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Section 1 - Chemical Product and Company Identification |
MSDS Name: Titanium reference standard solution
Catalog Numbers:
ST96-100, ST96-500
Synonyms:
None
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7647-01-0 |
Hydrogen chloride |
<5 | 231-595-7 |
| 7722-84-1 |
Hydrogen peroxide |
.1 | 231-765-0 |
| 7440-32-6 |
Titanium |
0.09 | unlisted |
| 7732-18-5 |
Water |
balance | 231-791-2 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: red-orange liquid.
Caution! May cause eye, skin, and respiratory
tract irritation. The toxicological properties of this material have
not been fully investigated.
Target Organs: None.
Potential Health Effects
Eye:
May cause severe eye irritation. May cause irreversible eye
injury.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish
surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Hydrogen chloride
|
2 ppm Ceiling
|
50 ppm IDLH
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5 ppm Ceiling; 7 mg/m3 Ceiling
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| Hydrogen peroxide
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1 ppm TWA
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1 ppm TWA; 1.4 mg/m3 TWA 75 ppm IDLH
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1 ppm TWA; 1.4 mg/m3 TWA
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| Titanium
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none listed
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none listed
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none listed
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| Water
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Hydrogen chloride:
No OSHA Vacated PELs are listed for this chemical.
Hydrogen peroxide:
1 ppm TWA; 1.4 mg/m3 TWA
Titanium:
No OSHA Vacated PELs are listed for this chemical.
Water:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: red-orange
Odor: none reported
pH: Not available.
Vapor Pressure: 14 mm Hg @20 deg C
Vapor Density: Not available.
Evaporation Rate:>1 (ether=1).
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: completely soluble in water.
Specific Gravity/Density:0.7
Molecular Formula:Solution
Molecular Weight:Mixture
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Hydrochloric acid is incompatible with acetate, acetic anhydride,
alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide,
calcium carbide, calcium phosphide, cesium acetylene carbide, cesium
carbide, chlorosulfonic acid, 1,1-difluoroethylene, ethylene diamine,
ethyleneimine, fluorine, lithium silicide, magnesium boride, mercuric
sulfate, oleum, perchloric acid, potassium permanganate,
b-propiolactone, propylene oxide, rubidum acetylene carbide, rubidum
carbide, silver perchlorate + carbon tetrachloride, sodium, sodium
hydroxide, sulfuric acid, uranium phosphide, vinyl acetate.
Substance polymerizes on contact with aldehydes or epoxides.
Titanium is incompatible with bromine trifluoride, carbon dioxide,
cupric oxide, fluorine, lead oxide, nickel and potassium
perchlorate, nitric acid, nitrogen, oxygen, potassium chlorate,
potassium nitrate, potassium permanganate, steam, trichloroethylene,
and trichlorotrifluoroethane.
Hazardous Decomposition Products:
Hydrogen chloride, titanium/titanium oxides, hydrogen gas.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7647-01-0:
MW4025000; MW4031000
CAS# 7722-84-1:
MX0887000; MX0888000; MX0890000; MX0899000; MX0899500;
MX0900000
CAS# 7440-32-6:
XR1700000
CAS# 7732-18-5:
ZC0110000
LD50/LC50:
CAS# 7647-01-0:
Inhalation, mouse:
LC50 = 1108 ppm/1H;
Inhalation,
mouse: LC50 = 20487 mg/m3/5M;
Inhalation, mouse: LC50 = 3940
mg/m3/30M;
Inhalation, mouse: LC50
= 8300 mg/m3/30M;
Inhalation, rat:
LC50 = 3124 ppm/1H;
Inhalation,
rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004
mg/m3/30M;
Inhalation, rat: LC50 =
45000 mg/m3/5M;
Inhalation, rat:
LC50 = 8300 mg/m3/30M;
Oral,
rabbit: LD50 = 900 mg/kg;
.
CAS# 7722-84-1:
Draize test,
rabbit, eye: 1 mg Severe;
Inhalation, rat: LC50 = 2 gm/m3/4H;
Inhalation, rat: LC50 = 2000 mg/m3;
Oral, mouse: LD50 = 2000 mg/kg;
Oral, rabbit: LD50 = 820 mg/kg;
Oral, rat: LD50 = 1518 mg/kg;
Oral, rat: LD50 = 910 mg/kg;
Oral, rat: LD50 = 376 mg/kg;
Oral, rat: LD50 = 4050 mg/kg;
Skin, rat: LD50 = 3 gm/kg;
Skin, rat: LD50 = 4060 mg/kg;
.
CAS# 7440-32-6:
.
CAS# 7732-18-5:
Oral, rat:
LD50 = >90 mL/kg;
.
Carcinogenicity:
CAS# 7647-01-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7722-84-1:
- ACGIH:
A3 - Confirmed animal carcinogen with unknown relevance to humans
- California:
Not listed.
- NTP:
Not listed.
- IARC:
Not listed.
CAS# 7440-32-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No data available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
HYDROCHLORIC ACID |
No information available. |
| Hazard Class: |
8 |
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| UN Number: |
UN1789 |
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| Packing Group: |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7722-84-1 is listed on the TSCA inventory.
CAS# 7440-32-6 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 7647-01-0: 500 lb TPQ (gas only)
CAS# 7722-84-1: 1000 lb TPQ (concentration >52%)
SARA Codes
CAS # 7647-01-0: immediate.
CAS # 7722-84-1: immediate, fire.
CAS # 7440-32-6: fire.
Section 313
This material contains Hydrogen
chloride (CAS# 7647-01-0, <5%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 7647-01-0 is considered highly hazardous by OSHA.
CAS# 7722-84-1 is considered highly hazardous by OSHA.
STATE
CAS# 7647-01-0 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7722-84-1 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7440-32-6 can be found on the
following state right to know lists: California, New Jersey.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7647-01-0: 1
CAS# 7722-84-1: 0
CAS# 7440-32-6: No information available.
CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7722-84-1 is listed on Canada's DSL List.
CAS# 7440-32-6 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7647-01-0 is listed on the Canadian Ingredient Disclosure List.
CAS# 7722-84-1 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 6/08/1998
Revision #5 Date: 11/06/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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