Weight : 45.0 %


10. rEactivity/StabiLity

Substances to avoid : Strong acids.Strong bases.
Stability : Stable
Hazardous polymerization : Will not occur.


11. toxicoLogicaL information

Ethylene glycol, CAS-No.: 107-21-1
Acute oral toxicity (LD-50 oral) 6,140 mg/kg ( Rat ) 14,600 mg/kg ( Mouse ) 8,200 mg/kg (Guinea pig ) 8,810 mg/kg (
Dog )
Vinyl acetate, CAS-No.: 108-05-4
Acute oral toxicity (LD-50 oral) 2,920 mg/kg ( Rat ) 1,613 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 3,680 mg/l for 4 h ( Rat ) 5,150 mg/l for 4 h ( Mouse ) 21,800 mg/l for 4 h ( Guinea
pig) 8,800 mg/l for 4 h ( Rabbit ) 1,550 mg/l for 4 h ( Mouse ) 2,500 mg/l for 4 h ( Rabbit ) 6,215 mg/l for 4 h
( Guinea pig ) 2,511 mg/l for 4 h ( Rabbit )
12. DiSPoSaL conSiDErationS

Not regulated under RCRA. Dispose of in compliance with state and local regulations. Do not incinerate.

13. rEgULatory information

North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Ethylene glycol 107-21-1
Vinyl acetate 108-05-4
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Ethylene glycol 107-21-1
Vinyl acetate 108-05-4
OSHA Status: Considered hazardous based on the following criteria: Irritant
OSHA Flammability : Not Regulated
Regulatory VOC (less water and exempt solvent): 61 g/l
VOC Method 310 : 3 %
U.S. State Regulations:
MASS RTK Components : Ethylene glycol 107-21-1
Vinyl acetate 108-05-4
Penn RTK Components : Ethylene-Vinyl Acetate Copolymer 24937-78-8
Water 7732-18-5
Ethylene glycol 107-21-1
NJ RTK Components : Ethylene-Vinyl Acetate Copolymer 24937-78-8
Water 7732-18-5
Ethylene glycol 107-21-1


14. otHEr information

HMIS Rating :
Health 1 0 = Minimum
Flammability 0 1 = Slight
Reactivity 0 2 = Moderate
PPE 3 = Serious
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act
RCRA - Resource Conservation and Recovery Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program
WHMIS - Workplace Hazardous Materials Information System

The information contained herein is based on the data available to us and is believed to be correct. However, we make no war-
ranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no
responsibility for injury from the use of the product described herein.

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NAMECAS
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100-42-5_107-21-1_112945-52-5.asp 100-42-5 107-21-1 112945-52-5
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107-21-1_115-96-8_61788-76-9.asp 107-21-1 115-96-8 61788-76-9
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107-21-1_8052-41-3.asp 107-21-1 8052-41-3
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8052-41-3_107-21-1_14808-60.asp 8052-41-3 107-21-1 14808-60-7
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24937-78-8_7732-18-5_107-21-1_108-05-4.asp 24937-78-8 7732-18-5 107-21-1 108-05-4
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107-21-1.asp 107-21-1
107-21-1_7664-93-9_7647-01-0_7681-49.asp 107-21-1 7664-93-9 7647-01-0 7681-49-4
107-21-1_75-07-0_123-91-1.asp 107-21-1 75-07-0 123-91-1
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107-21.asp 107-21-1


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