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104-54-1 104-55-2 91-64-5 97-53-0 78-70-6 5989-27-5 84961-46-6 38-41-4

File Name: 104-54-1_104-55-2_91-64-5_97-53-0_78-70-6_5989-27-5_84961-46.asp

                                                                                                                       Flavex Naturextrakte GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Print date : 15.09.2009 Page 1 of 6


1. Identification of the substance/preparation and of the company/undertaking

Identification of the substance or preparation
Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Further product name
Zimtrinden Burmanii CO2-to Extrakt (鰇ol.) DE-013-謐o-Kontrollstelle, Typ Nr. 034.003
------------------------------------------------------------------------------------------------------------
Cinnamon bark Burmanii CO2-to extract (organic) DE-013-organic auditor, type no. 034.003
Use of the substance/preparation
In food supplements and natural remedies
--------------------------------------------------
Identified uses: Industrial manufacturing. Manufacture of food products. Product categories [PC]:
Perfumes, fragrances Pharmaceuticals Cosmetics
Company/undertaking identification
Company name: Flavex Naturextrakte GmbH
Street: Nordstr. 7
Place: D-66780 Rehlingen-Siersburg
Telephone: Telefax: +49 (0)6835/919595
+49 (0)6835/9195-0
Contact person: Telephone:
Mr. J. Sewerin
e-mail: info@flavex.com
Internet: www.flavex.com
Inquiry office: Poison information center Freiburg
Emergency telephone: +49 (0)761/19240

2. Hazards identification

Classification
Indications of danger : Irritant
R-phrases :
Irritating to eyes, respiratory system and skin.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
Explication of special hazards for human health and environment
Special skid risk by leaking/spilling product.

Contains cinnamic alcohol [CAS-no. 104-54-1]
cinnamaldehyde [CAS-no. 104-55-2]
coumarin [CAS-no. 91-64-5]
eugenol [CAS-no. 97-53-0]
linalool [CAS-no. 78-70-6]
limonene [CAS-no. 5989-27-5]
May cause allergic reactions.

3. Composition/information on ingredients

Chemical characterization
INCI-Name (CTFA): Cinnamomum Burmanii Bark Extract; CAS-no. 84961-46-6 EC-no.
(EINECS/ELINCS): 284-635-0

contains a.o. 70 - 90 % Cinnamaldehyde [CAS-no. 104-55-2], < 6 % coumarin [CAS-no. 91-64-5]


Revision no. : 1,04 Revision date : 15.09.2009
Flavex Naturextrakte GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Print date : 15.09.2009 Page 2 of 6


Hazardous components
Quantity
EC-No. CAS-No. Chemical name
Classification
GHS classification
203-213-9 104-55-2 Cinnamaldehyde 70 - 90 %
Xi R36/37/38-41-43

202-086-7 91-64-5 Coumarin <6%
Xn R22



Full text of each relevant R phrase can be found in heading 16.
Further Information
no solvent residues

4. First aid measures

General information
Seek medical attention if problems persist.
After inhalation
Provide fresh air.
After contact with skin
After contact with skin, wash immediately with: Water and soap.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding
eyelids apart.
After ingestion
Rinse mouth immediately and drink large quantities of water. Consult physician.

5. Fire-fighting measures

Suitable extinguishing media
foam, CO2, powder
Extinguishing media which must not be used for safety reasons
water stream
Special exposure hazards arising from substance or preparation itself, combustion products, resulting gases
formation of dangerous fumes possible
Special protective equipment for fire-fighters
In case of fire: Wear self-contained breathing apparatus.

6. Accidental release measures

Personal precautions
Avoid contact with skin and eyes, concentrated extracts should not be swallowed.
Environmental precautions
keep away from canalisation, waterway, groundwater
Methods for cleaning up/taking up
Remove mechanically, placing in appropriate containers for disposal.



Revision no. : 1,04 Revision date : 15.09.2009
Flavex Naturextrakte GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Print date : 15.09.2009 Page 3 of 6


7. Handling and storage

Handling
Advice on safe handling
Avoid contact with skin and eyes, concentrated extracts should not be swallowed.
wear splash goggles and oilresistent gloves
Storage
Requirements for storage rooms and vessels
no special measures necessary
Further information on storage conditions
keep dark and dry, avoid heat
store in tightly closed container
Storageclass (VCI): 10

8. Exposure controls/personal protection

Exposure limit values
Exposure controls
Protective and hygiene measures
remove contaminated clothes
Respiratory protection
do not breathe vapour / aerosol
Respiratory protection required in case of: aerosol or mist generation.
Hand protection
When handling chemical substances, chemical protective gloves must be worn with CE label including
a four digit code. German Industry Norms (DIN) / European Norms (EN): EN 374
Eye protection
wear splash goggles
Skin protection
wear clothing as usual in chemical industry

9. Physical and chemical properties

General information
liquid, viscous
Physical state:
Colour: brown
Odour: cinnamon smell
Important health, safety and environmental information
Test method
Changes in the physical state
Flash point: > 61 癈 method Abel-Pensky
Density: > 1,00 g/cm? pycnometer
Water solubility: unsoluble
Solubility in other solvents: good soluble in fat phases
Solvent content
no solvent residues


Revision no. : 1,04 Revision date : 15.09.2009
Flavex Naturextrakte GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Print date : 15.09.2009 Page 4 of 6


10. Stability and reactivity

Conditions to avoid
heat, open flame, sun light
Materials to avoid
Oxidizing agents.
Hazardous decomposition products
none - when carefully used
Additional information
no decomposition in the application field

11. Toxicological information

Acute toxicity
According to our knowledge, the chemical, physical and toxicological properties have not been
examined extensively.
LD 50 / LC 50_________ Component___________Type__________Value________Species
LD50 Cinnamaldehyde [CAS-no. 104-55-2] oral 2220 mg/kg Rat.
LD50 Coumarin oral 293 mg/kg Rat.

Cinnamaldehyde [CAS-no. 104-55-2] RTECS-No.: GD6475000
Coumarin RTECS-No.: GN4200000
Corrosive and irritant effects
Cinnamaldehyde [CAS-no. 104-55-2]:
Irritant effect on the skin: Human. 40 mg 48 h strong irritant effect
Additional information on tests
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).
Empirical data on effects on humans
Irritating to eyes, respiratory system and skin
may cause sensitization by skin contact
Further information
Acute toxicity, irritation of the skin and mucous mebrane, and mutagenic potential of the preparation
assessed by the manufacturer on the basis of the data sheets available on the main components.
Information gaps exist on some of the main individual components. However, according to the
experience of the manufacturer, no dangers above and beyond those on the product label are to be
expected.

12. Ecological information

Ecotoxicity
No data for ecological evaluation on hand
Under appropriate use there are no ecological problems to expect
Further information
no heavy metals and inorganic components

13. Disposal considerations

Advice on disposal
in accordance with valid regulations



Revision no. : 1,04 Revision date : 15.09.2009
Flavex Naturextrakte GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Print date : 15.09.2009 Page 5 of 6

Waste disposal number of waste from residues/unused products
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; off-specification batches and unused
160305
products; organic wastes containing dangerous substances
Classified as hazardous waste.
Contaminated packaging
in accordance with valid regulations

14. Transport information

Further Information
no dangerous good in the sense of the transport regulations

15. Regulatory information

Labelling
Danger symbols: Xi - Irritant




Xi - Irritant
Hazardous component(s) to be indicated on label
Cinnamaldehyde
Coumarin
R phrases
37/38 Irritating to respiratory system and skin.
41 Risk of serious damage to eyes.
43 May cause sensitization by skin contact.
S phrases
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 Wear suitable gloves and eye/face protection.
Special labelling for certain preparations
Caution -- substance not yet tested completely.
Additional advice on labelling
The classification was undertaken in accordance with the method of calculation governed by the
preparation regulations (1999/45/EC).
GHS labelling
Signal word: Warning
Pictograms: exclamation mark




Hazard statements
H302 Harmful if swallowed.
H315 Causes skin irritation.

Revision no. : 1,04 Revision date : 15.09.2009
Flavex Naturextrakte GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Cinnamon bark Burmanii CO2-to extract (organic)_034.003
Print date : 15.09.2009 Page 6 of 6

Precautionary statements
P332+P313 If skin irritation occurs: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P362 Take off contaminated clothing and wash before reuse.
P330 Rinse mouth.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P270 Do no eat, drink or smoke when using this product.
P264 Wash hands thoroughly after handling.
National regulatory information
Employment restrictions: Observe employment restrictions for young people.
Water contaminating class (D): 1 - slightly water contaminating

16. Other information

Full text of R-phrases referred to under sections 2 and 3
22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
37/38 Irritating to respiratory system and skin.
41 Risk of serious damage to eyes.
43 May cause sensitization by skin contact.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
The receiver of our product is singulary responsible for adhering to existing laws and regulations.
Changes
Reason for revision: general revision of whole document




Revision no. : 1,04 Revision date : 15.09.2009

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