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CAS

78-93-3 108-95-2 95-48-7 50-00-0

File Name: 78-93-3_108-95-2_95-48-7_50-00.asp

ASHLAND                                                                         Page: 1
SAFETY DATA SHEET Revision Date: 03/26/2007
Print Date: 04/27/07
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version 1.1

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency Telephone Number 1-800-ASHLAND
(1-800-274-5263)

Product Name PLIOBOND?20 ADHESIVE (GENERAL PURPOSE/INDUSTRIAL)
Product Code 571656
Product Use Description No Data

2. HAZARDS IDENTIFICATION


Emergency Overview

Appearance: liquid, tan

WARNING! Flammable Liquid, Highly toxic by inhalation, Toxic by ingestion, Toxic
by skin absorption, Corrosive to skin, Corrosive to eyes, Carcinogen.

Potential Health Effects

Routes of Exposure
Inhalation, Skin contact, Eye contact, Ingestion

Eye Contact
Can cause eye irritation. Symptoms include stinging, tearing, redness, and
swelling of eyes.

Skin Contact
Can cause skin irritation. Prolonged or repeated contact may dry the skin.
Symptoms may include redness, burning, and drying and cracking of skin, burns and
other skin damage. Additional symptoms of skin contact may include: allergic skin
reaction (delayed skin rash which may be followed by blistering, scaling and other skin
effects)

Ingestion
Swallowing small amounts of this material during normal handling is not likely to
cause harmful effects. Swallowing large amounts may be harmful. This material can get
into the lungs during swallowing or vomiting. This results in lung inflammation and
other lung injury.


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Page 2
Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

Ingestion
Breathing of vapor or mist is possible. Breathing small amounts of this material
during normal handling is not likely to cause harmful effects. Breathing large amounts
may be harmful. Symptoms are not expected at air concentrations below the
recommended exposure limits, if applicable (see Section 8.).

Aggravated Medical Condition
Preexisting disorders of the following organs (or organ systems) may be
aggravated by exposure to this material: skin, lung, (for example, asthma-like conditions)

Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include: stomach or intestinal upset
(nausea, vomiting, and diarrhea), irritation (nose, throat, airways), central nervous system
depression (dizziness, drowsiness, weakness, fatigue, nausea, headache,
unconsciousness)

Target Organs
Based on animal studies, exposure to methyl ethyl ketone (MEK) increases the
onset of peripheral neuropathy caused by exposure to methyl butyl ketone (MBK), and/or
n-hexane, and/or ethyl butylketone. MEK alone has not been shown to cause peripheral
neuropathy. Overexposure to this material (or its components) has been suggested as a
cause of the following effect in laboratory animals: mild, reversible liver effects, mild,
reversible kidney effects.

Carcinogenicity
Human studies have associated nasopharyngeal cancers (area of the upper throat
behind the nose) and possibly other respiratory cancers (nasal cavity and sinuses) with
formaldehyde exposure in the workplace. Although the evidence is not conclusive, some
studies suggest an association between workplace formaldehyde exposure and leukemia.
In studies in rats, inhalation of formaldehyde has caused nasal tumors, while ingestion in
drinking water has caused leukemia and gastrointestinal tract tumors. Formaldehyde is
listed as a carcinogen by the International Agency for Research on Cancer (IARC), the
National Toxicology Program (NTP) and the Occupational Safety and Health
Administration (OSHA).

Reproductive Hazard
This material (or a component) has been shown to cause harm to the fetus in
laboratory animal studies. The relevance of these findings to humans is uncertain.

Other Information
No data



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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1


3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Concentration
METHYL ETHYL KETONE 78-93-3 >=70-<80%
PHENOL 108-95-2 >=1-<1.5%
ORTHO CRESOL 95-48-7 >=0.1-<0.5%
FORMALDEHYDE 50-00-0 >=0.1-<0.5%

4. FIRST AID MEASURES


Eyes
If symptoms develop, move individual away from exposure and into fresh air.
Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is
any visual difficulty, seek medical attention.

Skin
Remove contaminated clothing. Flush exposed area with large amounts of water.
If skin is damaged, seek immediate medical attention. If skin is not damaged and
symptoms persist, seek medical attention. Launder clothing before reuse.

Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give
anything by mouth; place individual on the left side with the head down. Contact a
physician, medical facility, or poison control center for advice about whether to induce
vomiting. If possible, do not leave individual unattended.

Inhalation
If symptoms develop, immediately move individual away from exposure and into
fresh air. Seek immediate medical attention; keep person warm and quiet. If person is
not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.

Notes to Physician
Hazards: This material is an aspiration hazard. Potential danger from aspiration
must be weighed against possible oral toxicity (See Section 2 ?Swallowing) when
deciding whether to induce vomiting.
Treatment: No information available.
5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media
Water mist, dry powder, foam, carbon dioxide (CO2)

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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

Hazardous Combustion Products
May form; carbon dioxide and carbon monoxide, hydrogen cyanide, nitrogen
compounds, phenols, various hydrocarbons

Precautions for Fire-Fighting
Material is volatile and readily gives off vapors which may travel along the
ground or be moved by ventilation and ignited by pilot lights, flames, sparks, heaters,
smoking, electric motors, static discharge or other ignition sources at locations near the
material handling point.

Flammability Class for Flammable Liquids
Flammable Liquid Class 1B

6. ACCIDENTAL RELEASE MEASURES


Personal Precautions
For personal protection see Section 8. Eliminate all ignition sources (flares,
flames including pilot lights, electrical sparks). Persons not wearing protective equipment
should be excluded from area of spill until clean-up has been completed. Stop spill at
source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent
from spreading. If runoff occurs, notify authorities as required. Pump or vacuum
transfer spilled product to clean containers for recovery. Absorb unrecoverable product.
Transfer contaminated absorbent, soil and other materials to containers for disposal.

Environmental Precautions
No data

Methods for Cleaning Up
Absorb liquid on vermiculite, floor absorbent or other absorbent material.

7. HANDLING AND STORAGE

Handling
Containers of this material may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard precautions
given in the data sheet must be observed. Static ignition hazard can result from handling
and use. Electrically bond and ground all containers, personnel and equipment before
transfer or use of material. Special precautions may be necessary to dissipate static
electricity for non-conductive containers. Use proper bonding and grounding during
product transfer as described in National Fire Protection Association document NFP 77.



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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1
Storage
No data
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Exposure Guidelines
METHYL ETHYL KETONE 78-93-3

ACCIH time weighed average 200 ppm
ACGIH Short term exposure limit 300 ppm
NIOSH Recommended exposure limit 200 ppm
(REL):
NIOSH Recommended exposure limit 590 mg/m3
(REL):
NIOSH Short term exposure limit 300 ppm
NIOSH Short term exposure limit 885 mg/m3
OSHA Z1 Permissible exposure limit 200 ppm
OSHA Z1 Permissible exposure limit 590 mg/m3

PHENOL 108-95-2

ACCIH time weighed average 5 ppm
NIOSH Recommended exposure limit 5 ppm
(REL):
NIOSH Recommended exposure limit 19 mg/m3
(REL):
NIOSH Ceiling Limit Value and Time 15.6 ppm
Period (if specified):
NIOSH Ceiling Limit Value and Time 60 mg/m3
Period (if specified):
OSHA Z1 Permissible exposure limit 5 ppm
OSHA Z1 Permissible exposure limit 19 mg/m3


FORMALDEHYDE 50-00-0

ACCIH Ceiling Limit Value 0.3 ppm
NIOSH Recommended exposure limit 0.016 ppm
(REL):
NIOSH Recommended exposure limit 0.016 ppm
(REL):
NIOSH Ceiling Limit Value and Time 0.1 ppm
Period (if specified):
NIOSH Ceiling Limit Value and Time 0.1 ppm
Period (if specified):
OSHA timed weighted average 0.75 ppm
OSHA Short term exposure limit 19 mg/m3
OSHA OSHA Action level: 0.5 ppm

General Advice
These recommendations provide general guidance for handling this product.
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical

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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

concentrations and ventilation. It is ultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.

Exposure Controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below TLV(s).

Eye Protection
Chemical splash goggles in compliance with OSHA regulations are advised;
however, OSHA regulations also permit other type safety glasses. Consult your safety
representative.

Skin and Body Protection
To prevent repeated or prolonged skin contact, wear impervious clothing and
boots. Wear resistant gloves such as: Natural Rubber

Respiratory Protection
If workplace exposure limit(s) of product exceeded (see exposure guidelines), a
NIOSH approved air-purifying particulate/organic vapor/acid gas combination cartridge
is recommended in the absence of proper environmental controls or when there is a
potential for dust/vapor inhalation.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid
Form No data
Colour tan
Odour No data
Boiling point/range 176篎 / 80篊@ 760 mmHg
pH No data
Flash Point 23篎 / -5篊 Tag open cup
Evaporation rate 1 Ethyl Ether
Exposure limits 2.0% (V) 12.0% (V)
Vapour pressure 71.0000 mmHg @ 68.00篎 / 20.00篊
Vapour density 2.5
Density 0.8629 g/cm3 @ 77.00篎 / 25.00篊
7.18 lb/gal @ 68.00篎 / 20.00篊
Solubility No data
Partition coeffieient (n- No data
Octanol/water)
Autoignition temperature No data




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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

10. STABILITY AND REACTIVITY


Stability
Stable

Conditions to Avoid
Avoid contact with:

Incompatible Products:
Avoid contact with: strong oxidizing agents

Hazardous Decomposition Products:
May form: carbon dioxide and carbon monoxide, hydrogen cyanide, nitrogen
compounds, phenols, various hydrocarbons

Hazardous Reactions
Product will not undergo hazardous polymerization

Thermal Decomposition
No data

11. TOXICOLOGICAL INFORMATION


Acute Oral Toxicity

METHYL ETHYL KETONE LD50 Mouse: 670 mg/kgLD 50 Rat: 2,300 ?3,500 mg/kg

PHENOL LD 50 Rat: 317 mg/kgLD 50 Mouse: 270
mg/kgLD 50 Rat: 317 mg/kgLD 50 Dog: 500
mg/kgLD 50 Cat: 100 mg/kgLD 50 Rat: 530 mg/kg

ORTHO CRESOL LD 50 Rat: 120 mg/kg

FORMALDEHYDE LD 50 Mouse: 42 mg/kgLD 50 Rat: 100 mg/kg

Acute Inhalation Toxicity

METHYL ETHYL KETONE LC50 Rat: 11,700 mg/l, 4 h




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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

PHENOL LC 50 Rat: 316 mg/m3, 4 h

ORTHO CRESOL LC 50 Mouse: 0.179 mg/l,
LC 50 Rat: 1,220 mg/m3, 2 h

FORMALDEHYDE LC 50 Rat: 203 mg/m3, 2 h

Acute Dermal Toxicity

METHYL ETHYL KETONE LD50 Rabbit: 5 g/kg

PHENOL LD 50 Rabbit: 850 mg/kg
LD 50 Rabbit: 850 mg/kg
LD 50 Rat: 669 mg/kg

ORTHO CRESOL LD 50 Rabbit: 890 mg/kg

FORMALDEHYDE LD 50 Rabbit: 280 mg/kg

12. ECOLOGICAL INFORMATION

Aquatic Toxicity

Acute and Prolonged Toxicity to Fish
No data

Acute Toxicity to Aquatic Invertebrates
No data

Environmental Fate and Pathways
No data

13. DISPOSAL CONSIDERATIONS


Waster Disposal Methods
Destroy by liquid incineration in accordance with applicable regulations. For
assistance with your waste management needs ?including disposal, recycling and waste
stream reduction, contact Ashland Distribution's Environmental Services Group at 1-800-
637-7922.




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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

14. TRANSPORT INFORMATION


IMDG:
UN1133, ADHESIVES 3, 11
IATA_P:
UN1133, ADHESIVES 3, 11
IATA_C:
UN1133, ADHESIVES 3, 11
CFR_ROAD:
UN1133, ADHESIVES 3, 11
CFR_RAIL:
UN1133, ADHESIVES 3, 11
CFR_INWTR:
UN1133, ADHESIVES 3, 11
IMDG_INWTR:
UN1133, ADHESIVES 3, 11
IMDG_ROAD:
UN1133, ADHESIVES 3, 11
IMDG_RAIL:
UN1133, ADHESIVES 3, 11


15. REGULATORY INFORMATION


California Prop. 65
WARNING! This product contains a chemical known in the State of California to cause
cancer.
FORMALDEHYDE

Additional Regulations
US. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures
(21 CFR 1310.12(c))

SARA Hazard Classification Fire Hazard
Acute Health Hazard
Chronic Health Hazard




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Revision Date: 03/26/2007
Print Date: 04/27/2007
PLIOBOND?20 ADHESIVE 571656 MSDS Number: A-1
(Musson PBC20 & PBC220) Version: 1.1

SARA 313 Component(s)
PHENOL 108-95-2 1.088%
FORMALDEHYDE 50-00-0 0.1346%

OSHA Hazards Flammable Liquid
Highly toxic by inhalation
Toxic by ingestion
Toxic by skin absorbtion
Corrosive to skin
Corrosive to eyes
Carcinogen

Health Flammability Reactivity Other
HMIS 1 3 0
NFPA 1 3 0

16. OTHER INFORMATION

The information accumulated herein is believed to be accurate but is not warranted to be
whether originating with the company or not. Recipients are advised to confirm in
advance of need that the information is correct, applicable, and suitable to their
circumstances.

This MSDS has been prepared by Ashland's Environmental Health and Safety
Department




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