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MSDS  
:
 Tetrabutylammonium dihydrogen trifluoride
CAS  
:
 99337-56-1
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification
MSDS Name: Tetrabutylammonium dihydrogen trifluoride
Catalog Numbers: AC383580000
Synonyms:

Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
99337-56-1 Tetrabutylammonium dihydrogen trifluoride unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Not available.
Target Organs: Respiratory system, gastrointestinal system, eyes, skin.


Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns. Toxic in contact with skin.
Ingestion: Causes gastrointestinal tract burns. Toxic if swallowed.
Inhalation: Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic: Limited evidence of a carcinogenic effect.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use foam, dry chemical, or carbon dioxide.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Do not breathe dust, mist, or vapor. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Tetrabutylammonium dihydrogen trifluoride none listed none listed 2.5 mg/m3 TWA (as dust) (listed under Fluorides).

OSHA Vacated PELs: Tetrabutylammonium dihydrogen trifluoride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: Not available.
Odor: sharp odor - pungent odor - irritating odor
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Reacts.
Specific Gravity/Density:Not available.
Molecular Formula:C16H38F3N
Molecular Weight:301.48

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid: Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information


RTECS#:      
CAS# 99337-56-1 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 99337-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.* No information available.
Hazard Class: 8
UN Number: UN2922
Packing Group: II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 99337-56-1 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 99337-56-1 can be found on the following state right to know lists: California, (listed as Fluorides), Pennsylvania, (listed as Fluorides).

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T C
Risk Phrases:

     R 23/24/25 Toxic by inhalation, in contact with skin and if
     swallowed.
     R 35 Causes severe burns.
     R 40 Limited evidence of a carcinogenic effect.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 7/9 Keep container tightly closed and in a well-ventilated place.

WGK (Water Danger/Protection)

     CAS# 99337-56-1: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 99337-56-1 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/14/2006
Revision #1 Date: 3/26/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
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2-Chloro-N-(4-fluoro-2-methylphenyl)-4-(trifluoromethyl)pyrimidine-5-carboxamide Not available
6-Chloro-N-(4-methoxybenzyl)-4-(trifluoromethyl)nicotinamide Not available
6-Chloro-N-(3,5-dimethoxybenzyl)-4-(trifluoromethyl)nicotinamide Not available
N-[6-Chloro-4-(trifluoromethyl)-2-pyridyl]-N'-(2-methylphenyl)urea Not available
N-[6-Chloro-4-(trifluoromethyl)-2-pyridyl]-N'-(3-methylphenyl)urea Not available
N-[6-Chloro-4-(trifluoromethyl)-2-pyridyl]-N'-(3-methoxyphenyl)urea Not available
(2-Chloropyridin-3-yl){4-[3-(trifluoromethyl)pyridin-2-yl]piperazino}methanone Not available
[4-(7-Chloroquinolin-4-yl)piperazino](phenyl)methanone Not available
6-Iodo-2-methyl-1,3-benzothiazole 68867-20-9
7-Bromo-2,3-dihydrothieno[3,4-b][1,4]dioxine-5-carbonyl chloride 886851-53-2
[5-(Trifluoromethyl)-2-furyl]methylamine 868755-68-4
Benzo[b]furan-3-ylacetaldehyde 352434-24-3
Methylal 109-87-5
1-Methyl-1H-indole-4-sulfonyl chloride 876316-36-8
(1-Methyl-1H-indol-6-yl)methylamine 864264-03-9
2-(Phenoxymethyl)benzaldehyde 168551-49-3
1-(Bromomethyl)-2-(phenoxymethyl)benzene 861319-72-4
2,4-Dichloro-3,5-Dinitrobenzoic Acid, 95% 52729-03-0
(2-Piperidinopyrid-4-yl)methylamine 876316-37-9
1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl]pyrrolidine 884507-39-5
3,5,5-Trimethyl-2-cyclohexen-1-ol, 95% 470-99-5
5-Morpholin-4-ylthiophene-2-carbaldehyde 24372-49-4
2-Oxoindoline-5-sulfonyl chloride 199328-31-9
2-(3-Chlorophenyl)-1,3-thiazole-4-carbaldehyde 859850-99-0
Coumarin 339, Laser Grade, 99+% (UV-Vis) 62669-73-2
N-Methyl-(7-bromo-2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)methylamine 886851-54-3
3-(Chloromethyl)-5-(2-furyl)-1-methyl-1H-pyrazole 876316-48-2
Methylamine Solution 40% 74-89-5Methylamine<-td>
3-Chloro-4,4-dimethylpent-2-enenitrile 216574-58-2
Diethyl 2-[2-(4-pyridyl)ethyl]malonate 92501-98-9
1-Benzyl-3-(tert-butyl)-1H-pyrazole-5-carbohydrazide 263385-00-8
Triethyl 3-acetylpentane-1,3,5-tricarboxylate 72948-75-5
5-Mercapto-4-(2-methylbutyl)-4H-1,2,4-triazol-3-ol 306936-78-7
3-Fluoropyridine-2-carbaldehyde 31224-43-8
Ethyl 7-chloro-3-(isopropylsulfonyl)thieno[3,2-b]pyridine-6-carboxylate Not available
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole-1-carboxylic acid tert-butyl ester 552846-17-0
Ammonium hexafluoroaluminate 7784-19-2
Tetrabutylammonium dihydrogen trifluoride 99337-56-1
Samarium(III) trifluoromethanesulfonate 52093-28-4
6-Methylquinoxaline 6344-72-5
Gadolinium(III) fluoride 13765-26-9
Methylcyclohexane 108-87-2
Chromium(III) trifluoride 7788-97-8
Methyl 3-hydrazino-4-(propylsulfonyl)thiophene-2-carboxylate 175202-01-4
1-[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazine 871125-86-9
3-(Butylamino)propanenitrile 693-51-6
2-(1,4-Thiazinan-4-yl)acetonitrile 53515-34-7
1,4-Dithiane-2-carbonitrile 175136-94-4
5-({2-[(5-Mercapto-1,3,4-thiadiazol-2-yl)thio]ethyl}thio)-1,3,4-thiadiazole-2-thiol 10486-54-1



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