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26761-40-0 1317-65-3 64742-95-6 25551-13-7 13463-67-7 85-68-7 14808-60-7 584-84-9 91-08-7 95-48-7

File Name: 26761-40-0_1317-65-3_64742-95-6_25551-13-7_13463-67-7_85-68.asp

Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007


SECTION 1 - PRODUCT IDENTIFICATION

Trade name : EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Product code : 273C 02

COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585

Product use : Sealant

SECTION 2 - HAZARDS IDENTIFICATION

Emergency Overview
Gray. Non-sag gunnable paste. May cause slight irritation to the respiratory system. May cause nausea,
headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical
attention. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by
trained personnel.

Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system. May cause nausea, headaches, and
:
dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization.
Eyes Direct contact may cause mild irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization resulting in irritation, itching and redness.
:

Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.

Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Prolonged or repeated contact/exposure to aromatic petroleum distillates may cause defatting, drying, and
irritation of the skin, dermatitis, and central nervous system (CNS) effects. Inhalation of crystalline silica (quartz)
can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1).
Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of
the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free
silica. A long-term NTP study showed that oral exposure to toluene diisocyanate (TDI) caused cancer in rats
and mice. A lifetime inhalation study sponsored by the International Isocyanate Institute did not show
carcinogenic activity in rats. May cause allergic skin and respiratory sensitization. Fillers are encapsulated and
not expected to be released from product under normal conditions of use.
Target Organs: Skin, Eye, Ingestion, Lung




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Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007



SECTION 3 - PRODUCT COMPOSITION


Chemical Name CAS-No. Weight %
Aromatic Polyisocyanate Resin NJ TSRN# 51721300-5270P 30.0 - 60.0
Diisodecyl phthalate 26761-40-0 10.0 - 30.0
Calcium Carbonate (Limestone) 1317-65-3 10.0 - 30.0
Tackifier NJ TSRN# 51721300-5272P 5.0 - 10.0
Aromatic petroleum distillates 64742-95-6 5.0 - 10.0
Thickener NJ TSRN# 51721300-5300P 3.0 - 7.0
Trimethyl benzene (mixed isomers) 25551-13-7 3.0 - 7.0
Titanium dioxide 13463-67-7 3.0 - 7.0
Butyl benzyl phthalate 85-68-7 - <1.0
Crystalline Silica (Quartz)/ Silica
14808-60-7 - <1.0
Sand
2,4-Toluene diisocyanate 584-84-9 - <1.0
Toluene-2,6-Diisocyanate 91-08-7 - <0.1
o-Cresol 95-48-7 - <0.1

SECTION 4 - FIRST AID MEASURES

Get immediate medical attention for any significant overexposure.

Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.Move to fresh air. If required, artificial respiration or administration
of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.


SECTION 5 - FIRE FIGHTING MEASURES

Flash point : Not available.
Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and
products nitrogen oxides can form.



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Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007

Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).


SECTION 6 - ACCIDENTAL RELEASE MEASURES

Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate
container for disposal.

SECTION 7 - HANDLING AND STORAGE

Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents
in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change
soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep
container closed when not in use. Since emptied containers retain product residue and vapor, observe
precautions even after container is emptied. Store under dry warehouse conditions away from heat and all
ignition sources.

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely.
Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne
contaminant concentration below the exposure limit listed in the MSDS

Exposure Limits

Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.

Trimethyl benzene (mixed 25551-13-7 ACGIH TWA: 25 ppm
isomers)




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Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007

Chemical Name CAS Number Regulation Limit Form
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.

Crystalline Silica (Quartz)/ 14808-60-7 OSHA TWA: 0.1 mg/m3 Respirable.
Silica Sand OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
ACGIH TWA: 0.025 mg/m3 Respirable fraction.

2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm

Toluene-2,6-Diisocyanate 91-08-7 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm

o-Cresol 95-48-7 ACGIH TWA: 5 ppm
OSHA PEL: 22 mg/m3



SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Form : Non-sag gunnable paste
Color : Gray
Odor : Aromatic Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Insoluble
Specific Gravity : 1.3
% Volatile Weight : 8.7 %


SECTION 10 - REACTIVITY / STABILITY

Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong
acids.Strong bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.



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Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007



SECTION 11 - TOXICOLOGICAL INFORMATION

Trimethyl benzene (mixed isomers), CAS-No.: 25551-13-7
Acute oral toxicity (LD-50 oral) 8,970 mg/kg ( Rat )

Butyl benzyl phthalate, CAS-No.: 85-68-7
Acute oral toxicity (LD-50 oral) 13,500 mg/kg ( Rat )

2,4-Toluene diisocyanate, CAS-No.: 584-84-9
Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 14 mg/l for 4 h ( Rat ) 10 mg/l for 4 h ( Mouse ) 13 mg/l for 4
h ( Guinea pig ) 11 mg/l for 4 h ( Rabbit )

o-Cresol, CAS-No.: 95-48-7
Acute oral toxicity (LD-50 oral) 940 mg/kg ( Rabbit ) 1,800 mg/kg ( Rabbit ) 121 mg/kg (
Rat ) 344 mg/kg ( Mouse ) 1,350 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 0.179 mg/l for 2 h ( Mouse )
Acute dermal toxicity (LD-50 dermal) 620 mg/kg ( Rat ) 890 mg/kg ( Rabbit ) 620 mg/kg ( Mouse )



SECTION 12 - ECOLOGICAL INFORMATION

No Data Available


SECTION 13 - DISPOSAL CONSIDERATIONS

Disposal Method : Waste not regulated under RCRA. Dispose of in compliance with state and local
regulations.


SECTION 14 - TRANSPORTATION / SHIPPING DATA

TDG / DOT Shipping Description:
NOT REGULATED


SECTION 15 - REGULATORY INFORMATION

North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.

U.S. Federal Regulations:
SARA 313 Components : 2,4-Toluene diisocyanate 584-84-9

SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard

OSHA Hazardous Components :


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Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007

Calcium Carbonate (Limestone) 1317-65-3
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
Butyl benzyl phthalate 85-68-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
2,4-Toluene diisocyanate 584-84-9
Toluene-2,6-Diisocyanate 91-08-7
o-Cresol 95-48-7

OSHA Status: Considered : Irritant
hazardous based on the Sensitizer
following criteria: Carcinogen

OSHA Flammability : Not Regulated

Regulatory VOC (less water and : 114 g/l
exempt solvent)
VOC Method 310 : 8%

Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Butyl benzyl phthalate 85-68-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7

U.S. State Regulations:
MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
2,4-Toluene diisocyanate 584-84-9
Toluene-2,6-Diisocyanate 91-08-7
o-Cresol 95-48-7

Penn RTK Components : Aromatic Polyisocyanate Resin NJ TSRN# 51721300-5270P
Diisodecyl phthalate 26761-40-0
Calcium Carbonate (Limestone) 1317-65-3
Tackifier NJ TSRN# 51721300-5272P
Aromatic petroleum distillates 64742-95-6
Thickener NJ TSRN# 51721300-5300P
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
2,4-Toluene diisocyanate 584-84-9

NJ RTK Components : Aromatic Polyisocyanate Resin NJ TSRN# 51721300-5270P
Diisodecyl phthalate 26761-40-0
Calcium Carbonate (Limestone) 1317-65-3
Tackifier NJ TSRN# 51721300-5272P
Aromatic petroleum distillates 64742-95-6
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
Butyl benzyl phthalate 85-68-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7

WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:


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Material Safety Data Sheet




EUCOLASTIC I GUN GRADE GRAY 2 GAL MTO
Version 1.3 Print Date 08/04/2007
REVISION DATE: 08/02/2007

85-68-7 Butyl benzyl phthalate
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
584-84-9 2,4-Toluene diisocyanate
1333-86-4 Carbon Black
91-08-7 Toluene-2,6-Diisocyanate
100-41-4 Ethylbenzene
91-20-3 Naphthalene



SECTION 16 - OTHER INFORMATION

HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe

Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

Prepared by: Rich Mikol

Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration




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