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MSDS Material Safety Data Sheet
CAS

10043-01-3 10028-22-5

File Name: 10043-01-3_10028-22-5.asp

Ref: MSDS/C02. Rev. 3
14/12/04



MATERIAL SAFETY
DATA SHEET Chemifloc Ltd


CHEMIFLOC AL-FE3 SERIES

SECTION 1 IDENTIFICATION
Trade Marks and Synonyms (if any) Chemical Names and Synonyms
Chemifloc 101, Chemifloc 202 Blend of Aluminium Sulfate and
Ferric Sulfate
Physical Form Molecular Formula
Brown Liquid. Al2(SO4)3. nH2O + Fe2(SO4)3. nH2O

Responsible Person : Emergency Telephone :
Chemifloc Ltd, Chemifloc Ltd,
Smithstown Ind. Estate, +353 61-708650
Shannon,
Co. Clare.
+353 61-708650


SECTION 2 INFORMATION ON INGREDIENTS

Ingredients Content Classification CAS No.:
Aluminium Sulphate 60 - 80 % Irritant 10043-01-3
Ferric Sulphate 20- 40% 8, Corrosive 10028-22-5




SECTION 3 HAZARDS IDENTIFICATION
Risk of damage to eyes. Prolonged contact with skin may cause possible dermatitis.


Occupational Exposure Limit (OEL)
Not Specified.




SECTION 4 PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odour : Brown Liquid with little or no odour.
pH 0. 5 - 1. 0 Conc:
Boiling Point (deg. C) Melting Point (deg. C) Flash Point (deg. C) Specific Gravity
105 - 108 - 10 None 1. 35 ?1.40
Autoignition (deg. C) Flammable Limit (% by Vol. in Air) Vapour Pressure (mm Hg)
None None N/A
Solubility in Water Solubility in Other Solvents Oxidising Properties
Totality Soluble N/A N/A

According to EC Directive 91/155/EEC
Page 1 of 4
Ref: MSDS/C02. Rev. 3
14/12/04




SECTION 5 STABILITY AND REACTIVITY

Stability Unstable Conditions to Avoid
Stable X
Incompatibility (Materials and Conditions to Avoid)
Contact with substances such as sulphides, cyanides or carbonates can result in the
evolution of toxic, flammable or asphyxiating gases. Attacks most metals liberating
flammable hydrogen gas.
Hazardous Decomposition Products
Emits highly toxic and corrosive fumes when heated to decomposition.

SECTION 6 TOXICITY DATA

Short term effects of over exposure when :

In contact with skin : Irritant after prolonged contact with skin.
Produces sores and possible dermatitis.

In contact with eyes : Irritates immediately and could cause severe damage which could
lead to permanent visual defects or even total loss of vision.

Inhaled : Not specified.

Ingested : Very astringent taste to mouth nose and throat normally followed
by rapid expectoration.

Long Term Exposure :




SECTION 7 FIRST AID MEASURES

Skin Contact : Remove contaminated clothing and wash affected area with
copious quantities of water.

Eye Contact : Immediately irrigate with water for at least 10 minutes.
Seek medical attention.

Inhalation : Remove patient to fresh air, keep warm and at rest.
Seek medical attention.

Ingestion : Provided patient is conscious wash out mouth with water and
give 5% sodium bicarbonate solution followed by a demulcent
such as milk.

Further Medical Advice : If in doubt seek medical attention.




According to EC Directive 91/155/EEC
Page 2 of 4
Ref: MSDS/C02. Rev. 3
14/12/04



SECTION 8 FIRE AND EXPLOSIVE HAZARD DATA

Would any material saturated Materials :
YES
with this product be subject to
NO X
spontaneous combustion ?
Fire Extinguishing Data
Water or dry powder may be used in the vicinity of Chemifloc Al-Fe3 products.
Keep containers cool with water spray.
Fire Fighting Protective Equipment
Wear full protective clothing and breathing apparatus.

Unusual Fire and Explosive Hazards
In contact with metals, Chemifloc Al-Fe3 products may liberate the flammable
gas Hydrogen.




SECTION 9 PERSONAL PROTECTION

General Precautions : Eye and skin protection should be used when handling
Chemifloc Al-Fe3 products.

Ventilation Requirements : Respiratory Protection :
None Not normally required

Protective Clothing Eye protection :
Gloves and Acid resistant footwear Goggles or full face mask
are essential.




SECTION 10 HANDLING AND STORAGE

Handling : Avoid contact with skin and eyes
Keep away from metals, organic materials, nitrates
chlorates and carbides.

Storage : Bulk quantities should be stored in Stainless Steel, rubber - lined
mild - steel or plastic tanks.
For small packages polyethylene or double skinned polyethylene
containers are acceptable.




SECTION 11 SPILLAGE/ACCIDENTAL RELEASE

Small Spillage : Wash away with large quantities of water.

Large Spillage : Neutralise with Lime or Soda Ash then dispose of according to
Local Regulations. Water can be used if washings can go to drain.

Personal Precautions : Wear full protective clothing.

Neutralising Chemicals : Hydrated Lime or Soda Ash.




According to EC Directive 91/155/EEC
Page 3 of 4
Ref: MSDS/C02. Rev. 3
14/12/04



SECTION 12 WASTE DISPOSAL

Neutralise with Lime and landfill in accordance with local regulations.



SECTION 13 ENVIRONMENTAL INFORMATION

Environmental Fate and Distribution
High tonnage material produced in wholly contained systems.
High tonnage material used in partially contained systems.
The substance is soluble in water.
Persistence and Degradation
Unlikely to cause harmful effects.
Remains indefinitely in the environment as Hydroxide.
Toxicity
Large discharges may contribute to the acidification of water and soil and
will injure aquatic life and soil micro - organisms.
Effects on effluent treatment:
Large discharges may contribute to the acidification of effluent treatment
systems and will injure treatment organisms. The product is a primary
coagulant and may cause solid settlement in treatment systems.




SECTION 14 REGULATORY INFORMATION

EEC Classification : Irritant Hazard Symbol : Xi
Risk Phrases : Iritating to eyes (R 36).

Safety Phrases: In case of eye contact, rinse immediately with water
and seek medical advise. (S 26).
Wear suitable gloves (S 37).




SECTION 15 TRANSPORT INFORMATION

UN No. NR UN Pack. Group NR ICAO/IATA Class NR
IMDG Class NR ADR/RID Class NR ADR/RID Item NR



SECTION 16 OTHER INFORMATION

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release, and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process
unless specified in the text.




According to EC Directive 91/155/EEC
Page 4 of 4

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