MATERIAL SAFETY DATA SHEET
FREEDOM Floor Stripper
HMIS NFPA Personal protective equipment
3 3
Health
0 0
Fire Hazard
0 0
Reactivity
Version Number: 1 Preparation date: 2006-08-14
1. PRODUCT AND COMPANY IDENTIFICATION
FREEDOM Floor Stripper
Product name:
MS0200041
MSDS #:
04609, 04616
Product Code:
Floor stripper. This product is intended to be diluted prior to use.
Recommended use:
Manufacturer, importer, supplier:
US Headquarters Canadian Headquarters
JohnsonDiversey, Inc. JohnsonDiversey - Canada, Inc.
8310 16th St. 2401 Bristol Circle
Sturtevant, Wisconsin 53177-0902 Oakville, Ontario L6H 6P1
Phone: 1-888-352-2249 Phone: 1-800-668-3131
MSDS Internet Address:
www.johnsondiversey.com
1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (M閤ico)
Emergency telephone number:
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED.
Eye contact. Skin contact. Inhalation.
Principle routes of exposure:
Corrosive. Causes permanent eye damage, including blindness.
Eye contact:
Corrosive. Causes permanent damage.
Skin contact:
May cause irritation and corrosive effects to nose, throat and respiratory tract.
Inhalation:
Corrosive. Causes burns to mouth, throat and stomach.
Ingestion:
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - Rat
(mg/kg) Rabbit
Sodium sulfate 7757-82-6 0.1 - 1.5% 10000 Not available Not available
Sodium hydroxide 1310-73-2 0.1 - 1.5% 140 1350 mg/kg Not available
Monoethanolamine 141-43-5 5 - 10% 1720 1 mL/kg Not available
Methanol 67-56-1 0.1 - 1.5% 5628 =15800 mg/kg =64000 ppm (4 h)
=83.2 mg/L (4 h)
4. FIRST AID MEASURES
Immediately flush eyes with running water for at least 15-20 minutes, keeping eyelids open. Get medical
Eye contact:
attention immediately.
Flush immediately with plenty of water for at least 15-20 minutes. Get medical attention immediately.
Skin contact:
If breathing is affected, remove to fresh air. Get medical attention immediately.
Inhalation:
If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON
Ingestion:
CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person.
Persons with pre-existing skin disorders may be more susceptable to irritating effects
Aggravated Medical Conditions:
5. FIRE-FIGHTING MEASURES
The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Suitable extinguishing media:
None known.
Specific hazards:
Corrosive material (See sections 8 and 10).
Unusual hazards:
No special methods required
Specific methods:
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5. FIRE-FIGHTING MEASURES
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: None.
6. ACCIDENTAL RELEASE MEASURES
Put on appropriate personal protective equipment (see Section 8.).
Personal precautions:
Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a
Environmental precautions
water rinse for final clean-up.
and clean-up methods:
7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and
wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All
precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained.
Personal Protective Equipment
Chemical-splash goggles.
Eye protection:
Chemical-resistant gloves
Hand protection:
Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear.
Skin and body protection:
In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that
Respiratory protection:
meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use.
Handle in accordance with good industrial hygiene and safety practice
Hygiene measures:
Ingredient(s) CAS # ACGIH OSHA Mexico
2 mg/m3 (Ceiling) 2 mg/m3 (TWA) 2 mg/m3 (Ceiling)
Sodium hydroxide 1310-73-2
Monoethanolamine 141-43-5 6 ppm (STEL) 3 ppm (TWA) 6 ppm (STEL)
6 mg/m3 (TWA) 15 mg/m3 (STEL)
3 ppm (TWA)
3 ppm (TWA)
8 mg/m3 (TWA)
Methanol 67-56-1 250 ppm (STEL) 200 ppm (TWA) 250 ppm (STEL)
260 mg/m3 (TWA) 310 mg/m3 (STEL)
200 ppm (TWA)
260 mg/m3 (TWA)
200 ppm (TWA)
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid No information available
Physical State: Bulk density:
13.0 12.6
pH: Dilution pH:
Aqueous solution No information available
Appearance: Vapor density:
Colorless No information available
Color: Evaporation Rate
Citrus Not determined
Odor: Boiling point/range:
1.06 Not determined
Specific gravity: Melting point/range:
8.81 lbs/gal Not determined
Density: Decomposition temperature:
10.3% * No information available
VOC: Autoignition temperature:
>200癋 >93.3癈
Flash point: Partition coefficient (n-octanol/water): No information available
completely soluble No information available
Solubility: Solubility in other solvents:
No information available 0 %P
Viscosity: Elemental Phosphorus:
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
The product is stable
Stability:
Hazardous polymerization does not occur
Polymerization:
None known.
Hazardous decomposition products:
Acids. Oxidising agents.
Materials to avoid:
Do not freeze.
Conditions to avoid:
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11. TOXICOLOGICAL INFORMATION
Oral LD50 estimated to be >1000 and <5000 mg/kg , Dermal LD50 estimated to be > 2000 mg/kg
Acute toxicity:
See Section 3
Component Information:
None known
Chronic toxicity:
Specific effects
None known
Carcinogenic effects:
None known
Mutagenic effects:
None known
Reproductive toxicity:
None known
Target organ effects:
12. ECOLOGICAL INFORMATION
No data available
Environmental Information:
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Undiluted product is regulated under environmental and transportation laws as a corrosive waste. Dispose of in compliance with all Federal, state,
provincial, and local laws and regulations. Incineration is the preferred method. Relatively small quantities of product may be neutralized as stated
above, and if in accordance with local laws and the operators of the local sewage treatment plant, the neutralized material may be discharged into the
sewer system .
14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information
15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Sodium sulfate 7757-82-6 X - X -
Sodium hydroxide 1310-73-2 X X X X
Sodium xylene sulfonate 1300-72-7 - - - -
Diethylene glycol phenyl ether 104-68-7 - X X -
Ethylene glycol phenyl ether 122-99-6 - X X -
1-butoxypropanol 5131-66-8 - - - -
Monoethanolamine 141-43-5 X X X X
Water 7732-18-5 - - - -
Methanol 67-56-1 X X X X
CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
Sodium hydroxide 1310-73-2 0.1 - 1.5% 1000
Diethylene glycol phenyl ether 104-68-7 1 - 5% X
Ethylene glycol phenyl ether 122-99-6 10 - 20% X
Methanol 67-56-1 0.1 - 1.5% 5000 X
Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants
Diethylene glycol phenyl ether X
Ethylene glycol phenyl ether X
Methanol X
SARA 311/312 Hazard Categories
Canada
WHMIS hazard class: E Corrosive material .
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Ingredient(s) CAS # NPRI
Methanol 67-56-1 X
16. OTHER INFORMATION
Not applicable
Reason for revision:
NAPRAC
Prepared by:
None
Additional advice:
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.
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