Material Safety Data Sheet
PENEFELT AF - ASPHALT BASED 55 US GL
Version 1.1 Print Date 02/23/2007
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : PENEFELT AF - ASPHALT BASED 55 US GL
Product code : 366500 855
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Liquid solution. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and
fatigue. May cause slight irritation to the respiratory system. Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and
:
fatigue. May cause slight irritation to the respiratory system.
Eyes Direct contact may cause moderate irritation. Direct contact may cause temporary
:
redness and discomfort.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause moderate irritation. May cause itching, reddening, inflammation. May cause a
:
rash. May cause sensitization.
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged or repeated skin contact with asphalt may result in skin sensitivity, such as irritation, rashes, and
dermatitis. Prolonged or repeated exposure to polycyclic aromatic hydrocarbons and other volatiles which are
contained in trace amounts in asphalt have been shown to cause cancer or respiratory damage in animals.
Creosote can cause cancer of the skin, lung, kidneys or bladder. Prolonged or repeated skin contact with
thermally cracked petroleum distillates in these products may result in irritation and dermatitis. Although a direct
association between thermally cracked petroleum distillates and cancer or other lung disease has not been
established in man, thermally cracked petroleum distillates may contain variable amounts of polynuclear
aromatic hydrocarbons (PNA's) and other volatiles which have been shown to cause cancer and respiratory
damage in animals. May produce a phototoxic reaction when contaminated skin is exposed to sunlight. Fillers
are encapsulated and not expected to be released from product under normal conditions of use. Prolonged or
repeated exposure to mineral spirits (petroleum naphtha or stoddard solvent) may cause defatting, drying, and
irritation of the skin, dermatitis, central nervous system (CNS) effects, and adverse liver, kidney, and lung
effects.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve
SECTION 3 - PRODUCT COMPOSITION
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Material Safety Data Sheet
PENEFELT AF - ASPHALT BASED 55 US GL
Version 1.1 Print Date 02/23/2007
REVISION DATE: 09/01/2006
Chemical Name CAS-No. Weight %
Asphalt 64741-56-6 40.0 - 70.0
Stoddard solvent (Mineral Spirits) 8052-41-3 15.0 - 40.0
Coal tar 8007-45-2 7.0 - 13.0
Rosin oil 8002-16-2 3.0 - 7.0
Creosote 8001-58-9 3.0 - 7.0
1,2,4-Trimethylbenzene 95-63-6 1.0 - 5.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : 55 ?131 ?br>
C, F
Method : Pensky-Martens Closed Cup
Lower explosion limit : 0.70 %(V) Solvent
Upper explosion limit : 6 %(V) Solvent
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Oxides of
products sulfur can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
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Material Safety Data Sheet
PENEFELT AF - ASPHALT BASED 55 US GL
Version 1.1 Print Date 02/23/2007
REVISION DATE: 09/01/2006
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace
equipment at regular intervals.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Stoddard solvent (Mineral 8052-41-3 ACGIH TWA: 100 ppm
Spirits) OSHA PEL: 2,900 mg/m3
1,2,4-Trimethylbenzene 95-63-6 ACGIH TWA: 25 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid solution
Color : Black
Odor : Petroleum
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 243 癈, 469 癋
Water solubility : Negligible
Specific Gravity : 0.96
% Volatile Weight : 23 %
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Material Safety Data Sheet
PENEFELT AF - ASPHALT BASED 55 US GL
Version 1.1 Print Date 02/23/2007
REVISION DATE: 09/01/2006
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Creosote, CAS-No.: 8001-58-9
Acute oral toxicity (LD-50 oral) 725 mg/kg ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
RCRA Class : D001: Reportable Quantity = 100 lbs. (Characteristic of ignitability)
This classification applies only to the material as it was originally produced.
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Creosote 8001-58-9
1,2,4-Trimethylbenzene 95-63-6
SARA 311/312 Hazards : Acute Health Hazard
Fire Hazard
OSHA Hazardous Components :
Stoddard solvent (Mineral Spirits) 8052-41-3
Coal tar 8007-45-2
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Material Safety Data Sheet
PENEFELT AF - ASPHALT BASED 55 US GL
Version 1.1 Print Date 02/23/2007
REVISION DATE: 09/01/2006
Creosote 8001-58-9
1,2,4-Trimethylbenzene 95-63-6
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : II
Regulatory VOC (less water and : 222 g/l
exempt solvent)
VOC Method 310 : 23 %
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Coal tar 8007-45-2
Creosote 8001-58-9
U.S. State Regulations:
MASS RTK Components : Stoddard solvent (Mineral Spirits) 8052-41-3
Coal tar 8007-45-2
Creosote 8001-58-9
1,2,4-Trimethylbenzene 95-63-6
Penn RTK Components : Asphalt 64741-56-6
Stoddard solvent (Mineral Spirits) 8052-41-3
Coal tar 8007-45-2
Rosin oil 8002-16-2
Creosote 8001-58-9
1,2,4-Trimethylbenzene 95-63-6
NJ RTK Components : Asphalt 64741-56-6
Stoddard solvent (Mineral Spirits) 8052-41-3
Coal tar 8007-45-2
Rosin oil 8002-16-2
Creosote 8001-58-9
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
8001-58-9 Creosote
218-01-9 Chrysene
56-55-3 Benzo(a)anthracene
91-20-3 Naphthalene
91-22-5 Quinoline
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
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Material Safety Data Sheet
PENEFELT AF - ASPHALT BASED 55 US GL
Version 1.1 Print Date 02/23/2007
REVISION DATE: 09/01/2006
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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