Search    ENTER KEYWORD
MSDS Material Safety Data Sheet
CAS

64742-49-0 95-50-1 68476-85-7

File Name: 64742-49-0_95-50-1_68476-85.asp

                         0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 1 of 14



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
0893 051 - WURTH MAINTENANCE SPRAY

STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.

OTHER NAMES



PROPER SHIPPING NAME
AEROSOLS

PRODUCT USE
Lubrication spray.
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing.

SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104



Section 2 - HAZARDS IDENTIFICATION


GHS Classification
Acute Toxicity (Oral) Category 4
Carcinogen Category 2
Chronic Aquatic Hazard Category 2
Eye Irritation Category 2B
Flammable Aerosol Category 1
Reproductive Toxicity Category 2
Respiratory Irritation Category 3
Skin Corrosion/Irritation Category 2

EMERGENCY OVERVIEW

HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
2.1.2A 6.1D 6.3A 6.4A 6.7B 6.8B 9.1B
May cause respiratory irritation
Extremely flammable aerosol
Harmful if swallowed
Causes skin irritation

continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 2 of 14
Section 2 - HAZARDS IDENTIFICATION

Causes eye irritation
Suspected of causing cancer
Suspected of damaging fertility
Toxic to aquatic life with long lasting effects

PRECAUTIONARY STATEMENTS

Prevention
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use personal protective equipment as required.
Wash thoroughly after handling.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flame - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.

Response
IF ON SKIN: Gently wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists, get medical advice/attention.
Wear eye/face protection.
If skin irritation occurs, seek medical advice/attention.
Specific treatment: refer to Label or MSDS.
Leaking gas fire: Do not extinguish, unless leak can be stopped safely
Eliminate all ignition sources if safe to do so.
Wash/Decontaminate removed clothing before reuse.
Remove/Take off immediately all contaminated clothing
If exposed or concerned: Get medical attention advice.

Storage
Protect from sunlight and do not expose to temperatures exceeding 50??C/122??F.
Store locked up.

Disposal
Dispose of contents and container in accordance with relevant legislation.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
naphtha petroleum, light, hydrotreated 64742-49-0. 1-25
1, 2- dichlorobenzene 95-50-1 1-5
hydrocarbon propellant 68476-85-7. 2-80


Section 4 - FIRST AID MEASURES

NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111

SWALLOWED
?If swallowed do NOT induce vomiting.
?If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
?Observe the patient carefully.

continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 3 of 14
Section 4 - FIRST AID MEASURES

?Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
?Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
?Seek medical advice.

EYE
If this product comes in contact with the eyes:
?Immediately hold eyelids apart and flush the eye continuously with running water.
?Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
?Continue flushing until advised to stop by the Poisons Information Centre or a doctor,
or for at least 15 minutes.
?Transport to hospital or doctor without delay.
?Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN
If solids or aerosol mists are deposited upon the skin:
?Flush skin and hair with running water (and soap if available).
?Remove any adhering solids with industrial skin cleansing cream.
?DO NOT use solvents.
?Seek medical attention in the event of irritation.

INHALED
?If fumes or combustion products are inhaled remove from contaminated area.
?Lay patient down. Keep warm and rested.
?Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
?Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
?Transport to hospital, or doctor.

NOTES TO PHYSICIAN
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
?Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
?Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
?Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
?A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
?Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
?Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].




continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 4 of 14


Section 5 - FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA
?Water spray or fog.
?Foam.
?Dry chemical powder.
?BCF (where regulations permit).
?Carbon dioxide.

FIRE FIGHTING
?Alert Fire Brigade and tell them location and nature of hazard.
?May be violently or explosively reactive.
?Wear breathing apparatus plus protective gloves.
?Prevent, by any means available, spillage from entering drains or water course.
?If safe, switch off electrical equipment until vapour fire hazard removed.
?Use water delivered as a fine spray to control fire and cool adjacent area.
?DO NOT approach containers suspected to be hot.
?Cool fire exposed containers with water spray from a protected location.
?If safe to do so, remove containers from path of fire.
?Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.

FIRE/EXPLOSION HAZARD
?Liquid and vapour are highly flammable.
?Severe fire hazard when exposed to heat or flame.
?Vapour forms an explosive mixture with air.
?Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
?Vapour may travel a considerable distance to source of ignition.
?Heating may cause expansion or decomposition with violent container rupture.
?Aerosol cans may explode on exposure to naked flames.
?Rupturing containers may rocket and scatter burning materials.
?Hazards may not be restricted to pressure effects.
?May emit acrid, poisonous or corrosive fumes.
?On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include:.
carbon dioxide (CO2).

FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.

Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.


Section 6 - ACCIDENTAL RELEASE MEASURES


EMERGENCY PROCEDURES

MINOR SPILLS
?Clean up all spills immediately.
?Avoid breathing vapours and contact with skin and eyes.
?Wear protective clothing, impervious gloves and safety glasses.
?Shut off all possible sources of ignition and increase ventilation.
?Wipe up.
continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 5 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES

?If safe, damaged cans should be placed in a container outdoors, away from all ignition
sources, until pressure has dissipated.
?Undamaged cans should be gathered and stowed safely.

MAJOR SPILLS
?Clear area of personnel and move upwind.
?Alert Fire Brigade and tell them location and nature of hazard.
?May be violently or explosively reactive.
?Wear breathing apparatus plus protective gloves.
?Prevent, by any means available, spillage from entering drains or water courses
?No smoking, naked lights or ignition sources.
?Increase ventilation.
?Stop leak if safe to do so.
?Water spray or fog may be used to disperse / absorb vapour.
?Absorb or cover spill with sand, earth, inert materials or vermiculite.
?If safe, damaged cans should be placed in a container outdoors, away from ignition
sources, until pressure has dissipated.
?Undamaged cans should be gathered and stowed safely.
?Collect residues and seal in labelled drums for disposal.

PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE

half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE

From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
IERG Number 49

FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.

continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 6 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES

6 IERG information is derived from CANUTEC - Transport Canada.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing

life-threatening health effects is:
1,2-dichlorobenzene 200 ppm
hydrocarbon propellant 2000 ppm

irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
1,2-dichlorobenzene 50 ppm
hydrocarbon propellant 2000 ppm

other than mild, transient adverse effects without perceiving a clearly defined odour is:
1,2-dichlorobenzene 50 ppm
hydrocarbon propellant 2000 ppm

The threshold concentration below which most people will experience no appreciable risk of health effects:
1,2-dichlorobenzene 25 ppm
hydrocarbon propellant 1000 ppm

American Industrial Hygiene Association (AIHA)

Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture

Personal Protective Equipment advice is contained in Section 8 of the MSDS.


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
?Avoid all personal contact, including inhalation.
?Wear protective clothing when risk of exposure occurs.
?Use in a well-ventilated area.
?Prevent concentration in hollows and sumps.
?DO NOT enter confined spaces until atmosphere has been checked.
?Avoid smoking, naked lights or ignition sources.
?Avoid contact with incompatible materials.
?When handling, DO NOT eat, drink or smoke.
?DO NOT incinerate or puncture aerosol cans.
?DO NOT spray directly on humans, exposed food or food utensils.
?Avoid physical damage to containers.
?Always wash hands with soap and water after handling.
?Work clothes should be laundered separately.
?Use good occupational work practice.
?Observe manufacturer's storing and handling recommendations.
?Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.




continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 7 of 14
Section 7 - HANDLING AND STORAGE

SUITABLE CONTAINER
?Aerosol dispenser.
?Check that containers are clearly labelled.

STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.

STORAGE REQUIREMENTS
?Store in original containers in approved flame-proof area.
?DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
?No smoking, naked lights, heat or ignition sources.
?Keep containers securely sealed. Contents under pressure.
?Store away from incompatible materials.
?Store in a cool, dry, well ventilated area in an upright position.
?Avoid storage at temperatures higher than 40 deg C.
?Protect containers against physical damage and check regularly for leaks.
?Observe manufacturer's storing and handling recommendations.


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m?STEL ppm STEL mg/m砅eak ppm Peak mg/m?TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New 1, 2- 50 301
Zealand dichlorobe
Workplace nzene (o-
Exposure Dichlorobe
Standards nzene)
(WES)
New hydrocarbo 1, 000 1, 800
Zealand n
Workplace propellant
Exposure (LPG
Standards (Liquefied
(WES) petroleum
gas))

The following materials had no OELs on our records
?naphtha petroleum, light, hydrotreated: CAS:64742- 49- 0


EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
1, 2- dichlorobenzene 200
hydrocarbon propellant 2, 000 [LEL]

NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.


ODOUR SAFETY FACTOR (OSF)
OSF=0.16 (hydrocarbon propellant)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 8 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:

Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested

.

MATERIAL DATA
None assigned. Refer to individual constituents.

INGREDIENT DATA
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
?cause inflammation
?cause increased susceptibility to other irritants and infectious agents
?lead to permanent injury or dysfunction
?permit greater absorption of hazardous substances and
?acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA).

1,2-DICHLOROBENZENE:
Odour Threshold Value: 0.699 ppm (detection)
Liver damage occurs in animals exposed to 50 to 800 ppm after a few hours.
continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 9 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

The TLV-C is thought to minimise the potential for such damage and to
minimise eye and nasal irritation.

PERSONAL PROTECTION

EYE
?Safety glasses with side shields; or as required,
?Chemical goggles.
?Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].

HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or as required
: Wear chemical protective gloves, eg. PVC. Wear safety footwear.

OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
?Overalls.
?Skin cleansing cream.
?Eyewash unit.
?Do not spray on hot surfaces.

RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.

Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 AX- AUS -
1000 50 - AX- AUS
5000 50 Airline * -
5000 100 - AX- 2
10000 100 - AX- 3
100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demand.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.

continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 10 of 14


Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE
Light coloured liquid with a characteristic solvent odour; does not mix
with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.

PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.
Floats on water.

Molecular Weight: Not Applicable Boiling Range (?Not Av ailable
C):
Melting Range (?Not Available
C): Specific Gravity (water= 1): 0.69
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Under pressure
Volatile Component (%vol): 60 Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (?- 60
C):
Lower Explosive Limit (%): 1.4 Upper Explosive Limit (%): 32
Autoignition Temp (?Not Available
C): Decomposition Temp ( ?Not Available
C):
State: Liquid Viscosity: Not Available

log Kow (Prager 1995): 3.38
log Kow (Sangster 1997): 3.38


Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
?Elevated temperatures.
?Presence of open flame.
?Product is considered stable.
?Hazardous polymerisation will not occur.


Section 11 - TOXICOLOGICAL INFORMATION


POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Harmful if swallowed. Limited evidence of a carcinogenic effect.
Irritating to skin. Possible risk of impaired fertility.
Can be absorbed through skin.
Vapours may cause dizziness or suffocation.

TOXICITY AND IRRITATION
Not available. Refer to individual constituents.

NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
No significant acute toxicological data identified in literature search.

1,2-DICHLOROBENZENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 500 mg/kg Eye(rabbit):100mg/30s rinse- Mild
continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 11 of 14
Section 11 - TOXICOLOGICAL INFORMATION

Intraperitoneal (rat) LD50: 840 mg/kg
Subcutaneous (rat) LD50: 5000 mg/kg
Inhalation (rat) LDLo: 821 ppm/7 hr
Oral (mouse) LD50: 4386 mg/kg
Intraperitoneal (mouse) LD50: 1228 mg/kg
Oral (rabbit) LD50: 500 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Diffuse and zonal hepatocellular necrosis, lachrymation, general
anaesthesia, paternal effects, specific developmental anormalities
(musculoskeletal sysytem) recorded.

HYDROCARBON PROPELLANT:
Not available. Refer to individual constituents.


Section 12 - ECOLOGICAL INFORMATION

Marine Pollutant:Not Determined
Water hazard class 1 (self assessment): slightly hazardous to water.
Refer to data for ingredients, which follows:

NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.

Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.

Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.

Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.

1,2-DICHLOROBENZENE:
Fish LC50 (96hr.) (mg/l): 9.4- 100
Algae IC50 (72hr.) (mg/l): 53- 100
BCF<100: 36, 128
Water solubility (g/l): 156
log Kow (Prager 1995): 3.38
log Kow (Sangster 1997): 3.38
log Pow (Verschueren 1983): 3.38
Half- life Soil - High (hours): 4320
continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 12 of 14
Section 12 - ECOLOGICAL INFORMATION

Half- life Soil - Low (hours): 672
Half- life Air - High (hours): 1528
Half- life Air - Low (hours): 152.8
Half- life Surface water - High (hours): 4320
Half- life Surface water - Low (hours): 672
Half- life Ground water - High (hours): 8640
Half- life Ground water - Low (hours): 1344
Aqueous biodegradation - Aerobic - High (hours): 4320
Aqueous biodegradation - Aerobic - Low (hours): 672
Aqueous biodegradation - Anaerobic - High (hours): 17280
Aqueous biodegradation - Anaerobic - Low (hours): 2880
Aqueous biodegradation - Removal secondary treatment - High (hours): 76%
Photolysis maximum light absorption - High (nano- m): 269
Photolysis maximum light absorption - Low (nano- m): 219.5
Photooxidation half- life air - High (hours): 1528
Photooxidation half- life air - Low (hours): 152.8
First order hydrolysis half- life (hours): >879 YRS
Base rate constant [MOH)- HR]- 1: <0.9

0etox4# log Kow : 3.38-3.65
log Koc: 2.26-4.5
Koc: 280-320
log Kom: 2.26-2.54
Kom: 162-186
Half-life (hr) air: 152.8-1528
Half-life (hr) H2O surface water: 4.4-4320
Half-life (hr) H2O ground: 1344-8640
Henry's Pa m?/mol: 122-248
Henry's atm m?/mol: 0.0012
BOD 5 if unstated: nil
BCF: 66-560
Log BCF: 1.6-2.75

HYDROCARBON PROPELLANT:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.

Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.

Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.

Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.




continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 13 of 14


Section 13 - DISPOSAL CONSIDERATIONS

?Consult State Land Waste Management Authority for disposal.
?Discharge contents of damaged aerosol cans at an approved site.
?Allow small quantities to evaporate.
?DO NOT incinerate or puncture aerosol cans.
?Bury residues and emptied aerosol cans at an approved site.


Section 14 - TRANSPORTATION INFORMATION




Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y

UNDG:
Dangerous Goods Class: 2.1 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS

Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
ERG Code: 10L
Shipping name:AEROSOLS

Maritime Transport IMDG:
IMDG Class: 2.1 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Marine Pollutant: Not Determined
Shipping name:AEROSOLS



Section 15 - REGULATORY INFORMATION


REGULATIONS
naphtha petroleum, light, hydrotreated (CAS: 64742-49-0) is found on the following
regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Transferred List of Single Component Substances
OECD Representative List of High Production Volume (HPV) Chemicals

1,2-dichlorobenzene (CAS: 95-50-1) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of

continued...
0893 051 - WURTH MAINTENANCE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 7504-43
NA477ECP Version No:3
CD 2007/2 Page 14 of 14
Section 15 - REGULATORY INFORMATION

health significance in drinking-water

hydrocarbon propellant (CAS: 68476-85-7) is found on the following regulatory lists;
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances
(Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
hydrocarbon propellant (CAS: 68476-86-8) is found on the following regulatory lists;
OECD Representative List of High Production Volume (HPV) Chemicals

Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html


Section 16 - OTHER INFORMATION

NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111



INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name CAS
hydrocarbon propellant 68476- 85- 7, 68476- 86 - 8


Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 1-Feb-2005
Print Date: 20-Jul-2007

Search    ENTER KEYWORD
ALL PAGES On Chemical Property IN THIS GROUP
NAMECAS
038-00-6_108-38-3_106-42-3_95-47-6_100-41-4_95-63-6_108-88.asp 038-00-6 108-38-3 106-42-3 95-47-6 100-41-4 95-63-6 108-88-3 103-65-1 110-54-3 98-82-8 71-43-2
108-38-3_106-42-3_100-41-4_95-47-6_108-88-3_71-43-2_1330-20.asp 108-38-3 106-42-3 100-41-4 95-47-6 108-88-3 71-43-2 1330-20-7
67-64-1_75-05-8_107-02-8_107-13-1_107-18-6_107-05-1_919-94.asp 67-64-1 75-05-8 107-02-8 107-13-1 107-18-6 107-05-1 919-94-8 994-05-8 71-43-2 100-44-7 505-60-2 598-31-2 74-97-5 75-27-4 460-00-4 75-25-2 74-83-9 71-36-3 78-93-3 75-65-0 75-15-0 56-23-5 302-17-0 108-90-7 124-48-1 75-00-3 107-07-3 110-75-8 67-66-3 74-87-3 126-99-8 4170-30-3 96-12-8 106-93-4 74-95-3 95-50-1 541-73-1 106-46-7 1476-11-5 110-57-6 75-71-8 75-34-3 107-06-2 75-35-4 156-60-5 78-87-5 96-23-1 10061-01-5 10061-02-6 1464-53-5 60-29-7 108-20-3 540-36-3 123-91-1 106-89-8 64-17-5 141-78-6 100-41-4 75-21-8 97-63-2 462-06-6 637-92-3 87-68-3 67-72-1 591-78-6 74-88-4 78-83-1 98-82-8 109-77-3 126-98-7 67-56-1 75-09-2 80-62-6 108-10-1 1634-04-4 91-20-3 98-95-3 79-46-9 924-16-3 123-63-7 76-01-7 107-87-9 109-06-8 71-23-8 67-63-0 107-19-7 57-57-8 107-12-0 107-10-8 110-86-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 2037-26-5 95-53-4 120-82-1 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 108-05-4 75-01-4 95-47-6 108-38-3 106-42-3
16150606.asp N/A
78-93-3_108-95-2_95-48-7_50-00.asp 78-93-3 108-95-2 95-48-7 50-00-0
50-00-0_95-48.asp 50-00-0 95-48-7
95-48.asp 95-48-7
91-80-2_95-48.asp 91-80-2 95-48-7
95-48.asp 95-48-7
1317-65-3_26761-40-0_1332-58-7_3290-92-4_13463-67-7_95-63.asp 1317-65-3 26761-40-0 1332-58-7 3290-92-4 13463-67-7 95-63-6 14808-60-7 85-68-7 50-00-0 95-48-7
141-78-6_64-17-5_67-64-1_123-86-4_108-39-4_95-48-7_106-44.asp 141-78-6 64-17-5 67-64-1 123-86-4 108-39-4 95-48-7 106-44-5 108-95-2 1300-71-6
26761-40-0_1317-65-3_64742-47-8_1333-86-4_85-68-7_14808-60.asp 26761-40-0 1317-65-3 64742-47-8 1333-86-4 85-68-7 14808-60-7 91-08-7 584-84-9 95-48-7
78-93-3_108-95-2_95-48-7_50-00-0.asp 78-93-3 108-95-2 95-48-7 50-00-0
7647-01-0_67-64-1_50-00-0_67-56-1_95-48-7_94-75-7_72-43-5_78-92.asp 7647-01-0 67-64-1 50-00-0 67-56-1 95-48-7 94-75-7 72-43-5 78-92-2 71-55-6 75-09-2 107-21-1 114-26-1 108-88-3 127-18-4 139-13-9 13463-67-7 7664-38-2 7761-88-8 7664-93-9 7440-66-6 1330-20-7 76-13-1
108-95-2_95-48-7_67-63-0_50-00-0_9039-25-2_78-93-3.asp 108-95-2 95-48-7 67-63-0 50-00-0 9039-25-2 78-93-3
50-00-0_95-48.asp 50-00-0 95-48-7
84989-05-9_64-19-7_85117-49-3_106-44-5_108-39-4_95-48-7_105-67.asp 84989-05-9 64-19-7 85117-49-3 106-44-5 108-39-4 95-48-7 105-67-9 95-87-4 108-95-2
26761-40-0_1317-65-3_64742-95-6_25551-13-7_13463-67-7_85-68.asp 26761-40-0 1317-65-3 64742-95-6 25551-13-7 13463-67-7 85-68-7 14808-60-7 584-84-9 91-08-7 95-48-7
26761-40-0_1317-65-3_64742-95-6_13463-67-7_25551-13-7_85-68.asp 26761-40-0 1317-65-3 64742-95-6 13463-67-7 25551-13-7 85-68-7 14808-60-7 584-84-9 91-08-7 95-48-7
108-95-2_95-57-8_95-48-7_88-75-5_105-67-9_120-83-2_59-50-7_88-06.asp 108-95-2 95-57-8 95-48-7 88-75-5 105-67-9 120-83-2 59-50-7 88-06-2 51-28-5 93951-79-2 534-52-1 87-86-5
75-09-2_1330-20-7_1319-77-3_95-49-8_8002-26-4_1310-58-3_100-41.asp 75-09-2 1330-20-7 1319-77-3 95-49-8 8002-26-4 1310-58-3 100-41-4
111-76-2_25168-05-2_95-49-8_106-43-4_64742-94-5.asp 111-76-2 25168-05-2 95-49-8 106-43-4 64742-94-5
64742-47-8_106-43-4_98-56-6_95-49.asp 64742-47-8 106-43-4 98-56-6 95-49-8
111-76-2_25168-05-2_95-49-8_106-43-4_64742-94-5.asp 111-76-2 25168-05-2 95-49-8 106-43-4 64742-94-5
91-80-2_95-49.asp 91-80-2 95-49-8
95-49-8.asp 95-49-8
08-05-9_106-43-4_95-49-8_29797-40.asp 08-05-9 106-43-4 95-49-8 29797-40-8
68333-29-9_95-49-8_106-43-4_61790-12-3_111-42-2_111-76-2.asp 68333-29-9 95-49-8 106-43-4 61790-12-3 111-42-2 111-76-2
8052-41-3_98-56-6_95-49-8_127-18-4.asp 8052-41-3 98-56-6 95-49-8 127-18-4
95-49-8_108-88-3_8002-05-9.asp 95-49-8 108-88-3 8002-05-9
95-49-8_106-46-7.asp 95-49-8 106-46-7
7664-93-9_64742-47-8_95-49-8.asp 7664-93-9 64742-47-8 95-49-8
7664-93-9_95-49-8_64741-65-7.asp 7664-93-9 95-49-8 64741-65-7
67-64-1_75-05-8_98-86-2_107-02-8_107-13-1_107-05-1_919-94.asp 67-64-1 75-05-8 98-86-2 107-02-8 107-13-1 107-05-1 919-94-8 994-05-8 62-53-3 71-43-2 75-97-5 75-27-4 75-25-2 74-83-9 78-93-3 75-65-0 104-51-8 135-98-8 98-06-6 75-15-0 56-23-5 108-90-7 124-48-1 75-00-3 67-66-3 74-87-3 95-49-8 106-43-4 110-82-7 96-12-8 74-95-3 95-50-1 541-73-1 106-46-7 764-41-0 110-57-6 75-71-8 75-34-3 107-06-2 75-35-4 156-60-5 156-59-2 78-87-5 142-28-9 594-20-7 563-58-6 10061-01-5 10061-02-6 60-29-7 108-20-3 123-91-1 64-17-5 141-78-6 100-41-4 637-92-3 97-63-2 87-68-3 591-78-6 74-88-4 78-83-1 98-82-8 99-87-6 126-98-7 79-20-9 108-87-2 1634-04-4 75-09-2 80-62-6 90-12-0 91-57-6 108-10-1 91-20-3 98-95-3 924-16-3 55-18-5 62-75-9 621-64-7 10595-95-6 76-01-7 109-06-8 107-12-0 103-65-1 110-86-1 100-42-5 79-34-5 127-18-4 109-99-9 108-88-3 95-53-4 87-61-6 120-82-1 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 76-13-1 95-63-6 108-67-8 75-01-4 95-47-6 108-38-3 106-42-3 2679-89-2 666-52-4 1665-00-5 392-56-3 1693-74-9 84508-45-2 363-72-4 1076-43-3 17060-07-0 462-06-6 540-36-3 17647-74-4 2037-26-5 7291-22-7 22581-63-1 3114-55-4 56004-61-6 460-00-4 4165-57-5 2199-69-1 434-90-2 4165-60-0 28077-31-4 1146-65-2 38072-94-5
91-80-2_95-50-1_106-46.asp 91-80-2 95-50-1 106-46-7
64742-95-6_108-93-0_108-10-1_71-36-3_628-63-7_107-98-2_95-50-1.asp 64742-95-6 108-93-0 108-10-1 71-36-3 628-63-7 107-98-2 95-50-1 108-94-1 8052-41-3
64742-49-0_95-50-1_68476-85.asp 64742-49-0 95-50-1 68476-85-7
75-09-2_64742-88-7_127-18-4_95-50-1_1319-77-3_67-56-1.asp 75-09-2 64742-88-7 127-18-4 95-50-1 1319-77-3 67-56-1
95-50.asp 95-50-1
95-50.asp 95-50-1
108-94-1_95-50-1_8002-09-3_71-36-3_1330-20-7_100-41-4.asp 108-94-1 95-50-1 8002-09-3 71-36-3 1330-20-7 100-41-4
75-09-2_95-50-1_1319-77-3_1330-20-7_67-56-1_111-76-2_143-18-0.asp 75-09-2 95-50-1 1319-77-3 1330-20-7 67-56-1 111-76-2 143-18-0 1310-58-3
76-22-2_108-94-1_95-50-1_8052-41-3.asp 76-22-2 108-94-1 95-50-1 8052-41-3
95-50.asp 95-50-1
95-50.asp 95-50-1
1310-58-3_7664-41-7_95-50-1.asp 1310-58-3 7664-41-7 95-50-1
64742-52-5_74-98-6_95-50-1_12001-85-3.asp 64742-52-5 74-98-6 95-50-1 12001-85-3
64742-95-6_95-50-1.asp 64742-95-6 95-50-1
1336-21-6_95-50-1_100-41-4_7553-56-2_8030-30-6_7723-14-0_108-88-3.asp 1336-21-6 95-50-1 100-41-4 7553-56-2 8030-30-6 7723-14-0 108-88-3 1330-20-7 60-29-7 299-42-3 7647-01-0 67-63-0 7439-93-2 67-56-1 78-93-3 1310-73-2 7664-93-9 7664-41-7 67-64-1 64-17-5
75-27-4_75-25-2_74-83-9_56-23-5_108-90-7_75-00-3_110-75-8_67-66.asp 75-27-4 75-25-2 74-83-9 56-23-5 108-90-7 75-00-3 110-75-8 67-66-3 74-87-3 124-48-1 95-50-1 541-73-1 106-46-7 75-34-3 107-06-2 75-35-4 156-60-5 75-43-4 75-09-2 78-87-5 10061-01-5 10061-02-6 79-34-5 127-18-4 71-55-6 79-00-5 79-01-6 75-69-4 75-01-4


HBCChem,Inc

Chemical Information Net chemcas.orgCopyright Reserved

Trading Lead

Leputech HPLC Laboratory