Section 1 - Chemical Product and Company Identification |
MSDS Name: Green Counterstain (PAS, GMS, Retic Kits)
Catalog Numbers:
58014A
Synonyms:
Mixture
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
Not available |
Proprietary Ingredient |
<1.0 | unlisted |
64-19-7 |
Acetic Acid |
<1.0 | 200-580-7 |
7732-18-5 |
Water |
Balance | 231-791-2 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: colorless liquid.
Caution! May cause irritation. This is expected to
be a low hazard for usual industrial handling.
Target Organs: None.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual
industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual
industrial handling.
Chronic:
None
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Rinse area with
large amounts of water for at least 15 minutes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Non-combustible, substance itself does not burn but
may decompose upon heating to produce irritating, corrosive and/or
toxic fumes.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Proprietary Ingredient
|
none listed
|
none listed
|
none listed
|
Acetic Acid
|
10 ppm TWA; 15 ppm STEL
|
10 ppm TWA; 25 mg/m3 TWA 50 ppm IDLH
|
10 ppm TWA; 25 mg/m3 TWA
|
Water
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Proprietary Ingredient:
No OSHA Vacated PELs are listed for this chemical.
Acetic Acid:
10 ppm TWA; 25 mg/m3 TWA
Water:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: colorless
Odor: acetic odor
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: >1.0
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.00
Molecular Formula:Solution
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Acetic acid is incompatible with acetaldehyde, acetic anhydride,
5-azidotetrazole, oxidants, phosphorus trichloride, potassium
tert-butoxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
|
RTECS#:
CAS# 64-19-7:
AF1225000
CAS# 7732-18-5:
ZC0110000
LD50/LC50:
CAS# 64-19-7: Draize test, rabbit,
skin: 50 mg/24H Mild; Inhalation,
mouse: LC50 = 5620 ppm/1H; Oral,
rat: LD50 = 3310 mg/kg; Skin,
rabbit: LD50 = 1060 uL/kg; .
CAS# 7732-18-5: Oral, rat:
LD50 = >90 mL/kg; .
Carcinogenicity:
CAS# 64-19-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
Proprietary Ingredient is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 64-19-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 64-19-7: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 64-19-7: immediate, delayed, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 64-19-7 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 64-19-7 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 64-19-7: 1
CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
CAS# 64-19-7 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 64-19-7 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 8/04/1997 Revision #5 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
Section 1 - Chemical Product and Company Identification |
MSDS Name: Potassium Hydroxide (Silver and Reticulum Kit)
Catalog Numbers:
35029, 58022A
Synonyms:
None.
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
1310-58-3 |
Potassium hydroxide |
10.0 | 215-181-3 |
7732-18-5 |
Water |
Balance | 231-791-2 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: colorless liquid.
Danger! Corrosive. Causes eye and skin burns.
Causes digestive and respiratory tract burns.
Target Organs: None.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Contact may cause ulceration of the conjunctiva and cornea. Eye
damage may be delayed.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
May cause circulatory system failure. May cause perforation of the
digestive tract. Causes severe digestive tract burns with abdominal
pain, vomiting, and possible death.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema. May
cause irritation of the respiratory tract with burning pain in the
nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
or repeated eye contact may cause conjunctivitis.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
Wear appropriate protective clothing to prevent contact with skin
and eyes. Wear a self-contained breathing apparatus (SCBA) to
prevent contact with thermal decomposition products. Use water with
caution and in flooding amounts. Contact with moisture or water may
generate sufficient heat to ignite nearby combustible materials.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Neutralize spill with a weak acid
such as vinegar or acetic acid.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Do not allow water to get into the container
because of violent reaction. Do not get in eyes, on skin, or on
clothing. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from strong acids.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Potassium hydroxide
|
2 mg/m3 Ceiling
|
none listed
|
none listed
|
Water
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Potassium hydroxide:
No OSHA Vacated PELs are listed for this chemical.
Water:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: colorless
Odor: Odorless.
pH: Very alkaline.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Complete in water.
Specific Gravity/Density:1.05 (Water=1)
Molecular Formula:Not applicable.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, acids, metals.
Incompatibilities with Other Materials:
Potassium hydroxide reacts with chlorine dioxide, nitrobenzene,
nitromethane, nitrogen trichloride, peroxidized tetrahydrofuran,
2,4,6-trinitrotoluene, bromoform+ crown ethers, acids alcohols,
sugars, germanium cyclopentadiene, maleic dicarbide. Corrosive to
metals such as aluminum, tin, and zinc to cause formation of
flammable hydrogen gas.
Hazardous Decomposition Products:
Oxides of potassium.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 1310-58-3:
TT2100000
CAS# 7732-18-5:
ZC0110000
LD50/LC50:
CAS# 1310-58-3: Draize test,
rabbit, skin: 50 mg/24H Severe;
Oral, rat: LD50 = 273 mg/kg; .
CAS# 7732-18-5: Oral, rat:
LD50 = >90 mL/kg; .
Carcinogenicity:
CAS# 1310-58-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No information reported.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 1310-58-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1310-58-3: immediate, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-58-3 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 1310-58-3 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28B After contact with skin, wash immediately with plenty of water
and soap.
WGK (Water Danger/Protection)
CAS# 1310-58-3: 1
CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
CAS# 1310-58-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1310-58-3 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/27/1998 Revision #3 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
Section 1 - Chemical Product and Company Identification |
MSDS Name: Thiosulfate (Silver and Reticulum Kit)
Catalog Numbers:
58021A
Synonyms:
Mixture
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7732-18-5 |
Water |
>97 | 231-791-2 |
10102-17-7 |
Sodium thiosulfate |
<3 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: Clear liquid.
Caution! May cause irritation. This is expected to
be a low hazard for usual industrial handling.
Target Organs: None known.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual
industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual
industrial handling.
Chronic:
Not available.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Rinse area with
large amounts of water for at least 15 minutes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Water
|
none listed
|
none listed
|
none listed
|
Sodium thiosulfate
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Sodium thiosulfate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Sodium thiosulfate is incompatible with metal nitrates, and sodium
nitrite.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide, sulfur oxides (SOx), including sulfur
oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 10102-17-7:
WE6660000
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 =
>90 mL/kg; .
CAS# 10102-17-7: .
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 10102-17-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 10102-17-7 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 10102-17-7 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 10102-17-7: 0
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 10102-17-7 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997 Revision #3 Date: 9/09/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
Section 1 - Chemical Product and Company Identification |
MSDS Name: Silver Nitrate (Silver and Reticulum Kit)
Catalog Numbers:
58019, 58019A, 59019
Synonyms:
None
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7732-18-5 |
Water |
90 | 231-791-2 |
7761-88-8 |
Silver nitrate |
10 | 231-853-9 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: Colorless solution.
Danger! Corrosive. Causes eye and skin burns.
Causes respiratory tract irritation. May cause severe digestive
tract irritation with possible burns. May cause methemoglobinemia.
Blue-gray permanent discoloration of the skin, conjunctiva, and
internal organs, known as argyria or argyrosis, results from chronic
exposure to silver or silver salts.
Target Organs: Blood, eyes, skin, mucous
membranes.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury. May
cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. Ingestion of nitrate containing
compounds can lead to methemoglobinemia. Ingestion of soluble silver
salts may cause argyria, characterized by permanent blue-gray
pigmentation of the skin, mucous membranes, and eyes. Ingestion of
silver compounds may cause abdominal pain, rigidity, convulsions and
shock. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Prolonged or repeated inhalation may cause nosebleeds, nasal
congestion, erosion of the teeth, perforation of the nasal septum,
chest pain and bronchitis. Prolonged or repeated eye contact may
cause conjunctivitis. Effects may be delayed. Chronic inhalation or
ingestion of silver salts may cause argyria characterized by a
permanent blue-gray discoloration of the eyes, skin, mucous
membranes, and internal organs. This malady results from the
accumulation of silver in the body.
Section 4 - First Aid Measures
|
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure. SPEEDY ACTION IS CRITICAL! Destroy contaminated
shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with water can cause violent liberation of heat and splattering of
the material.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Use dry chemical to fight fire.
Flash Point: None.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard: OX
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Do
not allow contact with water. Use only in a chemical fume hood.
Discard contaminated shoes.
Storage:
Do not store near combustible materials. Keep container closed when
not in use. Store in a cool, dry, well-ventilated area away from
incompatible substances. Do not store near alkaline substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Water
|
none listed
|
none listed
|
none listed
|
Silver nitrate
|
0.01 mg/m3 TWA (as Ag) (listed under Silver soluble compounds).
|
0.01 mg/m3 TWA (as Ag) (listed under Silver soluble compounds).10 mg/m3 IDLH (as Ag) (listed under Silver soluble compounds).
|
0.01 mg/m3 TWA (listed under Silver soluble compounds).
|
OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Silver nitrate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: Colorless solution
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:1.9
Molecular Formula:Solution
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Acetic acid, allyl chloride, chlorates, chlorine trifluoride,
permanganates, potassium chlorates, cesium acetylene carbide, lithium
silicide, rubidium, chlorosulfonic acid, acetone, bromine
pentafluoride, ethylene glycol, carbides, fulminates, picrates,
mesityl oxide, ethyleneimine, propylene oxide, mixtures of ammonium
hydroxide and silver nitrate, when dried, forms an explosive
compound, acetonitrile, allyl alcohol, cuprous nitride,
epichlorohydrin,, iodine heptafluoride, isoprene, mercuric nitride,
pyridine.
Hazardous Decomposition Products:
Nitrogen oxides, silver fumes.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 7761-88-8:
VW4725000
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 =
>90 mL/kg; .
CAS# 7761-88-8: Draize test,
rabbit, eye: 1 mg Severe; Draize
test, rabbit, eye: 10 mg Moderate;
Oral, mouse: LD50 = 50 mg/kg;
Oral, rat: LD50 = 1173 mg/kg; .
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7761-88-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
Adverse reproductive effects have occurred in experimental
animals.
Mutagenicity:
Mutagenic effects have occurred in humans.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7761-88-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7761-88-8: 1 lb final RQ; 0.454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7761-88-8: immediate, delayed, fire.
Section 313
This material contains Silver
nitrate (listed as Silver compounds), 10%, (CAS# 7761-88-8) which is
subject to the reporting requirements of Section 313 of SARA Title
III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7761-88-8 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 7761-88-8 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7761-88-8 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, (listed as Silver soluble compounds),
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 2 Keep out of reach of children.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 30 Never add water to this product.
S 28A After contact with skin, wash immediately with plenty of water
.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7761-88-8: 3
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7761-88-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E, C.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7761-88-8 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/26/1999 Revision #6 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
Section 1 - Chemical Product and Company Identification |
MSDS Name: Oxidizer
Catalog Numbers:
58066A
Synonyms:
Mixture
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
1333-82-0 |
Chromic Acid |
5.0 | 215-607-8 |
7732-18-5 |
Deionized Water |
Balance | 231-791-2 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: yellow liquid.
Danger! Corrosive. Causes eye and skin burns.
Harmful if swallowed. May cause severe respiratory tract irritation
with possible burns. May cause severe digestive tract irritation
with possible burns.
Target Organs: None known.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns. May cause
severe gastrointestinal tract irritation with nausea, vomiting and
possible burns.
Inhalation:
May cause severe irritation of the upper respiratory tract with
pain, burns, and inflammation. Causes chemical burns to the
respiratory tract.
Chronic:
None
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately. Do
NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation
with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Wash clothing before reuse. Rinse area
with large amounts of water for at least 15 minutes. Destroy
contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Do not ingest or inhale.
Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Chromic Acid
|
0.05 mg/m3 TWA (as Cr) (listed under Chromium (VI) compounds- water soluble).
|
0.001 mg/m3 TWA (as Cr) 15 mg/m3 IDLH (as Cr(VI))
|
none listed
|
Deionized Water
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Chromic Acid:
No OSHA Vacated PELs are listed for this chemical.
Deionized Water:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: yellow
Odor: Not available.
pH: 2.80-3.00
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Explosive reaction with acetaldehyde, acetic acid + heat, acetic
anhydride + heat, benzaldehyde, benzene, benzylthylaniline,
butyraldehyde, 1,3-dimethylhexahydropyrimidone, diethyl ether,
ethylacetate, isopropylacetate, methyl dioxane, pelargonic acid,
pentyl acetate, phosphorus + heat, propionaldehyde, and other
organic materials or solvents. Forms a friction- and heat-sensitive
explosive mixture with potassium hexacyanoferrate. Ignites on
contact with alcohols, acetic anhydride + tetrahydronaphthalene,
acetone, butanol, chromium(II) sulfide, cyclohexanol, dimethyl
formamide, ethanol, ethylene glycol, methanol, 2-propanol, pyridine.
Violent reaction with acetic anhydride + 3-methylphenol (above 75ºC),
acetylene, bromine pentafluoride, glycerol, hexamethylphosphoramide,
peroxyformic acid, selenium, sodium amide. Incandescent reaction
with alkali metals (e.g., sodium, potassium), ammonia, arsenic,
butyric acid (above 100ºC), chlorine trifluoride, hydrogen sulfide +
heat, sodium + heat, and sulfur. Incompatible with
N,N-dimethylformamide
Hazardous Decomposition Products:
Hydrogen iodide, iodide ions (I-).
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 1333-82-0:
GB6650000
CAS# 7732-18-5:
ZC0110000
LD50/LC50:
CAS# 1333-82-0: Oral, mouse: LD50
= 127 mg/kg; Oral, rat: LD50 = 80
mg/kg; .
CAS# 7732-18-5: Oral, rat:
LD50 = >90 mL/kg; .
Carcinogenicity:
CAS# 1333-82-0:
- ACGIH:
A1 - Confirmed Human Carcinogen (listed as 'Chromium (VI) compounds- water soluble').
- California:
carcinogen, initial date 2/27/87 (listed as Chromium (VI) compounds).
- NTP:
Known carcinogen
- IARC:
Group 1 carcinogen (listed as Chromium (VI) compounds).
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
Most soil chromium is in mineral, absorbed, or precipitated form.
Chromium probably occurs as the insoluble Cr(III) oxide Cr2O3.nH2O)
in soil, as the organic matter in soil is expected to reduce any
soluble chromate to insoluble chromic oxide (Cr2O3). Chromium in
soil can be transported to the atmosphere by way of aerosol
formation. Chromium is also transported from soil through runoff and
leaching of water.
Physical:
Chromium(VI) exists in the form of ions (chromate ion, dichromate
ion) in aqueous solutions and will react with oxidizable substances
readily to form Cr(III).
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 1333-82-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 1333-82-0: Section 6 (see 40 CFR 749.68, see also 1333-83-0)
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1333-82-0: immediate, delayed.
Section 313
This material contains Chromic Acid
(listed as Chromium (VI) compounds), 5.0%, (CAS# 1333-82-0) which is
subject to the reporting requirements of Section 313 of SARA Title
III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 1333-82-0 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Minnesota, (listed as Chromium (VI) compounds- water soluble),
Minnesota, (listed as Chromium (VI) compounds), Massachusetts.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Chromic Acid, listed as `Chromium
(VI) compounds', a chemical known to the state of California to cause
cancer.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 1333-82-0: 3
CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
CAS# 1333-82-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1333-82-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 2/25/1999 Revision #4 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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