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MSDS Material Safety Data Sheet
CAS

85-86-9

File Name: 85-86.asp

                             SIGMA-ALDRICH

MATERIAL SAFETY DATA SHEET

Date Printed: 11/10/2005
Date Updated: 04/04/2004
Version 1.3


Section 1 - Product and Company Information

Product Name SUDAN III
Product Number S4131
Brand SIAL

Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052

Section 2 - Composition/Information on Ingredient

Substance Name CAS # SARA 313
SUDAN III 85-86-9 No

Formula C22H16N4O
Synonyms Atul Oil Red G *
Benzeneazobenzeneazo-beta-naphthol * Brasilazina
Oil Scarlet * Cerasin Red * Cerasinrot *
Cerotinscharlach R * Certiqual Oil Red * Cerven
rozpoustedlova 23 (Czech) * C.I. 23 * C.I. 26100
* C.I. Solvent Red 23 * D & C Red No. 17 * Fast
Oil Scarlet III * Fat Red (bluish) * Fat Red HRR
* Fat Red R * Fat Red RS * Fat Scarlet LB * Fat
Soluble Red ZH * Grasal Brilliant Red G *
Fettponceau G * Fettscharlach * Fettscharlach LB
* Motirot 2R * Oil Red 6566 * Oil Red AS * Oil
Red 3G * Oil Scarlet G * Organol Red BS * Organol
Scarlet *
1-((4-(Phenylazo)phenyl)azo)-2-naphthalenol *
1-((p-Phenylazo)phenyl)azo-2-naphthol *
Pyronalrot B * 111440 Red * Red No. 225 * Red ZH
* Rouge cerasine * Scarlet B Fat Soluble *
Schultz No. 31 * Silotras Scarlet TB * Somalia
Red III * Soudan III * Stearix Scarlet * Sudan
III * Sudan III (G) * Sudan P III * Sudan Red III
* Tetrazobenzene-beta-naphthol * Toney Red
RTECS Number: QK4250000

Section 3 - Hazards Identification

EMERGENCY OVERVIEW
Caution: Avoid contact and inhalation.

HMIS RATING
HEALTH: 1
FLAMMABILITY: 0
REACTIVITY: 0

NFPA RATING
HEALTH: 1
FLAMMABILITY: 0
REACTIVITY: 0

For additional information on toxicity, please refer to Section 11.

Section 4 - First Aid Measures

ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

INHALATION EXPOSURE
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.

DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.

EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.

Section 5 - Fire Fighting Measures

FLASH POINT
N/A

AUTOIGNITION TEMP
N/A

FLAMMABILITY
N/A

EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.

FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.

Section 6 - Accidental Release Measures

PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Exercise appropriate precautions to minimize direct contact with
skin or eyes and prevent inhalation of dust.

METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.

Section 7 - Handling and Storage

HANDLING
User Exposure: Avoid inhalation. Avoid contact with eyes, skin,
and clothing. Avoid prolonged or repeated exposure.



SIAL - S4131 www.sigma-aldrich.com Page 2
STORAGE
Suitable: Keep tightly closed.

Section 8 - Exposure Controls / PPE

ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.

PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Wear dust mask.
Hand: Protective gloves.
Eye: Chemical safety goggles.

GENERAL HYGIENE MEASURES
Wash thoroughly after handling.

Section 9 - Physical/Chemical Properties

Appearance Physical State: Solid
Color: Deep red

Property Value At Temperature or Pressure

Molecular Weight 352.4 AMU
pH N/A
BP/BP Range N/A
MP/MP Range 199 癈
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A

N/A = not available

Section 10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.

HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nitrogen oxides Carbon monoxide,


SIAL - S4131 www.sigma-aldrich.com Page 3
Carbon dioxide.

HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

Section 11 - Toxicological Information

ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.

SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.

CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that is not
classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.

IARC CARCINOGEN LIST

Rating: Group 3

CHRONIC EXPOSURE - MUTAGEN

Species: Hamster Mouse
Route: Oral
Dose: 20 UMOL/L 1 GM/KG
Exposure Time: 5H
Cell Type: ovary
Mutation test: Cytogenetic analysis DNA damage

Species: Hamster
Dose: 20 UMOL/L
Exposure Time: 5H
Cell Type: ovary
Mutation test: Cytogenetic analysis

Section 12 - Ecological Information

No data available.

Section 13 - Disposal Considerations

APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

Section 14 - Transport Information

DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is
considered to be non-hazardous for transport.


SIAL - S4131 www.sigma-aldrich.com Page 4
IATA
Non-Hazardous for Air Transport: Non-hazardous for air
transport.

Section 15 - Regulatory Information

EU ADDITIONAL CLASSIFICATION
S: 22-24/25
Safety Statements: Do not breathe dust. Avoid contact with skin
and eyes.

US CLASSIFICATION AND LABEL TEXT
US Statements: Caution: Avoid contact and inhalation.

UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
TSCA INVENTORY ITEM: Yes Yes

CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No

Section 16 - Other Information

DISCLAIMER
For R&D use only. Not for drug, household or other uses.

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.




SIAL - S4131 www.sigma-aldrich.com Page 5

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