Page 1/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
* 1 Identification of substance:
?Product details:
?Trade name: Nutlock NLK 34700
?Article number: 34700
?Application of the substance / the preparation Adhesives
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
Monday - Thursday 8.30am - 5.30pm, Friday 9.00am - 3.00pm
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@
?
G Xi Irritant
?Information pertaining to particular dangers for man and environment
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 43 May cause sensitisation by skin contact.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Warning
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H317 - May cause an allergic skin reaction.
H335 - May cause respiratory irritation.
?Prevention:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
?Response:
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
(Contd. on page 2)
GB
Page 2/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Nutlock NLK 34700
(Contd. of page 1)
?Dangerous components:
CAS: 25852-47-5 Methacrylic diester of polyethylene gylcol 50-70%
? Xi; R 36/37/38
G
@
Warning: ~ 3.2/2, 3.3/2, 3.8/3
CAS: 868-77-9 2-hydroxyethyl methacrylate 10-30%
EINECS: 212-782-2 ? Xi; R 36/38-43
@
G
Warning: ~ 3.2/2, 3.3/2, 3.4.S/1
CAS: 80-15-9 a,a -dimethylbenzyl hydroperoxide <1%
EINECS: 201-254-7 ? C; R 34
@
A
Danger: ~ 3.1.I/3; ~ 3.2/1B
Warning: ~ 2.15/E; ~ 3.9/2; 3.1.O/4, 3.1.D/4
~ 4.1.C/2
* 4 First aid measures
?General information Instantly remove any clothing soiled by the product.
?After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness bring patient into stable side position for transport.
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
Do not pull solidified product away from the skin.
Seek immediate medical advice.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
Do not induce vomiting; instantly call for medical help.
Rinse out mouth and then drink plenty of water.
* 5 Fire fighting measures
?Suitable extinguishing agents Use fire fighting measures that suit the environment.
?Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
?Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
?Additional information Cool endangered containers with water spray jet.
* 6 Accidental release measures
?Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
?Measures for environmental protection:
Inform respective authorities in case product reaches water or sewage system.
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable containers.
Dispose of contaminated material as waste according to item 13.
* 7 Handling and storage
?Handling
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle container with care.
?Information about protection against explosions and fires: No special measures required.
(Contd. on page 3)
GB
Page 3/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Nutlock NLK 34700
(Contd. of page 2)
?Storage
?Requirements to be met by storerooms and containers: Store in cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Protect from heat and direct sunlight.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Take off immediately all contaminated clothing
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
?Breathing equipment: Use breathing protection in case of insufficient ventilation.
?Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Safety glasses
?Body protection: Protective work clothing.
* 9 Physical and chemical properties:
?General Information
Form: Fluid
Colour: Blue
Odour: Characteristic
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
?Flash point: 90癈
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive.
?Density at 20癈 1.05 g/cm?br>
?Solubility in / Miscibility with
Water: Unsoluble
?Solvent content:
Organic solvents: 49g/l VOC
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
(Contd. on page 4)
GB
Page 4/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Nutlock NLK 34700
(Contd. of page 3)
?Materials to be avoided: Strong acids and oxidizing agents
?Dangerous reactions No dangerous reactions known
?Dangerous products of decomposition: Carbon monoxide and carbon dioxide
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
a,a -dimethylbenzyl hydroperoxide
Oral LD50 382 mg/kg (rat)
Dermal LD50 500 mg/kg (rat)
Inhalative LC50/4 h 220 mg/l (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
Irritant
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
?Sensitisation May cause sensitisation by skin contact.
* 12 Ecological information:
?Additional ecological information:
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
?Product:
?Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: N/A
?Maritime transport IMDG:
?IMDG Class: N/A
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: N/A
?UN "Model Regulation": N/A
* 15 Regulatory information
?Designation according to EC guidelines: Observe the normal safety regulations when handling chemicals
(Contd. on page 5)
GB
Page 5/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Nutlock NLK 34700
(Contd. of page 4)
?Code letter and hazard designation of product:
@
?
G Xi Irritant
?Hazard-determining components of labelling:
2-hydroxyethyl methacrylate
?Risk phrases:
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitisation by skin contact.
?Safety phrases:
24 Avoid contact with skin.
37 Wear suitable gloves.
60 This material and its container must be disposed of as hazardous waste.
?National regulations
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
34 Causes burns.
36/37/38 Irritating to eyes, respiratory system and skin.
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
?Department issuing data specification sheet: Environment protection department.
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB
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