MATERIAL SAFETY DATA SHEET
PRODUCT NAME: STYROSAFE RESIN HMIS CODES: H F R P
PRODUCT CODE: 30P-121 232H
D.O.T. PROPER SHIPPING NAME: RESIN SOLUTION, 3, UN1866, PGIII
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURER'S NAME: DURA TECHNOLOGIES, INC.
ADDRESS : 2720 SOUTH WILLOW AVE.
BLOOMINGTON, CA 92316
EMERGENCY PHONE : 800-424-9300 DATE PRINTED : 02/15/08
INFORMATION PHONE : 909-877-8477 NAME OF PREPARER : Richard Stewart
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT
-------------------------------------------------------------------------------------
* STYRENE 100-42-5 4.5 70 10-30%
OSHA TWA: 50 PPM ;ACGIH TWA 20 PPM
CERCLA RQ: 1000 LBS ;DOT RQ: 3336 LBS
601-026-00-0 CAS: 100-42-5 EC: 202-851-5
Xn,Xi; R10-20-36/38
2-Hydroxyethyl Methacrylate; 868-77-9 10-30%
607-124-00-X CAS: 868-77-9 EC: 202-809-6
Xi; R36/38-43
* Indicates toxic chemical(s) subject to the reporting requirements of section
313 of Title III and of 40 CFR 372.
NOTE: A ZERO IN THE WEIGHT PERCENT COLUMN INDICATES THAT THERE IS LESS THAN
ONE-HALF OF ONE PERCENT PRESENT.
WARNING ! THERE ARE CERTIAN HEALTH HAZARDS INVOLVED WITH HANDLING AND STORING
THIS MATERIAL. PLEASE READ AND FOLLOW THE SAFTY RECOMMENDATIONS PUT FORWARD ON
THIS MSDS.
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING RANGE: 295 deg?F SPECIFIC GRAVITY (H2O=1): 1.11
VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER
COATING VOC: 2.41 lb/gl
MATERIAL V.O.C.: 2.41 lb/gl
The VOC is calculated using the assumption that ONE HUNDRED percent of the
styrene monomer will EVAPORATE. You should use the emissions factor approved by
the Regulatory Agency responsible for air quality in your area for reporting the
emissions of MONOMERS.
SOLUBILITY IN WATER: negligible
APPEARANCE AND ODOR: POLYESTER COATING WITH CHARACTERISTIC STYRENE ODOR
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT: 90 deg F METHOD USED: TCC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1.1 UPPER: 6.1
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG
SPECIAL FIREFIGHTING PROCEDURES
Wear full protective equipment including SELF-CONTAINED BREATHING APPARATUS. If
water is used, fog nozzles are preferable. Water may be used to cool containers
to prevent pressure build-up or auto ignition. Water spray may be ineffective.
WARNING: Burning liquid chemicals are usually lighter than water and will float
spreading flames as the water flows from the site of the fire fighting efforts.
WARNING!: Stay away from hot drums due to explosion hazard.
UNUSUAL FIRE AND EXPLOSION HAZARDS
At high temperatures this material may self polymerize. If polymerization
occurs, there is the possibility of violent rupture of sealed containers.
Styrene vapors are uninhibited and may form polymers in the vents or flame
arrestors of storage tanks rendering them useless. These vents should be
inspected frequently for blockage. Vapors may cause flash fires. Keep storage
containers tightly closed and isolated from heat, electrical equipment, sparks
and flames.
======================== SECTION V - REACTIVITY DATA =======================
STABILITY: STABLE
CONDITIONS TO AVOID
AVOID HEAT, Sparks or open flames. Never allow the PROMOTER/ACCELERATOR to come
in direct contact with the CATALYST (When mixed in an undiluted form, cobalt and
peroxide will react violently and cause an explosion). Do not use plastic or
non-conducting containers to store and handle flammable liquids. These
containers can not be properly grounded and static charge may build up in the
MATERIAL SAFETY DATA SHET
flammable liquid.
INCOMPATIBILITY (MATERIALS TO AVOID)
Avoid contact with strong acids, oxidizers (bleaches), and strong bases (caustic
soda).
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
If ignited this product will release carbon dioxide, carbon monoxide, and some
organic acids. Do not breathe fumes.
HAZARDOUS POLYMERIZATION: MAY OCCUR
==================== SECTION VI - HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
WARNING: Based on studies of components similar to the ones used in this
coating, it has been shown that Acrolein (TLV:0.1) and Acetaldehyde (TLV: 100
PPM) can be released during the curing of the product.
The excessive inhalation of vapors may cause nasal and respiratory irritation,
dizziness, weakness, fatigue, nausea, and headaches. The symptoms of inhalation
exposure are very similar to common complaints caused by colds and other minor
medical problems and must be monitored scrupulously to detect the appearance of
overexposure.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
EYE CONTACT: This material can be irritating to the eyes. The symptoms of this
are tearing, redness, and discomfort. SKIN CONTACT: This material may cause
severe skin irritation. Symptoms include redness, burning drying and cracking.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
Exposure by skin contact can cause severe skin irritation. Prolonged or
repeated exposure may induce redness, burning, and cracking of the skin. Skin
absorption is possible but no adverse effects are expected from this route of
exposure under normal conditions of handling and use.
INGESTION HEALTH RISKS AND SYMPTOMS OF OVEREXPOSURE
Swallowing can cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Aspiration of the liquid material can cause pneumonitis which can be FATAL.
Care should be taken that such aspiration DOES NOT OCCUR SHOULD THE VICTIM
VOMIT.
HEALTH HAZARDS (ACUTE AND CHRONIC)
Reports have associated repeated or prolonged occupational exposure to solvents
with permanent brain and nervous system damage, and liver or kidney atrophy.
Intentional misuse by concentrating and inhaling the vapors can be fatal. This
material has not been tested as a whole for health effects. WARNING! Although
all intentional PROP 65 chemicals will be listed, THERE MAY BE DETECTABLE LEVELS
OF UNINTENTIONAL CHEMICALS WHICH ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM PRESENT IN THIS PRODUCT.
TARGET ORGAN INFORMATION:
Overexposure to this material has been suggested as a cause of the following
effects in laboratory animals, and may aggravate pre-existing disorders of these
organs in humans: mild, reversible kidney effects, effects on hearing
respiratory tract damage, testis damage, and liver damage. Overexposure to this
material has been suggested as a cause of the following effects in humans and
may aggravate pre-existing disorders of these organs: central nervous system
effects, effects on hearing, respiratory tract damage.
CARCINOGENICITY:
NTP CARCINOGEN: No IARC MONOGRAPHS: No OSHA REGULATED: No
PROPOSITION 65: YES
WARNING: TOLUENE IS AN IMPURITY IN XYLENE. THIS PRODUCT CONTAINS TOLUENE A
CHEMICAL KNOWN BY THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. WARNING: Benzene may be present in styrene monomer as an
impurity. This product contains styrene monomer which is believed to be free of
benzene. WARNING: BASED ON THE STUDY OF COMPONENTS SIMILIAR TO THE ONES USED
IN THIS COATING, IT HAS BEEN SHOWN THAT ACETALDEHYDE (TLV: 100 PPM) CAN BE
RELEASED DURING THE CURING OF THE PRODUCT. ACETALDEHYDE IS KNOW BY THE STATE OF
CALIFORNIA TO CAUSE CANCER.
WARNING! THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER STATES THAT STYRENE IS
'POSSIBLY CARCINOGENIC TO HUMANS' (GROUP 2B) BASED ON 'INADEQUATE EVIDENCE' IN
HUMANS, 'LIMITED EVIDENCE' IN ANIMALS, AND OTHER 'RELEVANT DATA'.
THIS MATERIAL CONTAINS OSHA REGULATED HAZARDOUS MATERIALS.
MATERIAL SAFETY DATA SHEET
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Respiratory problems such as asthma; Skin disorders such as dermatitis; eye
disorders or overly sensitive eyes.
EMERGENCY AND FIRST AID PROCEDURES
FOR ANY OVEREXPOSURE MOVE VICTIM TO FRESH AIR AND SEEK MEDICAL AID. EYE CONTACT:
Immediately flush eyes with warm clean water. If symptoms persists seek medical
attention. SKIN CONTACT: Immediately flush contaminated skin with water using
mild soap if necessary. Remove all contaminated clothing and do not reuse
clothes until thoroughly clean. INHALATION OVEREXPOSURE: Where breathing has
stopped give artificial respiration. If breathing is difficult have qualified
persons give medical oxygen. INGESTION: Give victim water to dilute chemical.
NEVER induce vomiting in an unconscious or convulsing victim. aspiration of
this material may occur during vomiting and can lead to lung damage or death.
Seek immediate medical help
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Evacuate personnel, remove sources of ignition, provide ventilation, equip
cleanup crew with safety equipment, contain the spill with dikes, then use an
absorbent or vacuum equipment to remove material. Store waste in a sealed
container. Use only nonsparking tools during clean up. Do not allow this
material to flow into the environment. If the spill exceeds the reportable
quantity notify EPA and DOT officials.
WASTE DISPOSAL METHOD
Dispose of in accordance with Local, State and Federal regulations. Closed
containers may explode if incinerated and all wastes should be incinerated in
approved facilities only. In it's uncatalyzed liquid state this material is a
hazardous waste due to its flammability and should not be released into the
environment. The preferred waste management option is to send material that has
been declared waste to a licensed or permitted recycler, reclaimer, or
incinerator. Use proper waste manifests and permitted haulers for transportation
of and material which has been declared a waste. Waste disposal and
characterization are the responsibility of the waste generator.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Do not store above 120 deg. F. Store large quantities in buildings designed to
comply with Osha, EPA, and local fire department regulations. KEEP AWAY FROM
HEAT, SPARKS AND FLAMES. Keep containers closed and upright when not in use to
prevent the escape of fumes and liquid into the work or storage area.
Inspect containers frequently to detect any possible damage or deterioration
which might cause release of the material to the environment?
Polymerization of this coating during storage may cause the container to burst
explosively. STORE IN COOL DRY AREA.
OTHER PRECAUTIONS
Containers should be grounded when the material is being transferred/mixed to
prevent static build up. Empty containers retain all of the hazardous
characteristics of the material itself and should be handled carefully until
they are thoroughly clean or destroyed. Large quantities of this material
should be stored only in buildings which conform to OSHA standards. If any
materials (such as catalysts, colorants, or thinners)_ are added to this product
read all relevant MSDS as the mixture will retain ALL of the hazardous
characteristics of the chemicals added.
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY PROTECTION
During the application of this product or at any time vapors escape into the
work space, exposed persons should use appropriate cartridge respirators
(NIOSH/MSHA approved) or in instances of high concentrations, air provided
breathing apparatus. Refer to OSHA regulations to maintain workspace safety. If
MATERIAL SAFETY DATA SHEET
respirators are required, employees must be trained to use the respirators, the
fit of the respirator must be tested, and the employee's lung capacity must be
tested for ability to use the respirator. Respiratory protection should be used
during the curing, cutting, sanding, or polishing of this product. If
Respirators are required they must be carefully selected according to the
conditions present at customers location.
VENTILATION
Clean air dilution and local exhaust may be used to maintain the vapor
concentration below current exposure limits and 20% below the LEL, except in
confined areas where forced ventilation may be necessary. Refer to OSHA
guidelines for handling these types of materials.
PROTECTIVE GLOVES
Solvent impermeable gloves should be worn to prevent physical contact with the
product.
EYE PROTECTION
To protect your eyes, wear safety glasses with side shields, chemical goggles, or
face shields.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Solvent impermeable, protective clothing should be worn to minimize skin contact
with this product. Emergency showers and eye wash stations should be provided in
the work space. Wear steel toed shoes when handling heavy objects.
WORK/HYGIENIC PRACTICES
Inspect Fire extinguishers at regular intervals. Keep work space clean. Retain
safety features on all equipment.
================ SECTION IX - OTHER REGULATORY INFORMATION ================
WHMIS INFO.:
Directive 2000/39/EC (Occupational exposure limit values). Regulation (EC) No 1907/2006
(REACH).
Symbols:
Xn Harmful
R Phrases:
R10 Flammable.
R20 Harmful by inhalation.
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
S Phrases:
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S37 Wear suitable gloves.
S43 In case of fire, use nebulized water , CO2 ,light water , dry chemical powder.
Contents:
HEMA
Styrene
========================= SECTION X - DISCLAIMER ==========================
To the best of our knowledge this MSDS is accurate. To the extent allowed by
law, this statement is made in lieu of any other warranties, expressed or
implied including but not limited to any implied warranty of merchantability or
fitness for a particular purpose and is in lieu of any other obligations or
liability on the part of DURA TECHNOLOGIES, INC.
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