AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 1 of 18
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
AC100E PART A
SYNONYMS
"adhesive system cartridge component A part A two-part"
PRODUCT USE
Adhesive system applied by a cartridge.
SUPPLIER
Company: Powers Fasteners Australasia Pty Ltd
Address:
Factory 3, 205 Abbotts Road
Dandenong South
VIC, 3175
AUS
Telephone: +61 3 8787 5888
Telephone: +1 800 677 872 (freecall)
Fax: +61 3 9878 5899
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
Irritating to eyes respiratory system and Wear eye/ face protection.
skin.
May cause SENSITISATION by skin contact. Use only in well ventilated areas.
Harmful to aquatic organisms may cause Keep container in a well ventilated place.
long- term adverse effects in the aquatic
environment.
To clean the floor and all objects
contaminated by this material use water and
detergent.
Take off immediately all contaminated
clothing.
In case of contact with eyes rinse with
plenty of water and contact Doctor or
Poisons Information Centre.
If swallowed IMMEDIATELY contact Doctor or
Poisons Information Centre (show this
container or label).
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 2 of 18
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
2- hydroxyethyl methacrylate 868-77-9 1-19
methylstyrene, mixed isomers 1321-45-5 1-19
silica amorphous 7631-86-9 1-10
dipropoxy- p- toluidine 38668-48-3 0.1-0.9
silica crystalline - quartz 14808-60-7 Not Spec
Section 4 - FIRST AID MEASURES
SWALLOWED
?Immediately give a glass of water.
?First aid is not generally required. If in doubt, contact a Poisons Information Centre
or a doctor.
EYE
If this product comes in contact with eyes:
?Wash out immediately with water.
?If irritation continues, seek medical attention.
?Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
?Immediately remove all contaminated clothing, including footwear.
?Flush skin and hair with running water (and soap if available).
?Seek medical attention in event of irritation.
INHALED
?If fumes or combustion products are inhaled remove from contaminated area.
?Other measures are usually unnecessary.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to styrene:
INHALATION:
?Severe exposures should have cardiac monitoring to detect arrhythmia.
?Catecholamines, especially epinephrine (adrenaline) should be used cautiously (if at
all).
?Aminophylline and inhaled beta-two selective bronchodilators (e.g. salbutamol) are the
drugs of choice for treatment of bronchospasm.
INGESTION:
?Ipecac syrup should be given for ingestions exceeding 3ml (styrene)/kg.
?For patients at risk of aspiration because of obtundation, intubation should precede
lavage.
?Pneumonitis is a significant risk. Watch the patient closely in an upright (alert
patient) or left lateral head-down position (obtunded patient) to reduce aspiration
potential. [Ellenhorn and Barceloux: Medical Toxicology]
BIOLOGICAL EXPOSURE INDEX - BEI
These represent the determinants observed in specimens collected from a healthy worker
who has been exposed at the Exposure Standard (ES or TLV):
Determinant Index Sampling Time Comments
1. Mandelic acid in 800 mg/gm creatinine End of shift NS
urine
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 3 of 18
Section 4 - FIRST AID MEASURES
300 mg/gm creatinine Prior to next shift NS
2. Phenylglyoxylic 240 mg/gm creatinine End of shift NS
acid in urine
100 mg/gm creatinine Prior to next shift
3. Styrene in venous 0.55 mg/L End of shift SQ
blood
0.02 mg/L Prior to next shift SQ
NS: Non-specific determinant; also seen after exposure to other materials.
SQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a
screening test or confirmatory test.
B: Background levels occur in specimens collected from subjects NOT exposed.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
?There is no restriction on the type of extinguisher which may be used.
?Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
?Alert Fire Brigade and tell them location and nature of hazard.
?Wear breathing apparatus plus protective gloves for fire only.
?Prevent, by any means available, spillage from entering drains or water courses.
?Use fire fighting procedures suitable for surrounding area.
?DO NOT approach containers suspected to be hot.
?Cool fire exposed containers with water spray from a protected location.
?If safe to do so, remove containers from path of fire.
?Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
?Non combustible.
?Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of:
carbon dioxide (CO2),
nitrogen oxides (NOx),
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
HAZCHEM: None
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 4 of 18
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
?Clean up all spills immediately.
?Avoid contact with skin and eyes.
?Wear impervious gloves and safety goggles.
?Trowel up/scrape up.
?Place spilled material in clean, dry, sealed container.
?Flush spill area with water.
MAJOR SPILLS
Minor hazard.
?Clear area of personnel.
?Alert Fire Brigade and tell them location and nature of hazard.
?Control personal contact by using protective equipment as required.
?Prevent spillage from entering drains or water ways.
?Contain spill with sand, earth or vermiculite.
?Collect recoverable product into labelled containers for recycling.
?Absorb remaining product with sand, earth or vermiculite and place in appropriate
containers for disposal.
?Wash area and prevent runoff into drains or waterways.
?If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
?Avoid all personal contact, including inhalation.
?Wear protective clothing when risk of exposure occurs.
?Use in a well-ventilated area.
?Prevent concentration in hollows and sumps.
?DO NOT enter confined spaces until atmosphere has been checked.
?DO NOT allow material to contact humans, exposed food or food utensils.
?Avoid contact with incompatible materials.
?When handling, DO NOT eat, drink or smoke.
?Keep containers securely sealed when not in use.
?Avoid physical damage to containers.
?Always wash hands with soap and water after handling.
?Work clothes should be laundered separately. Launder contaminated clothing before re-use.
?Use good occupational work practice.
?Observe manufacturer's storing and handling recommendations.
?Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
?Polyethylene or polypropylene container.
?Packing as recommended by manufacturer.
?Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
?Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
?Store in original containers.
?Keep containers securely sealed.
?Store in a cool, dry, well-ventilated area.
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 5 of 18
Section 7 - HANDLING AND STORAGE
?Store away from incompatible materials and foodstuff containers.
?Protect containers against physical damage and check regularly for leaks.
?Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA STEL ppm STEL TWA F/CC
mg/m? mg/m?br>
__________________ __________________ _______ _______ _______ _______ _______
Australia Exposure methylstyrene, mixed 50 242 100 483
Standards isomers (Vinyl
toluene)
Australia Exposure silica amorphous 0.5 0.5
Standards (Glasswool)
Australia Exposure silica amorphous 2
Standards (Silica - Amorphous
Fumed silica
(respirable dust))
Australia Exposure silica amorphous 10
Standards (Inspirable dust (not
otherwise classified))
Australia Exposure silica amorphous 2
Standards (Silica - Amorphous
Fume (thermally
generated)(respirable
dust) (g))
Australia Exposure silica crystalline - 0.1
Standards quartz (Silica -
Crystalline Quartz)
Australia Exposure silica crystalline - 2
Standards quartz (Silica -
Amorphous Fume
(thermally
generated)(respirable
dust) (g))
The following materials had no OELs on our records
?2- hydroxyethyl methacrylate: CAS:868- 77- 9
?dipropoxy- p- toluidine: CAS:38668- 48- 3
EMERGENCY EXPOSURE LIMITS
Material Original IDLH Value (mg/m3) Revised IDLH Value (mg/m3)
Revised IDLH Value (ppm) N.E. N.E.
3, 000 silica crystalline - quartz N.E.
N.E.
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
2-HYDROXYETHYL METHACRYLATE:
METHYLSTYRENE, MIXED ISOMERS:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 6 of 18
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-
category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
?cause inflammation
?cause increased susceptibility to other irritants and infectious agents
?lead to permanent injury or dysfunction
?permit greater absorption of hazardous substances and
?acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
2-HYDROXYETHYL METHACRYLATE:
Designated S in List of MAK values: Danger of sensitization.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany.
CEL TWA: 50 ppm, 260 mg/m3
METHYLSTYRENE, MIXED ISOMERS:
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV- TWA for
example) is being reached,
even when distracted by
working activities
B 26- 550 As " A" for 50- 90% of
persons being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by
smell that the Exposure
Standard is being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
The toxicological properties of vinyltoluene are similar to those of
styrene and the TLV- TWA and STEL are analogous. The limits are thought to
be protective against mucous membrane and ocular irritation and should
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 7 of 18
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
reduce the complaints of objectionable odour. Given that axonal
degeneration found in rats inhaling vinyltoluene is more significant than
in rats inhaling comparable concentrations of styrene, and that
neurological changes are more prominent, the limits are the subject of
review.
Human subjects show ocular and upper respiratory tract irritation at
400 ppm, complain of a strong objectionable odour at 300 ppm and a strong
but tolerable odour at 200 ppm.. At 50 ppm, the odour is detectable and
may become disagreeable, but does not produce irritation of the mucous
membranes.
SILICA AMORPHOUS:
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their
equivalent) for all substances for which there is evidence of health effects at airborne
concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce
adverse health effects (as evidenced in animal experiments or clinical experience).
Airborne concentrations must be maintained as low as is practically possible and
occupational exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified
(P.N.O.S) does NOT apply.
DIPROPOXY-P-TOLUIDINE:
No exposure limits set by NOHSC or ACGIH.
SILICA CRYSTALLINE - QUARTZ:
Because the margin of safety of the quartz TLV is not known with certainty and given
the associated link between silicosis and lung cancer it is recommended that quartz
concentrations be maintained as far below the TLV as prudent practices will allow.
PERSONAL PROTECTION
EYE
?Safety glasses with side shields.
?Chemical goggles.
?Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
?NOTE: The material may produce skin sensitisation in predisposed individuals. Care must
be taken, when removing gloves and other protective equipment, to avoid all possible skin
contact.
OTHER
?Overalls.
?P.V.C. apron.
?Barrier cream.
?Skin cleansing cream.
?Eye wash unit.
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 8 of 18
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration
is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half- Face Respirator Full- face Respirator
(Min)
10 x ES A- - AUS -
A- - PAPR- AUS -
20 x ES - A- - AUS
- A- - PAPR- AUS
100 x ES - A- - 2
- A- - PAPR- 2
^ - Full-face.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Molecular Weight: Not Applicable Boiling Range (?Not Available
C):
Melting Range (?Not Available
C): Specific Gravity (water= 1): 1.61
Solubility in water (g/L): Partly Miscible pH (as supplied): Not Available
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Flash Point (?Not A pplicable
C):
Available
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (?Not Available
C): Decomposition Temp ( ?Not Available
C):
State: Non Slump Paste Viscosity: Not available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Product is considered stable and hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 9 of 18
Section 11 - TOXICOLOGICAL INFORMATION
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification systems as
"harmful by ingestion". This is because of the lack of corroborating animal or human
evidence. The material may still be damaging to the health of the individual, following
ingestion, especially where pre-existing organ (eg. liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses producing
mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal
tract discomfort may produce nausea and vomiting. In an occupational setting however,
ingestion of insignificant quantities is not thought to be cause for concern.
EYE
Although the material is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
INHALED
The material is not thought to produce adverse health effects or irritation of the
respiratory tract (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure.
There is some evidence that inhaling this product is more likely to cause a sensitisation
reaction in some persons compared to the general population.
Skin contact with the material is more likely to cause a sensitisation reaction in some
persons compared to the general population.
Sensitisation may give severe responses to very low levels of exposure, i.e.
hypersensitivity. Sensitised persons should not be allowed to work in situations where
exposure may occur.
Chronic solvent inhalation exposures may result in nervous system impairment and liver
and blood changes. [PATTYS].
Sensitisation may result in allergic dermatitis responses including rash, itching, hives
or swelling of extremities.
TOXICITY AND IRRITATION
None assigned. Refer to individual constituents.
2-HYDROXYETHYL METHACRYLATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 10 of 18
Section 11 - TOXICOLOGICAL INFORMATION
Oral (rat) LD50: 5050 mg/kg Eye (rabbit): SEVERE *
Intraperitoneal (Mouse) LD50: 497 mg/kg
post- exposure
Oral (Guinea pig) LD50: 4680 mg/kg Skin (rabbit): non- irritating*
Intraperitoneal (Rat) LD50: 1250 mg/kg
Oral (Mouse) LD50: 3275 mg/kg
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria
or Quincke's oedema. The pathogenesis of contact eczema involves a cell-mediated (T
lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g.
contact urticaria, involve antibody-mediated immune reactions. The significance of the
contact allergen is not simply determined by its sensitisation potential: the
distribution of the substance and the opportunities for contact with it are equally
important. A weakly sensitising substance which is widely distributed can be a more
important allergen than one with stronger sensitising potential with which few
individuals come into contact. From a clinical point of view, substances are noteworthy
if they produce an allergic test reaction in more than 1% of the persons tested.
Asthma-like symptoms may continue for months or even years after exposure to the material
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.
Based on the available oncogenicity data and without a better understanding of the
carcinogenic mechanism the Health and Environmental Review Division (HERD), Office of
Toxic Substances (OTS), of the US EPA previously concluded that all chemicals that
contain the acrylate or methacrylate moiety (CH2=CHCOO or CH2=C(CH3)COO) should be
considered to be a carcinogenic hazard unless shown otherwise by adequate testing.
This position has now been revised and acrylates and methacrylates are no longer de facto
carcinogens.
Dermal (rabbit): >5000 mg/kg* Effects persist beyond 21 days
* Rohm & Haas
METHYLSTYRENE, MIXED ISOMERS:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 2255 mg/kg Skin (rabbit): 100% Moderate
Intraperitoneal (rat) LD50: 2324 mg/kg Eye (rabbit): 90 mg - Mild
Oral (mouse) LD50: 3160 mg/kg
Inhalation (mouse) LC50: 3020 mg/m?4h
Inhalation (Human) TCLo: 400 ppm/4h
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
Olfaction and eye effects recorded
SILICA AMORPHOUS:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 11 of 18
Section 11 - TOXICOLOGICAL INFORMATION
Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 3160 mg/kg Skin (rabbit): non- irritating *
Dermal (rabbit) LD50: >5000 mg/kg * Eye (rabbit): non- irritating *
Inhalation (rat) LC50: >0.139 mg/l/14h * *
[Grace]
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Reports indicate high/prolonged exposures to amorphous silicas induced lung
fibrosis in experimental animals; in some experiments these effects were
reversible. [PATTYS]
DIPROPOXY-P-TOLUIDINE:
None available.
SILICA CRYSTALLINE - QUARTZ:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Inhalation (human) LCLo: 0.3 mg/m?10Y Nil Reported
Inhalation (human) TCLo: 16 mppcf*/8H/17.9Y
Inhalation (rat) TCLo: 50 mg/m?6H/71W
WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as
Group 1: CARCINOGENIC TO HUMANS.
Intermittent; focal fibrosis,
(pneumoconiosis), cough, dyspnoea
Intermittent; liver - tumours.
* Millions of particles per cubic foot (based on impinger samples counted
by light field techniques).
NOTE : the physical nature of quartz in the product determines whether
it is likely to present a chronic health problem. To be a hazard
the material must enter the breathing zone as respirable particles.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
_______________ ____________ __________ __________ __________
methylstyrene, IARC:3
mixed isomers
silica amorphous IARC:3
silica IARC:1
crystalline -
quartz
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: methylstyrene,
mixed isomers Category: The substance is classified by IARC as Group 3: NOT
classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be
inadequate or limited in animal testing.
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: silica amorphous
Category: The substance is classified by IARC as Group 3: NOT classifiable as to its
carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in
animal testing.
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: silica
crystalline - quartz Category: WARNING: This substance has been classified by the IARC
as Group 1: CARCINOGENIC TO HUMANS.
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 12 of 18
Section 12 - ECOLOGICAL INFORMATION
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
2-HYDROXYETHYL METHACRYLATE:
Ecotoxicity of acrylates is a function of n-octanol/ water partition coefficient (log Pow,
log Kow). Compounds with a log Pow >5 exhibit simple narcosis, but at lower log Pow the
toxicity of acrylates is greater than predicted for simple narcotics.
If released to surface water, acrylic acid and the acrylic esters would all be rapidly
biodegraded while a portion would volatilise to the air. Acrylic acid was shown to
rapidly biodegrade aerobically in soil (t1/2 < 1 day). Volatilised acrylic
acid and acrylic esters are predicted to degrade rapidly by atmospheric photo-oxidation
with estimated half-lives of 2 to 24 h.
The mobility in soil of acrylic acid and its esters ranged from `medium' to `very high'.
Calculated bioconcentration factors ranged from 1 to 37, suggesting a low
bioconcentration potential. Acrylic acid and methyl acrylate showed limited
biodegradability in the five day biochemical oxygen demand (BOD5) test, while
ethyl acrylate and butyl acrylate were degraded easily (77% and 56%, respectively). Using
the OECD method 301D 28-d closed bottle test, degradability for acrylic acid was 81% at
28 days, while the acrylic esters ranged from 57% to 60%. Acrylic acid degraded rapidly
to carbon dioxide in soil (t1/2<1 day).
According to classification procedures developed by the US EPA, the acute toxicity of
acrylic acid to fish and invertebrates ranged from `slightly' toxic to `practically non-
toxic'. The acute toxicity of the acrylic esters was `moderately' toxic. Effects on algae
of these compounds could not be judged from static tests due to the extensive
biodegradation and volatilisation that occurred during the tests. Toxicity tests were
conducted using freshwater and marine fish, invertebrates, and algae. Acrylic acid effect
concentrations for fish and invertebrates ranged from 27 to 236 mg/l. Effect
concentrations (LC50 or EC50) for fish and invertebrates using
methyl acrylate, ethyl acrylate, and butyl acrylate ranged from 1.1 to 8.2 mg/l. The
chronic maximum acceptable toxicant concentration (MATC) for acrylic acid with Daphnia
magna was 27 mg/l based on length and young produced per adult reproduction day and for
ethyl acrylate was 0.29 mg/l based on both the reproductive and growth endpoints. MATC
values represent an approximate threshold of chronic effects to an organism.
Overall these studies show that acrylic acid and the acrylic esters studied can rapidly
biodegrade, have a low potential for persistence or bioaccumulation in the environment,
and have low to moderate toxicity.
C. A. Staples et al; Chemosphere Vol 40, January 2000, pp 29-38.
Substances containing unsaturated carbons are ubiquitous in indoor environments. They
result from many sources (see below). Most are reactive with environmental ozone and many
produce stable products which are thought to adversely affect human health.The potential
for surfaces in an enclosed space to facilitate reactions should be considered.
Source of unsaturated Unsaturated substances Major Stable Products
substances (Reactive Emissions) produced following reaction
with ozone.
Occupants (exhaled breath, Isoprene, nitric oxide, Methacrolein, methyl vinyl
ski oils, personal care squalene, unsaturated ketone, nitrogen dioxide,
products) sterols, oleic acid and other acetone, 6MHQ, geranyl
unsaturated fatty acids, acetone, 4OPA, formaldehyde,
unsaturated oxidation nonanol, decanal, 9- oxo-
products nonanoic acid, azelaic acid,
nonanoic acid.
Soft woods, wood flooring, Isoprene, limonene, alpha- Formaldehyde, 4- AMC,
including cypress, cedar and pinene, other terpenes and pinoaldehyde, pinic acid,
silver fir boards, sesquiterpenes pinonic acid, formic acid,
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 13 of 18
Section 12 - ECOLOGICAL INFORMATION
houseplants methacrolein, methyl vinyl
ketone, SOAs including
ultrafine particles
Carpets and carpet backing 4- Phenylcyclohexene, 4- Formaldehyde, acetaldehyde,
vinylcyclohexene, styrene, 2- benzaldehyde, hexanal,
ethylhexyl acrylate, nonanal, 2- nonenal
unsaturated fatty acids and
esters
Linoleum and paints/polishes Linoleic acid, linolenic acid Propanal, hexanal, nonanal,
containing linseed oil 2- heptenal, 2- nonenal, 2-
decenal, 1- pentene- 3- one,
propionic acid, n- butyric
acid
Latex paint Residual monomers Formaldehyde
Certain cleaning products, Limonene, alpha- pinene, Formaldehyde, acetaldehyde,
polishes, waxes, air terpinolene, alpha- glycoaldehyde, formic acid,
fresheners terpineol, linalool, linalyl acetic acid, hydrogen and
acetate and other terpenoids, organic peroxides, acetone,
longifolene and other benzaldehyde, 4- hydroxy- 4-
sesquiterpenes methyl- 5- hexen- 1- al, 5-
ethenyl- dihydro- 5- methyl-
2(3H)- furanone, 4- AMC, SOAs
including ultrafine particles
Natural rubber adhesive Isoprene, terpenes Formaldehyde, methacrolein,
methyl vinyl ketone
Photocopier toner, printed Styrene Formaldehyde, benzaldehyde
paper, styrene polymers
Environmental tobacco smoke Styrene, acrolein, nicotine Formaldehyde, benzaldehyde,
hexanal, glyoxal, N-
methylformamide,
nicotinaldehyde, cotinine
Soiled clothing, fabrics, Squalene, unsaturated Acetone, geranyl acetone,
bedding sterols, oleic acid and other 6MHO, 40PA, formaldehyde,
saturated fatty acids nonanal, decanal, 9- oxo-
nonanoic acid, azelaic acid,
nonanoic acid
Soiled particle filters Unsaturated fatty acids from Formaldehyde, nonanal, and
plant waxes, leaf litter, and other aldehydes; azelaic
other vegetative debris; acid; nonanoic acid; 9- oxo-
soot; diesel particles nonanoic acid and other oxo-
acids; compounds with mixed
functional groups (=O, - OH,
and - COOH)
Ventilation ducts and duct Unsaturated fatty acids and C5 to C10 aldehydes
liners esters, unsaturated oils,
neoprene
" Urban grime" Polycyclic aromatic Oxidized polycyclic aromatic
hydrocarbons hydrocarbons
Perfumes, colognes, essential Limonene, alpha- pinene, Formaldehyde, 4- AMC,
oils (e.g. lavender, linalool, linalyl acetate, acetone, 4- hydroxy- 4-
eucalyptus, tea tree) terpinene- 4- ol, gamma- methyl- 5- hexen- 1- al, 5-
terpinene ethenyl- dihydro- 5- methyl-
2(3H) furanone, SOAs
including ultrafine particles
Overall home emissions Limonene, alpha- pinene, Formaldehyde, 4- AMC,
styrene pinonaldehyde, acetone, pinic
acid, pinonic acid, formic
acid, benzaldehyde, SOAs
including ultrafine particles
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 14 of 18
Section 12 - ECOLOGICAL INFORMATION
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA,
4-oxopentanal, SOA, Secondary Organic Aerosols
Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
DO NOT discharge into sewer or waterways.
METHYLSTYRENE, MIXED ISOMERS:
BCF<100: 49
Water solubility (g/l): 89
Substances containing unsaturated carbons are ubiquitous in indoor environments. They
result from many sources (see below). Most are reactive with environmental ozone and many
produce stable products which are thought to adversely affect human health.The potential
for surfaces in an enclosed space to facilitate reactions should be considered.
Source of unsaturated Unsaturated substances Major Stable Products
substances (Reactive Emissions) produced following reaction
with ozone.
Occupants (exhaled breath, Isoprene, nitric oxide, Methacrolein, methyl vinyl
ski oils, personal care squalene, unsaturated ketone, nitrogen dioxide,
products) sterols, oleic acid and other acetone, 6MHQ, geranyl
unsaturated fatty acids, acetone, 4OPA, formaldehyde,
unsaturated oxidation nonanol, decanal, 9- oxo-
products nonanoic acid, azelaic acid,
nonanoic acid.
Soft woods, wood flooring, Isoprene, limonene, alpha- Formaldehyde, 4- AMC,
including cypress, cedar and pinene, other terpenes and pinoaldehyde, pinic acid,
silver fir boards, sesquiterpenes pinonic acid, formic acid,
houseplants methacrolein, methyl vinyl
ketone, SOAs including
ultrafine particles
Carpets and carpet backing 4- Phenylcyclohexene, 4- Formaldehyde, acetaldehyde,
vinylcyclohexene, styrene, 2- benzaldehyde, hexanal,
ethylhexyl acrylate, nonanal, 2- nonenal
unsaturated fatty acids and
esters
Linoleum and paints/polishes Linoleic acid, linolenic acid Propanal, hexanal, nonanal,
containing linseed oil 2- heptenal, 2- nonenal, 2-
decenal, 1- pentene- 3- one,
propionic acid, n- butyric
acid
Latex paint Residual monomers Formaldehyde
Certain cleaning products, Limonene, alpha- pinene, Formaldehyde, acetaldehyde,
polishes, waxes, air terpinolene, alpha- glycoaldehyde, formic acid,
fresheners terpineol, linalool, linalyl acetic acid, hydrogen and
acetate and other terpenoids, organic peroxides, acetone,
longifolene and other benzaldehyde, 4- hydroxy- 4-
sesquiterpenes methyl- 5- hexen- 1- al, 5-
ethenyl- dihydro- 5- methyl-
2(3H)- furanone, 4- AMC, SOAs
including ultrafine particles
Natural rubber adhesive Isoprene, terpenes Formaldehyde, methacrolein,
methyl vinyl ketone
Photocopier toner, printed Styrene Formaldehyde, benzaldehyde
paper, styrene polymers
Environmental tobacco smoke Styrene, acrolein, nicotine Formaldehyde, benzaldehyde,
hexanal, glyoxal, N-
methylformamide,
nicotinaldehyde, cotinine
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 15 of 18
Section 12 - ECOLOGICAL INFORMATION
Soiled clothing, fabrics, Squalene, unsaturated Acetone, geranyl acetone,
bedding sterols, oleic acid and other 6MHO, 40PA, formaldehyde,
saturated fatty acids nonanal, decanal, 9- oxo-
nonanoic acid, azelaic acid,
nonanoic acid
Soiled particle filters Unsaturated fatty acids from Formaldehyde, nonanal, and
plant waxes, leaf litter, and other aldehydes; azelaic
other vegetative debris; acid; nonanoic acid; 9- oxo-
soot; diesel particles nonanoic acid and other oxo-
acids; compounds with mixed
functional groups (=O, - OH,
and - COOH)
Ventilation ducts and duct Unsaturated fatty acids and C5 to C10 aldehydes
liners esters, unsaturated oils,
neoprene
" Urban grime" Polycyclic aromatic Oxidized polycyclic aromatic
hydrocarbons hydrocarbons
Perfumes, colognes, essential Limonene, alpha- pinene, Formaldehyde, 4- AMC,
oils (e.g. lavender, linalool, linalyl acetate, acetone, 4- hydroxy- 4-
eucalyptus, tea tree) terpinene- 4- ol, gamma- methyl- 5- hexen- 1- al, 5-
terpinene ethenyl- dihydro- 5- methyl-
2(3H) furanone, SOAs
including ultrafine particles
Overall home emissions Limonene, alpha- pinene, Formaldehyde, 4- AMC,
styrene pinonaldehyde, acetone, pinic
acid, pinonic acid, formic
acid, benzaldehyde, SOAs
including ultrafine particles
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA,
4-oxopentanal, SOA, Secondary Organic Aerosols
Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
SILICA AMORPHOUS:
DO NOT discharge into sewer or waterways.
Aquatic toxicity (Daphnia magna) 24h EC50: >1000 mg/l
Fish toxicity (Brachydanio rerio) 96h LC50: >10,000 mg/l [Grace]
SILICA CRYSTALLINE - QUARTZ:
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
?Recycle wherever possible or consult manufacturer for recycling options.
?Consult State Land Waste Management Authority for disposal.
?Bury residue in an authorised landfill.
?Recycle containers if possible, or dispose of in an authorised landfill.
?Containers may still present a chemical hazard/ danger when empty.
?Return to supplier for reuse/ recycling if possible.
Otherwise:
?If container can not be cleaned sufficiently well to ensure that residuals do not
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 16 of 18
Section 13 - DISPOSAL CONSIDERATIONS
remain or if the container cannot be used to store the same product, then puncture
containers, to prevent re-use, and bury at an authorised landfill.
?Where possible retain label warnings and MSDS and observe all notices pertaining to the
product.
Section 14 - TRANSPORTATION INFORMATION
Labels Required:
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
AC100e Part A (CAS: None):
No regulations applicable
2-hydroxyethyl methacrylate (CAS: 868-77-9) is found on the following regulatory lists;
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
methylstyrene, mixed isomers (CAS: 1321-45-5) is found on the following regulatory lists;
Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported
Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
International Air Transport Association (IATA) Dangerous Goods Regulations
methylstyrene, mixed isomers (CAS: 25013-15-4) is found on the following regulatory lists;
Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported
Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported
Australia Exposure Standards
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
IMO IBC Code Chapter 17: Summary of minimum requirements
International Agency for Research on Cancer (IARC) Carcinogens
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
silica amorphous (CAS: 7631-86-9) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
IMO IBC Code Chapter 17: Summary of minimum requirements
International Agency for Research on Cancer (IARC) Carcinogens
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
silica amorphous (CAS: 112945-52-5) is found on the following regulatory lists;
Australia - Victoria Occupational Health and Safety Regulations - Schedule 5 Hazardous Substances: Substances Prohibited for Specified Uses
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
IMO IBC Code Chapter 17: Summary of minimum requirements
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
dipropoxy-p-toluidine (CAS: 38668-48-3) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
silica crystalline - quartz (CAS: 14808-60-7) is found on the following regulatory lists;
Australia - New South Wales Hazardous Substances Prohibited for Specific Uses
Australia - New South Wales Hazardous Substances Requiring Health Surveillance
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 17 of 18
Section 15 - REGULATORY INFORMATION
Australia - South Australia Hazardous Substances Requiring Health Surveillance
Australia - Tasmania Hazardous Substances Prohibited for Specified Uses
Australia - Tasmania Hazardous Substances Requiring Health Surveillance
Australia - Western Australia Hazardous Substances Requiring Health Surveillance
Australia Exposure Standards
Australia Hazardous Substances
Australia Hazardous Substances Requiring Health Surveillance
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Occupational Health and Safety (Commonwealth Employment) (National Standards) Regulations 1994 - Hazardous Substances Requiring Health Surveillance
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO Provisioanl Categorization of Liquid Substances
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for silica crystalline - quartz as CAS: 122304-48-7, CAS: 122304-49-8, CAS: 12425-26-2, CAS: 1317-79-9, CAS: 70594-95-5, CAS: 87347-84-0.
Section 16 - OTHER INFORMATION
Denmark Advisory list for selfclassification of dangerous substances
Substance CAS Suggested codes
methylstyrene, mixed isomers 25013- 15- R43
4
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
methylstyrene, mixed isomers 1321- 45- 5, 25013- 15- 4
silica amorphous 7631- 86- 9, 112945- 52- 5
silica crystalline - quartz 14808- 60- 7, 122304- 48- 7, 122304- 49- 8,
12425- 26- 2, 1317- 79- 9, 70594- 95- 5,
87347- 84- 0
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 260 mg/m?br>
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m? (%)
2-hydroxyethyl methacrylate 50.00 260.0000 19.0
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 6-Dec-2007
continued...
AC100E PART A
Chemwatch Material Safety Data Sheet
Issue Date: 6-Dec-2007 CHEMWATCH 4936-72
NC317ECP Version No:2.0
CD 2008/1 Page 18 of 18
Section 16 - OTHER INFORMATION
Print Date: 19-Mar-2008
|