Material Safety Data Sheet
PERMAROOF TAR PATCH 3 US GAL.
Version 2. Print Date 07/07/2009
REVISION DATE: 06/29/2009
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : PERMAROOF TAR PATCH 3 US GAL.
Product code : 40403P
COMPANY : Republic Powdered Metals
2628 Pearl Road
Medina, OH 44256
Telephone : (800) 551-7081
Emergency Phone: : 1-800-551-7081
After Hours: Chemtrec 1-800-424-9300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Paste. Vapor may irritate respiratory tract. May cause nausea, headaches, and dizziness. Move to fresh
air. If required, artificial respiration or administration of oxygen can be performed by trained personnel.
Acute Potential Health Effects/ Routes of Entry
Inhalation Vapor may irritate respiratory tract. May cause nausea, headaches, and dizziness.
:
Eyes Direct contact may cause moderate irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause mild irritation. May cause sensitization. May cause a rash.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Creosote can cause cancer of the skin, lung, kidneys or bladder. Inhalation of crystalline silica (quartz) can
cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged
and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of the lungs
with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free silica. Fillers
are encapsulated and not expected to be released from product under normal conditions of use.
Target Organs: Skin, Lung, Liver, Kidney, Eye
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Coal tar 8007-45-2 > 60.0
Magnesium aluminum silicate 12174-11-7 5.0 - 10.0
Calcium Carbonate (Limestone) 1317-65-3 5.0 - 10.0
Inert Filler NJTSRN# 51721300-5013P 3.0 - 7.0
Rosin oil 8002-16-2 3.0 - 7.0
Creosote 8001-58-9 1.0 - 5.0
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Material Safety Data Sheet
PERMAROOF TAR PATCH 3 US GAL.
Version 2. Print Date 07/07/2009
REVISION DATE: 06/29/2009
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 - <1.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Oxides of
products sulfur can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Empty
containers may contain ignitable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Handle in compliance with common hygienic
practices. Clean hands thoroughly after handling. Do not smoke, weld, generate sparks, or use flame near
container. Store under dry warehouse conditions away from heat and all ignition sources.
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Material Safety Data Sheet
PERMAROOF TAR PATCH 3 US GAL.
Version 2. Print Date 07/07/2009
REVISION DATE: 06/29/2009
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.Workers must be fully clothed and
must wear protective cream or other protective barrier on exposed skin.
Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace
equipment at regular intervals.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Inert Filler 51721300-5013P ACGIH TWA: 10 mg/m3
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Crystalline Silica 14808-60-7 OSHA TWA: 0.1 mg/m3 Respirable.
(Quartz)/ Silica Sand OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
ACGIH TWA: 0.025 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Paste
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Material Safety Data Sheet
PERMAROOF TAR PATCH 3 US GAL.
Version 2. Print Date 07/07/2009
REVISION DATE: 06/29/2009
Color : Black
Odor : Tarry odor
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 150 癈, 302 ?br>
F
Water solubility : Negligible
Specific Gravity : 1.19
% Volatile Weight : 24 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Creosote, CAS-No.: 8001-58-9
Acute oral toxicity (LD-50 oral) 725 mg/kg ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Not regulated under RCRA as such; however any liquid separation, if discarded, is
considered hazardous waste (ignitable liquid, D001) under RCRA to be disposed of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
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Material Safety Data Sheet
PERMAROOF TAR PATCH 3 US GAL.
Version 2. Print Date 07/07/2009
REVISION DATE: 06/29/2009
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
All components are listed or exempt from the TSCA inventory.
U.S. Federal Regulations:
SARA 313 Components : Creosote 8001-58-9
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Coal tar 8007-45-2
Magnesium aluminum silicate 12174-11-7
Calcium Carbonate (Limestone) 1317-65-3
Inert Filler NJTSRN# 51721300-5013P
Creosote 8001-58-9
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : IIIA
Regulatory VOC (less water and : 287 g/l
exempt solvent)
VOC Method 310 : 24 %
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Coal tar 8007-45-2
Creosote 8001-58-9
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Coal tar 8007-45-2
Calcium Carbonate (Limestone) 1317-65-3
Inert Filler NJTSRN# 51721300-5013P
Creosote 8001-58-9
Penn RTK Components : Coal tar 8007-45-2
Magnesium aluminum silicate 12174-11-7
Calcium Carbonate (Limestone) 1317-65-3
Inert Filler NJTSRN# 51721300-5013P
Rosin oil 8002-16-2
Creosote 8001-58-9
NJ RTK Components : Coal tar 8007-45-2
5/6 40403P
Material Safety Data Sheet
PERMAROOF TAR PATCH 3 US GAL.
Version 2. Print Date 07/07/2009
REVISION DATE: 06/29/2009
Magnesium aluminum silicate 12174-11-7
Calcium Carbonate (Limestone) 1317-65-3
Inert Filler NJTSRN# 51721300-5013P
Rosin oil 8002-16-2
Creosote 8001-58-9
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
12174-11-7 Magnesium aluminum silicate
8001-58-9 Creosote
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
218-01-9 Chrysene
91-20-3 Naphthalene
50-32-8 Benzo(a)pyrene
56-55-3 Benzo(a)anthracene
71-43-2 Benzene
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
NTP - National Toxicology Program RCRA - Resource Conservation and Recovery Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
CERCLA - Comprehensive Environmental Response, Compensation, and WHMIS - Workplace Hazardous Materials Information
Liability Act System
OSHA - Occupational Safety and Health Administration
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