MATERIAL SAFETY DATA SHEET
AIMTM EC HERBICIDE
MSDS Ref. No.: 128639-02-1-13
Date Approved: 02/02/2007
Revision No.: 7
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The
information contained herein is for the concentrate as packaged, unless otherwise noted.
1. PRODUCT AND COMPANY IDENTIFICATION
AIMTM EC HERBICIDE
PRODUCT NAME:
6165
PRODUCT CODE:
Carfentrazone-ethyl
ACTIVE INGREDIENT(S):
Triazolinone
CHEMICAL FAMILY:
C15H14N3O3F3Cl2 (carfentrazone-ethyl)
MOLECULAR FORMULA:
FMC 116426; F8426; Ethyl 2-chloro-3-[2-chloro-4-fluoro-5-[4-
SYNONYMS:
(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-
yl]phenyl]-propanoate; IUPAC: 2-chloro-3-[2-chloro-5-(4-
difluoromethyl-3-methyl-5-oxo-4,5-dihydro-[1,2,4] triazol-1-yl)-4-
fluoro-phenyl] propionic acid ethyl ester, or Ethyl 2-chloro-3-[2-
chloro-5-(4-difluoromethyl-3-methyl-5-oxo-4,5-dihydro-[1,2,4]
triazol-1-yl)-4-fluoro-phenyl] propionate
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION (800) 331-3148 (FMC - U.S.A. & Canada)
Agricultural Products Group (716) 735-3765 (FMC - Reverse charges)
1735 Market Street
Philadelphia, PA 19103
(215) 299 6000 (General Information) For leak, fire, spill, or accident emergencies, call:
(800) 424-9300 (CHEMTREC - U.S.A. & Canada)
(703) 527-3887 (CHEMTREC - All Other Countries)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
? Brown-orange liquid with an aromatic solvent odor.
? Moderately combustible. May support combustion if heated above the product's flash point (see
Section 9, "Physical and Chemical Properties" below).
? Thermal decomposition and burning may form toxic by-products.
? For large exposures or fire, wear personal protective equipment.
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? Highly toxic to algae and toxic to fish and aquatic organisms. Keep out of drains and water courses.
POTENTIAL HEALTH EFFECTS: Effects from overexposure may result from
swallowing, breathing or coming into contact with the skin or eyes. Symptoms of overexposure include
pinpoint pupils, muscular incoordination, labored breathing, tearing, and diarrhea.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Carfentrazone-ethyl 128639-02-1 22.37 None R50/53; S60-61
Aromatic Hydrocarbons 64742-95-6 <60 265-199-0 R10-37-51/53-65-66-67;
S23-24-43A-57-60-62
Naphthalene 91-20-3 <9.5 202-049-5 R22-40-50/53; S2-36/37-
46-60-61
Surfactant Blend <6.4 None Not classified
4. FIRST AID MEASURES
EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, obtain medical
attention.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Do not induce vomiting and do not give liquids of any kind to the person. Never give
anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain
medical attention.
NOTES TO MEDICAL DOCTOR: This product has low oral dermal and inhalation
toxicity. It is mildly irritating to the skin and eyes. This product contains light aromatic hydrocarbons that
can produce a severe pneumonitis or fatal pulmonary edema if aspirated during vomiting. Consideration
should be given to gastric lavage with an endotracheal tube in place. Treatment is otherwise controlled
removal of exposure followed by symptomatic and supportive care.
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if
necessary. Contain all runoff.
FIRE / EXPLOSION HAZARDS: Moderately combustible. When heated above the flash
point, this material releases vapors which, when mixed with air, can burn or be explosive.
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Remove nearby ignition sources (such as
smoking, matches or open flames). Wear protective clothing and respiratory protection as prescribed in
Section 8, "Exposure Controls/Personal Protection" below. Keep unprotected persons and animals out of
the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non-
combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label
contents for disposal.
To clean and neutralize spill area, tools and equipment, wash with a suitable solution of caustic or soda ash,
and an appropriate alcohol (i.e., methanol, ethanol or isopropanol). Follow this by washing with a strong
soap and water solution. Absorb, as above, any excess liquid and add to the drums of waste already
collected. Repeat if necessary. Dispose of drummed waste according to the method outlined in Section 13,
"Disposal Considerations".
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Do not use or
store near heat, open flame or hot surfaces. Store in original containers only. Keep out of reach of children
and animals. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name ACGIH OSHA Supplier
Aromatic 18 ppm
Hydrocarbons
Naphthalene 10 ppm (TWA) 10 ppm (TWA)
50 mg/m3 (TWA)
15 ppm (STEL)
15 ppm (STEL)
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield.
RESPIRATORY: For splash, mist or spray exposures wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
watchbands - that become contaminated should be removed and destroyed. Launder all work
clothing before reuse (separately from household laundry).
GLOVES: Wear chemical protective gloves made of materials such as nitrile or neoprene.
Thoroughly wash the outside of gloves with soap and water prior to removal. Inspect regularly for
leaks.
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.
COMMENTS:
CANADIAN OCCUPATIONAL EXPOSURE LIMITS (OELs)
Naphthalene
Alberta: 15 ppm, 79 mg/m3 (STEL); 10 ppm, 52 mg/m3 (TWA)
British Columbia: 15 ppm (STEL); 10 ppm (TWA)
Manitoba: 15 ppm, 75 mg/m3 (STEL); 10 ppm, 50 mg/m3 (TWA)
New Brunswick: 15 ppm, 79 mg/m3 (STEL); 10 ppm, 52 mg/m3 (TWA)
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
Northwest Territories; 15 ppm, 79 mg/m3 (STEL); 10 ppm, 52 mg/m3 (TWA)
Nova Scotia: 15 ppm (STEL), 10 ppm (TWA)
Nunavut: 15 ppm, 79 mg/m3 (STEL); 10 ppm, 52 mg/m3 (TWA)
Ontario: 15 ppm, 78 mg/m3 (STEV); 10 ppm, 52 mg/m3 (TWAEVs)
Quebec: 15 ppm, 79 mg/m3 (STEV); 10 ppm, 52 mg/m3 (TWAEVs)
Saskatchewan: 15 ppm, 79 mg/m3 (STEL); 10 ppm, 52 mg/m3 (TWA)
Yukon: 15 ppm, 79 mg/m3 (STEL); 10 ppm, 50 mg/m3 (TWA)
Personal protective recommendations for mixing or applying this product are prescribed on the product
label. Information stated above provides useful, additional guidance for individuals whose use or handling
of this product is not guided by the product label.
9. PHYSICAL AND CHEMICAL PROPERTIES
Aromatic solvent
ODOR:
Brown-orange liquid
APPEARANCE:
9.0 lb/gal. (1080 g/L)
DENSITY / WEIGHT PER VOLUME:
79.9 癈 (176 癋) (CC)
FLASH POINT:
412.2 (carfentrazone-ethyl)
MOLECULAR WEIGHT:
5.3 (1% aqueous solution)
pH:
1.08 @ 20 癈 (water = 1)
SPECIFIC GRAVITY:
10. STABILITY AND REACTIVITY
Excessive heat and fire.
CONDITIONS TO AVOID:
Stable
STABILITY:
Will not occur
POLYMERIZATION:
Carbon monoxide, carbon dioxide, nitrogen oxides,
HAZARDOUS DECOMPOSITION PRODUCTS:
hydrogen chloride, and hydrogen fluoride.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Mildly irritating (rabbit)
SKIN EFFECTS: Mildly irritating (rabbit)
DERMAL LD50: > 4,000 mg/kg (rat)
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
ORAL LD50: 4,077 mg/kg (rat)
INHALATION LC50: > 6.31 mg/l (4 h) (rat) Zero mortality
ACUTE EFFECTS FROM OVEREXPOSURE: This product has low oral, dermal
and inhalation toxicity. It is mildly irritating to the skin and eyes. Signs of toxicity in laboratory animals
included mydriasis, cyanosis, ataxia, dyspnea, lacrimation, and diarrhea. Inhalation of aromatic
hydrocarbon vapors may cause dizziness, disturbances in vision, drowsiness, respiratory irritation, and eye,
skin and mucous membrane irritation. Vomiting after ingestion of this product may cause aspiration of
aromatic hydrocarbons into the lungs, which may result in fatal pulmonary edema. Naphthalene, if
ingested, may cause red blood cell hemolysis, especially in individuals with glucose-6-phosphate
dehydrogenase deficiency.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the
formulation. In studies with laboratory animals, carfentrazone-ethyl did not cause reproductive toxicity,
teratogenicity, or carcinogenicity. An overall absence of genotoxicity has been demonstrated in tests of
mutagenicity, DNA damage and chromosome aberrations. Chronic exposure to aromatic hydrocarbons may
cause headaches, dizziness, loss of sensations or feelings (such as numbness), and liver and kidney damage.
Naphthalene causes cataracts in humans, rats, rabbits and mice. In 2-year inhalation studies conducted by
the National Toxicology Program (NTP), there was no evidence of carcinogenic activity of naphthalene in
male mice, there was some evidence of carcinogenic activity in female mice and there was clear evidence
of carcinogenic activity in male and female rats. Inhalation studies conducted by the International Agency
for Research on Cancer (IARC) have found that there is inadequate evidence of carcinogenicity in humans,
therefore, IARC has classified naphthalene as a Group 2B (possibly carcinogenic to humans); however,
IARC has found that there is sufficient evidence of carcinogenicity in experimental animals.
CARCINOGENICITY:
Chemical Name IARC NTP OSHA Other
Naphthalene Listed Listed Not listed (ACGIH) Not listed
12. ECOLOGICAL INFORMATION
No data available for the formulation. Data presented below are based on the active ingredient.
ENVIRONMENTAL DATA: Carfentrazone-ethyl is rapidly degraded in soil (DT50 < 1.5
days) through microbial degradation, initially by hydrolysis to F8426-chloropropionic acid, and then
through further side-chain degradation to other acids. Based on field studies, carfentrazone-ethyl and its
major metabolite, F8426-chloropropionic acid, are confined to the top soil layer, indicating only slight
mobility in soil. Carfentrazone-ethyl is hydrolytically unstable in base (half-life of 5.1 hours), with stability
increasing with decreasing pH. It is susceptible to photolytic degradation in water, with a half-life of 8.3
days (pH 5). The Log Pow is 3.36 and the measured bioconcentration factor in whole fish is 159, both
indicating a low potential for accumulation. Its vapor pressure is 1.19 x 10-7 torr, indicating that volatility
is not a concern with this chemical.
ECOTOXICOLOGICAL INFORMATION: Carfentrazone-ethyl is very toxic to algae
(EC50: 5.7 to 17 礸/L), and much less toxic to fish (LC50: 1.6 to 2.0 mg/L), and aquatic crustacea (LC50 >
9.8 mg/L). Care should be taken to avoid contamination of the aquatic environment. In a test with
earthworms, carfentrazone-ethyl was shown to cause no effects at concentrations up to 820 mg/kg in soil.
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
Carfentrazone-ethyl shows little toxicity to birds either orally (LD50 > 2,250 mg/kg), or in the diet (LC50 >
5,620 ppm). Similarly, carfentrazone-ethyl has low toxicity to bees (no death at 200 礸/bee).
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned,
prior to disposal, by triple rinsing. Containers which held this material may be cleaned by being triple-
rinsed, and recycled, with the rinsate being incinerated. Do not cut or weld metal containers. Vapors that
form may create an explosion hazard.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Non-Bulk
PACKAGING TYPE:
This material is not a hazardous material as
ADDITIONAL INFORMATION:
defined by US Department of
Transportation at 49 CFR Parts 100 through
185.
Bulk
PACKAGING TYPE:
Combustible liquid, n.o.s.
PROPER SHIPPING NAME:
Aromatic hydrocarbons
TECHNICAL NAME(S):
NA 1993
UN/NA NUMBER:
III
PACKING GROUP:
Combustible
PLACARD(S):
1993
MARKING(S):
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
Non-Bulk
PACKAGING TYPE:
This material is not identified as a Marine
ADDITIONAL INFORMATION:
Pollutant since the ADR criterion of toxic
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
to algae has not, at this time, been adopted
under MARPOL.
ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
Non-Bulk
PACKAGING TYPE:
Environmentally hazardous substance,
PROPER SHIPPING NAME:
liquid, n.o.s.
Carfentrazone-ethyl
TECHNICAL NAME(S):
9
PRIMARY HAZARD CLASS / DIVISION:
M6
CLASSIFICATION CODE:
UN3082
UN/NA NUMBER:
III
PACKING GROUP:
90
HAZARD IDENTIFICATION NUMBER:
Carfentrazone-ethyl
MARINE POLLUTANT:
9
LABEL(S):
9
PLACARD(S):
3082, Marine Pollutant
MARKING(S):
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
Non-Bulk
PACKAGING TYPE:
Environmentally hazardous substance,
PROPER SHIPPING NAME:
liquid, n.o.s.
Carfentrazone-ethyl
TECHNICAL NAME(S):
9
PRIMARY HAZARD CLASS / DIVISION:
UN3082
UN/NA NUMBER:
III
PACKING GROUP:
9
LABEL(S):
Y914 / 30 kg G
LIMITED QUANTITY:
914 / 450 L
LIMITED QUANTITY: PASSENGER / CARGO:
914 / 450 L
LIMITED QUANTITY: CARGO:
Marks: Environmentally hazardous
ADDITIONAL INFORMATION:
substance, liquid, n.o.s. (carfentrazone-
ethyl), UN3082 + Marine Pollutant
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
OTHER INFORMATION:
Carfentrazone-ethyl is toxic to algae and is considered a Marine Pollutant under ADR. Air shipment from,
to, or within ADR member country is shown under IATA above. Shipment to, from or within the USA
presently does not recognize the ADR Marine Pollutant criterion of .toxic to algae..
HARMONIZED SYSTEM:
Import to the U.S.A.: 3808.30.1500
Export from the U.S.A.: 3808.30.0000
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Immediate, Delayed, Fire
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
This product contains the following ingredients subject to Section 313 reporting requirements:
Naphthalene
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Listed
Chemical Name RQ
Naphthalene 100 lb
FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT
U.S. EPA Signal Word: CAUTION
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Chemical Name: Aromatic Hydrocarbons
Hazard Classification / Division: B3
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
Domestic Substance List: Listed
Chemical Name: Naphthalene
Hazard Classification / Division: B4, D.2.A
Ingredient Disclosure List: 1%
Domestic Substance List: Listed
INTERNATIONAL LISTINGS
Australian Hazard Code: 3XE
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
Carfentrazone-ethyl, (Index #607-309-00-5):
EC Symbols: N (Dangerous for the environment)
EC Risk Phrases: R50/53 (Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
EC Safety Phrases: S60 (This material and its container must be disposed of as
hazardous waste)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
Aromatic Hydrocarbons, (Index #649-356-00-4):
EC Symbols: Xn (Harmful)
T (Toxic)
EC Risk Phrases: R10 (Flammable)
R37 (Irritating to respiratory system.)
R51/53 (Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
EC Safety Phrases: S23 (Do not breathe gas, fumes, vapor, or spray)
S24 (Avoid contact with skin.)
S43A (In case of fire use sand, earth, chemical powder or foam.)
S57 (Use appropriate container to avoid environmental
contamination.)
S60 (This material and its container must be disposed of as
hazardous waste)
S62 (If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.)
Notes For Preparation:
Nota H applies to the product or one or more of its components. Annex 1
Nota P of Annex 1 applies to the product or one or more of its components.
Naphthalene, (Index #601-052-00-2):
EC Symbols: Xn (Harmful)
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
N (Dangerous for the environment)
EC Risk Phrases: R22 (Harmful if swallowed.)
R50 (Very toxic to aquatic organisms.)
R53 (May cause long-term adverse effects in the aquatic
environment.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S36/37 (Wear suitable protective clothing and gloves.)
S60 (This material and its container must be disposed of as
hazardous waste)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
COMMENTS:
ADDITIONAL CANADIAN INFORMATION:
2006 National Pollutant Release Inventory (NPRI):
Aromatic hydrocarbons: Part 5 Substance
Naphthalene: Part 1, Group 1 Substance
16. OTHER INFORMATION
REVISION SUMMARY:
This MSDS replaces Revision #6, dated September 01, 2004.
Changes in information are as follows:
Section 1 (Product and Company Identification)
Section 8 (Exposure Controls / Personal Protection)
Section 14 (Transport Information)
Section 15 (Regulatory Information)
Section 16 (Other Information)
Aim and FMC Logo - Trademarks of FMC Corporation
?2007 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. Use of this product is regulated
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AIMTM EC HERBICIDE (128639-02-1-13) Date: 02/02/2007
by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a
manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the
control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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