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MSDS Material Safety Data Sheet
CAS

91-63-4

File Name: 91-63.asp

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Material Safety Data Sheet
Quinaldine, 97%

ACC# 96582

Section 1 - Chemical Product and Company
Identification
MSDS Name: Quinaldine, 97%
Catalog Numbers: AC132170000, AC132170050, AC132171000, AC132172500, AC132175000,
AC9487634
Synonyms: 2-Methylquinoline 020
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300



Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
91-63-4 Quinaldine 97 202-085-1

Hazard Symbols: XN
Risk Phrases: 21/22 36/37/38



Section 3 - Hazards Identification
EMERGENCY OVERVIEW

Appearance: colorless, oily liquid. Flash Point: 79 deg C. Combustible liquid and vapor.
Warning! Causes eye and skin irritation. Causes digestive and respiratory tract irritation. May
be harmful if swallowed. May be harmful if absorbed through the skin.
Target Organs: None.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: Causes gastrointestinal tract irritation. May be harmful if swallowed.
Inhalation: Causes respiratory tract irritation.
Chronic: No information found.


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Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid.
Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid
immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.



Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-
demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating
and highly toxic gases may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible Liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. Containers may explode
when heated.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-
resistant foam. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: 79 deg C ( 174.20 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
Upper: N/A
NFPA Rating: Not published.



Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in
suitable container. Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.



Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before


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reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in
a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible
substances.



Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Use
process enclosure, local exhaust ventilation, or other engineering controls to control airborne
levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Quinaldine none listed none listed none listed

OSHA Vacated PELs: Quinaldine: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline
respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.



Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: colorless, oily
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 4.9
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 248 deg C @ 760.00mm Hg
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: practically insoluble
Specific Gravity/Density:1.0580g/cm3


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Molecular Formula:C10H9N
Molecular Weight:143.19



Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials: Oxidizing agents
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.



Section 11 - Toxicological Information

RTECS#:
CAS# 91-63-4: UZ9625000
LD50/LC50:
CAS# 91-63-4:
Draize test, rabbit, skin: 500 mg/24H Mild;
Oral, rat: LD50 = 1230 mg/kg;
Skin, rabbit: LD50 = 1870 uL/kg;
Carcinogenicity:
CAS# 91-63-4: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: No data available.



Section 12 - Ecological Information
No information available.



Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations
to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

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Section 14 - Transport Information
US DOT IATA RID/ADR IMO Canada TDG
No
Shipping No information
information
Name: available.
available.
Hazard
Class:
UN Number:
Packing
Group:



Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 91-63-4 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 91-63-4: acute.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any
Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None
of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the


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chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 91-63-4 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.

Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)
CAS# 91-63-4: No information available.
Canada - DSL/NDSL
CAS# 91-63-4 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
Canadian Ingredient Disclosure List
CAS# 91-63-4 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits



Section 16 - Additional Information
MSDS Creation Date: 4/13/1998
Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.




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