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MSDS Material Safety Data Sheet
CAS

76-22-2 108-94-1 95-50-1 8052-41-3

File Name: 76-22-2_108-94-1_95-50-1_8052-41-3.asp

                                   MATERIAL SAFETY DATA SHEET
GARE 73


Page 1 of 4
Revised 7/03/03
0.7726H Replaces 6/25/02
Printed 27/08/03


Section I (General Information)

MANUFACTURER'S NAME:
Johnson Matthey Inc.
Colours and Coatings Division
EMERGENCY TELEPHONE NUMBER:
Regulatory Information: (610) 873-3200 (Weekdays 8:00am-5:00pm EST)
Emergency Telephone: (856) 384-7000 (24 hrs.)
ADDRESS (NUMBER,STREET,CITY,STATE,ZIP):
498 Acorn Lane, Downingtown, PA 19335
CHEMICAL NAME AND SYNONYMS:
Thinners GARE GOLD ESSENCE
TRADE NAME AND SYNONYMS:
O.7726/H
CHEMICAL FAMILY:
Mixed solvents
FORMULA:
Proprietary
DATE OF PREPARATION:
11/17/94
PREPARED BY:
Environmental, Health and Safety Technician
DISCLAIMER:
Employers should use this information only as a supplement to other
information gathered by them, and should make independent judgements of
suitability of this information to ensure proper use and protect the health
and safety of employees. This information is furnished without warranty, and
any use of the product not in conformance with this Material Safety Data
Sheet, or in combination with any other product or process, is the
responsibility of the user.
______________________________________________________________________________
Section II - Hazardous Ingredients

NAME WT% CAS# ACGIH TLV OSHA PEL
Camphor 15-20 76-22-2 2 ppm 2 ppm
Cyclohexanone 20-25 108-94-1 25 ppm 50 ppm
o-Dichlorobenzene 25-30 95-50-1 25 ppm 50 ppm (C)
Stoddard Solvent 20-25 8052-41-3 100 ppm 500 ppm

(C) Ceiling Limit Value
* Withheld as a trade secret.
______________________________________________________________________________
Section III - Physical Data
BOILING POINT(INDICATE IF "F" OR "C"):
Not applicable
VAPOR PRESSURE(mm Hg):
Not applicable
VAPOR DENSITY (AIR = 1):
Heavier than air
SPECIFIC GRAVITY (H2O=1):
Greater than Water




ISO 9002
498 Acorn Lane, Downingtown, PA 19335 * (610) 873-3200 * FAX (610) 873-3255
Cert. No. FM39113
MATERIAL SAFETY DATA SHEET
Page 2 of 4
Revised 7/03/03
0.7726H Replaces 6/25/02
Printed 27/08/03


Section III - Physical Data (Cont.)

PERCENT VOLATILE BY VOLUME (%):
Not less than 75%
EVAPORATION RATE (BuAc = 1):
Slower than Butyl Acetate
SOLUBILITY IN WATER:
Insoluble
APPEARANCE AND ODOR:
Clear Yellow liquid with solvent odor.
______________________________________________________________________________
Section IV - Fire and Explosion Hazard Data

FLASH POINT (METHOD USED):
105 F (Setaflash Closed Cup)
EXTINGUISHING MEDIA:
Carbon Dioxide, Dry Chemical or Chemical Foam. Water may be ineffective, but
may be used to cool exposed containers.
SPECIAL FIRE FIGHTING PROCEDURES:
Fire fighters should wear Self Contained Breathing Apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Toxic fumes of metals and vapors may be evolved in a fire.
______________________________________________________________________________
Section V - Health Hazard Data

PRIMARY ROUTES OF EXPOSURE:
Skin: Yes Eyes: No Inhalation: Yes Ingestion: No
TOXICOLOGICAL INFORMATION:
There is no specific toxicological data available for this preparation. Any
toxicological information is based on individual components that make up this
material.
TARGET ORGAN EFFECTS:
Camphor-Central Nervous System, eye, skin, respiratory system.
Cyclohexanone-Eyes, skin, respiratory system, Central Nervous System.
o-Dichlorobenzene-Respiratory system, GI tract.
Stoddard Solvent-Skin, eyes, respiratory system, Central Nervous System.
CARCINOGENICITY STATUS:
The following chemical(s) are listed as carcinogens by NTP, IARC, OSHA or
all:
Not applicable
EFFECTS OF OVEREXPOSURE:
Eyes: Short term liquid or vapor contact may result in slight eye
irritation. Prolonged and repeated contact may be more irritating.
Skin: Prolonged and repeated liquid contact can cause defatting and drying
of the skin, which may result in skin irritation and dermatitis.
Inhalation: Solvents can act as Central Nervous System depressants,
exhibiting narcotic and anesthetic effects. Overexposure to some of these
components may cause headaches, nausea, vomiting, drowisness, diarrhea, liver
and kidney damage.
EMERGENCY AND FIRST AID PROCEDURES:
Inhalation: Remove from exposure to fresh air. Give artificial respiration
if not breathing. If breathing is difficult, give oxygen. Contact a




ISO 9002
498 Acorn Lane, Downingtown, PA 19335 * (610) 873-3200 * FAX (610) 873-3255
Cert. No. FM39113
MATERIAL SAFETY DATA SHEET
Page 3 of 4
Revised 7/03/03
0.7726H Replaces 6/25/02
Printed 27/08/03


Section V - Health Hazard Data (Cont.)

physician immediately.
Skin: Remove contaminated clothing and wash skin with soap and water.
Wash or clean before reuse.
Eyes: Rinse with clean water or saline solution for at least 15 minutes.
Seek medical advice if irritation persists.
Ingestion: Rinse mouth with water and give water or milk to drink. Do not
induce vomiting. Do not give anything to an unconscious person. Contact a
physician.
______________________________________________________________________________
Section VI - Reactivity Data

STABILITY (choose one): ( )UNSTABLE
(x)STABLE
CONDITIONS TO AVOID:
Avoid heating substance where it may be inhaled, open flames,
oxidizers and sources of ignition. Solvent vapors are heavier than
air and can accumulate, travel to sources of ignition and flash back.
INCOMPATIBILITY (MATERIALS TO AVOID):
Oxidizers such as chlorates, perchlorates, permanganates, and nitrates.
If the preparation comes into contact with ammonia, explosive gold compounds
may be formed. Ammoniacal gold solutions should never be stored.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon dioxide, carbon monoxide, hydrochloric acid, oxides of sulfur and
carbonaceous fumes.
HAZARDOUS POLYMERIZATION (choose one): ( )MAY OCCUR
(x)WILL NOT OCCUR
______________________________________________________________________________
Section VII - Spill or Leak Procedures

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Use appropriate personal protective equipment during clean up operations.
Promptly absorb spill using inert materials such as sand, vermiculite or
sawdust. Remove all sources of ignition and prevent from entry into drains
and waterways. If a Reportable Quantity is exceed for any ingredients,
contact the National Response Center.
WASTE DISPOSAL METHOD:
Follow all Federal, State and Local regulations for removal and disposal.
______________________________________________________________________________
Section VIII - Special Protection Information

RESPIRATORY PROTECTION (SPECIFY TYPE):
A NIOSH/MSHA approved respirator with Organic Vapor cartridge represents the
minimum level of protection. See OSHA 29 CFR 1910.134 for respirator fit,
selection and use.
VENTILATION:

LOCAL EXHAUST: Recommended
MECHANICAL (GENERAL): Acceptable for small quantities

PROTECTIVE GLOVES:




ISO 9002
498 Acorn Lane, Downingtown, PA 19335 * (610) 873-3200 * FAX (610) 873-3255
Cert. No. FM39113
MATERIAL SAFETY DATA SHEET
Page 4 of 4
Revised 7/03/03
0.7726H Replaces 6/25/02
Printed 27/08/03


Section VIII - Special Protection Information (Cont.)

Solvent impermeable gloves
EYE PROTECTION:
Safety glasses or goggles
Eye bath and safety shower
______________________________________________________________________________
Section IX - Special Precautions
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Store in sealed containers in cool, dry place. Keep away from heat and
sources of ignition.
OTHER PRECAUTIONS:
Do not eat, drink or smoke while using this material. Follow good industrial
hygiene practices.
______________________________________________________________________________
Section X - Regulatory Information
REGULATORY INFORMATION:

TSCA Status: All components are on Inventory

SARA Title III Section 313 Reportable Chemicals:
o-Dichlorobenzene
______________________________________________________________________________
Section XI - Right-to-Know Information

RIGHT-TO-KNOW INFORMATION:
Component CAS#
Camphor 76-22-2
Cyclohexanone 108-94-1
o-Dichlorobenzene 95-50-1
Stoddard Solvent 8052-41-3
Terpene Hydrocarbon Mixture ------------
TSRN 80100419-5028p

California Proposition 65:
This material does not contain any ingredients that are known to the
State of California to cause cancer or reproductive toxicity.
______________________________________________________________________________
Section XII - References
REFERENCES:

Barclays California Code of Regulations.
NIOSH Pocket Guide to Chemical Hazards.
The Sigma Aldrich Library of Regulatory and Safety Data.
29 CFR 1910.1000, Z-tables.
ACGIH TLV for Chemical Substances and Physical Agents.




ISO 9002
498 Acorn Lane, Downingtown, PA 19335 * (610) 873-3200 * FAX (610) 873-3255
Cert. No. FM39113

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