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MSDS Material Safety Data Sheet
CAS

868-77-9 84170-27-4 14807-96-6 1147-14-8 112945-52-2

File Name: 868-77-9_84170-27-4_14807-96-6_1147-14-8_112945-52-2.asp

MATERIAL SAFETY DATA SHEET

V-Wrap 778 HTg ?Adhesive Resin
High Temperature Resistant Resin

1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
MATERIAL IDENTITY: INFORMATION TELEPHONE:
V-Wrap 778 HTg ?Adhesive Resin 410-850-7000
Vinyl Ester Resin

COMPANY: EMERGENCY TELEPHONE:
VStructural LLC CHEMTREC: 800-424-9300
7455 T New Ridge Road
Hanover, MD 21076


2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s) CAS Number % (by weight) Exposure Limits
PEL STEL TLV
Vinyl Ester Polymer Proprietary 25 - 85 NE NE NE
Monomer(s) 868-77-9 15 - 75 NE NE NE
Hexanediol ethoxylated diacrylate 84170-27-4 1-5 NE NE NE
2 mg/m3
Talc 14807-96-6 5 - 30 NE NE
15 mg/m3
Calcium carbonate 1147-14-8 5 - 30 Total Dust
5 mg/m3 Resp Dust
6 mg/m3
Fumed Silica 112945-52-2 1 - 10 NE NE

3. HAZARDS IDENTIFICATION
EYE
This material can cause severe eye irritation. Symptoms severe irritation, redness, tearing, blurred vision
and corneal damage.

SKIN ABSORPTION
May be absorbed through the skin in harmful amounts. May cause skin sensitization, and allergic reaction,
which become evident upon re-exposure.

SKIN IRRITATION
Prolonged or repeated contact can cause moderate irritation and dermatitis.

INGESTION
Can cause gastrointestinal irritation with nausea, vomiting and diarrhea. Aspiration of material into the
lungs can cause chemical pneumonitis which can be fatal.

INHALATION
Wear appropriate respiration equipment if vapor or mist is expected. Inhalation may cause respiratory tract
irritation. Excessive inhalation of vapors can cause nasal irritation, dizziness, weakness, fatigue, nausea,
headache, possible unconsciousness, and even asphyxiation. This product contains talc which is currently
listed by OSHA as a respirable dust hazard with an exposure limits of 2 mg/m3.

CHRONIC EFFECTS


www.vsl.net ?410-850-7000
VStructural LLC ?A Structural Group Company ?7455 New Ridge Road, Suite T ?Hanover, MD 21076
V-Wrap 778 HTg MSDS ?REV 12/2007 ?Page 1 of 5
MATERIAL SAFETY DATA SHEET

V-Wrap 778 HTg ?Adhesive Resin
High Temperature Resistant Resin

The toxicological properties of this substance have not been fully investigated. Chronic effects of exposure
to monomers may cause reproductive disorders.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
This material or its emissions may induce an allergic or sensitization reaction and thereby aggravate
systemic disease. Exposure to dusts may aggravate breathing problems, colds and congestion.

4. FIRST AID MEASURES
EYES
Immediately flush eyes gently with large amounts of water for at least 15 minutes. Retract eyelids often.
Get prompt medical attention.
SKIN
Remove contaminated clothing. Wash the exposed area with mild soap and water. Flush w/lukewarm water
for 15 minutes. Launder contaminated clothing before re-use. Seek medical attention if ill effect or
irritation develops.
INGESTION
Do not induce vomiting. Never give anything by mouth to an unconscious person. Keep person warn, quiet
and get medical attention. Aspiration of material into the lungs due to vomiting can cause chemical
pneumonitis which can be fatal.
INHALATION
If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention immediately.
ADVISE TO PHYSICIANS
Treat symptomatically and supportively.

5. FIRE FIGHTING MEASURES
FLASH POINT METHOD
GT 215 F/102 C for volatile components

FLAMMABLE LIMITS (% VOLUME IN AIR) AUTOIGNITION TEMP. METHOD = N/AP
LOWER: N/AP UPPER: N/AP

FIRE AND EXPLOSIVE HAZARDS
Fire or excessive heat may result in rupture of container due to bulk polymerization. Heating may cause
explosion.

EXTINGUISHING MEDIA
Dry Chemical, CO2, Foam, Water spray/water fog for cooling. USE WATER WITH CAUTION. Water
may be ineffective in fighting the fire.

FIRE FIGHTING INSTRUCTIONS
Wear self contained breathing apparatus (pressure-demand MSHA/NIOSH) approved or equivalent and
protective clothing. See Section 10 ?decomposition products possible. Fight fire from safe
distance/protected location. Water may be ineffective in firefighting due to low solubility. Use water
spray/fog for cooling. Pressure relief system may plug with solids, increasing risk of overpressure. Notify
authorities if liquid enters sewer/public waters.


www.vsl.net ?410-850-7000
VStructural LLC ?A Structural Group Company ?7455 New Ridge Road, Suite T ?Hanover, MD 21076
V-Wrap 778 HTg MSDS ?REV 12/2007 ?Page 2 of 5
MATERIAL SAFETY DATA SHEET

V-Wrap 778 HTg ?Adhesive Resin
High Temperature Resistant Resin

6. ACCIDENTAL RELEASE MEASURES
Spilled or released material may polymerize and release heat/gases. Eliminate all ignition sources and
ventilate area. Wear protective equipment during clean up. Dike and recover large spill. Soak up small
spill with inert solids (such as vermiculite, clay) and sweep/shovel into vented disposal container. Wash
spill area with a strong detergent and water solution; rinse with water but minimize water use during clean
up. Prevent runoff from entering drains, sewers, or streams. Dispose/report per regulatory requirements.

7. HANDLING AND STORAGE
Unless inhibited, product can polymerize, raising temperature and pressure, possibly rupturing container.
Check inhibitor content often, adding to bulk liquid if needed. Do not blanket or mix with oxygen-free gas
as it renders inhibitor ineffective. Do not store at below 32F ?inhibitor can separate as a solid. If frozen,
warm and remix material gently (<90F). Prevent moisture contact. Store in tightly closed, properly vented
containers away from: heat, sparks, open flame, strong oxidizers, radiation and other initiators. Prevent
contamination by foreign materials. Use only non-sparking tools and limit storage time.

DECONTAMINATION PROCEDURES
Follow standard plant procedures or supervisor's instructions for decontamination operations.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE PROTECTION
Eye protection such as chemical splash goggles and/or face shield must be worn when possibility exists for
eye contact due to splashing or spraying liquid, airborne particles or vapor. Contact lenses should not be
worn.

SKIN PROTECTION
When skin contact is possible, protective clothing including apron, sleeves, boots head and face protection
should be worn. Wear chemical resistant gloves such as neoprene, rubber, latex, etc.

RESPIRATORY PROTECTIONS
Where exposure through inhalation may occur from use, NIOSH/MSHA approved respiratory protection
equipment is recommended. If cured material is cut or sanded a NIOSH/MSHA particulate respirator is
recommended.

ENGINEERING CONTROLS
Local exhaust ventilation may be required in addition to general room ventilation.

OTHER HYGIENIC PRACTICES
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any
potential exposure.

OTHER WORK PRACTICES
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet
facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work using
plenty of soap and water.




www.vsl.net ?410-850-7000
VStructural LLC ?A Structural Group Company ?7455 New Ridge Road, Suite T ?Hanover, MD 21076
V-Wrap 778 HTg MSDS ?REV 12/2007 ?Page 3 of 5
MATERIAL SAFETY DATA SHEET

V-Wrap 778 HTg ?Adhesive Resin
High Temperature Resistant Resin

9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point 408 F/198 C
Vapor Pressure 0.23 mm Hg
Vapor Density (air=1) >1
Specific Gravity (water=1 @39.2F) 1.12 @ 25C/77F
Percent Volatiles Negligible
Evaporation Rate (Bac=1) N/DA
Viscosity Units, Temp. (Brookfield) AP varies with product mix cps @ 25C/77F
Odor Mild to sweet acrylic odor
pH N/DA
Color Straw to light yellow
State viscous liquid

10. STABILITY AND REACTIVITY
CONDITIONS AND MATERIALS TO AVOID
High temperatures, localized heat sources (i.e., drum or band heaters), oxidizing conditions, freezing
conditions, direct sunlight, ultraviolet radiation, inert gas blanketing; strong oxidizers, strong reducers, free
radical initiators, inert gases, oxygen scavengers.

HAZARDOUS DECOMPOSITION PRODUCTS
Acrid smoke-fumes, carbon monoxide, carbon dioxide and perhaps other toxic vapors may be released
during a fire involving this product.

11. SUPPLEMENT
NPCA HMIS RATING
Health 2
Flammability 2
Reactivity 1
Personal Protection** D

**Respiratory protection may be necessary depending on conditions of use.

12. TOXICOLOGY INFORMATION



No information found

13. REGULATORY INFORMATION

SARA TITLE 3: SECTION 311/312 HAZARD CLASS (40CFR370)
This product does not contain a chemical which is listed in Section 313 at or above the de minimus
concentrations.

CERCLA INFORMATION (40CFR302.4)
This material contains no hazardous or extremely hazardous substances as defined by CERCLA or SARA
Title III, and release is therefore not reportable.

www.vsl.net ?410-850-7000
VStructural LLC ?A Structural Group Company ?7455 New Ridge Road, Suite T ?Hanover, MD 21076
V-Wrap 778 HTg MSDS ?REV 12/2007 ?Page 4 of 5
MATERIAL SAFETY DATA SHEET

V-Wrap 778 HTg ?Adhesive Resin
High Temperature Resistant Resin

TSCA status: All components of this product are listed, or excluded from listing, on the United States
Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory.

California Proposition 65 Information: This product does not contain substance(s) known to the state of
California to cause cancer and/or reproductive toxicity.

This material contains an inhibitor (HQ, MEHQ, etc.). The type and amount meet product specifications.
Contact a company representative for exact concentrations and details on inhibitor level maintenance.

TRANSPORTATION INFORMATION
US DOT Hazard Class Non-Regulated

WORKPLACE CLASSIFICATION
This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR
1910.1200)

WASTE CLASSIFICATION
When a decision is made to discard this material as supplied, it does not meet RCRA's characteristics
definition of ignitability, corrosiveness, or reactivity and is not listed in 40CFR261.33. The toxicity
characteristic (TC), has not been evaluated by the Toxicity Characteristic Leaching Procedure (TCLP).

14. OTHER INFORMATION
Some of the information presented and conclusions drawn herein are from sources other than direct test
data on the product itself. The information in this MSDS was obtained from sources, which we believe are
reliable. However, the information is provided without any warranty, express or implied, regarding its
correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond
our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility
and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the
handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be
applicable. This MSDS has been prepared in accordance with the requirements of the OSHA Hazard
Communication Standard (29 CFR 1910.1200).

*Note ?qualifiers and codes used in this MSDS
EQ=Equal; AP= Approximately; LT= Less Than; GT = Greater Than; TR =Trace; UK = Unknown; N/AP
= Not Applicable; N/P = No Applicable Information Found; N/DA = No Data Available; NE = Not
Established




www.vsl.net ?410-850-7000
VStructural LLC ?A Structural Group Company ?7455 New Ridge Road, Suite T ?Hanover, MD 21076
V-Wrap 778 HTg MSDS ?REV 12/2007 ?Page 5 of 5

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