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Section 1 - Chemical Product and Company Identification |
MSDS Name: Bromine, 1M solution in dichloromethane
Catalog Numbers:
AC389660000, AC389661000, AC389668000
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 75-09-2 |
Methylene chloride |
70-90 | 200-838-9 |
| 7726-95-6 |
Bromine |
10-30 | 231-778-1 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Not available.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic:
Limited evidence of a carcinogenic effect.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
2 - health, 1 - flammability, 0 - instability
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Do not let this chemical
enter the environment.
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Section 7 - Handling and Storage
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Handling:
Do not breathe dust, mist, or vapor. Do not get in eyes, on skin, or
on clothing. Do not ingest or inhale. Use only in a chemical fume
hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Methylene chloride
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50 ppm TWA
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2300 ppm IDLH
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25 ppm TWA; 12.5 ppm Action Level; 25 ppm TWA; 125 ppm STEL (15 min, Cancer, cardiac effects , central nervous system effects, liver effects, and skin and eye irritation - See 29 CFR 1910.1052)
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| Bromine
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0.1 ppm TWA; 0.2 ppm STEL
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0.1 ppm TWA; 0.7 mg/m3 TWA 3 ppm IDLH
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0.1 ppm TWA; 0.7 mg/m3 TWA
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OSHA Vacated PELs:
Methylene chloride:
500 ppm TWA
Bromine:
0.1 ppm TWA; 0.7 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: yellow-brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:Not available.
Molecular Formula:2Br
Molecular Weight:159.81
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Section 10 - Stability and Reactivity
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Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Chlorine, carbon monoxide, carbon dioxide, hydrogen bromide, chloride
fumes, bromine.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 75-09-2:
PA8050000
CAS# 7726-95-6:
EF9100000
LD50/LC50:
CAS# 75-09-2:
Draize test, rabbit,
eye: 162 mg Moderate;
Draize test,
rabbit, eye: 10 mg Mild;
Draize
test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, skin: 810 mg/24H
Severe;
Draize test, rabbit, skin:
100 mg/24H Moderate;
Inhalation,
mouse: LC50 = 14400 ppm/7H;
Inhalation, mouse: LC50 = 49100
mg/m3/6H;
Inhalation, mouse: LC50
= 54000 mg/m3/2H;
Inhalation,
mouse: LC50 = 56220 mg/m3/7H;
Inhalation, rat: LC50 = 52 gm/m3;
Inhalation, rat: LC50 = 76000
mg/m3/4H;
Inhalation, rat: LC50 =
CAS# 7726-95-6:
Inhalation,
mouse: LC50 = 750 ppm/9M;
Inhalation, mouse: LC50 = 2900
mg/m3;
Inhalation, rat: LC50 = 2700
mg/m3;
Inhalation, rat: LC50 = 2700
mg/m3;
Oral, mouse: LD50 = 3100
mg/kg;
Oral, rabbit: LD50 = 2500
mg/kg;
Oral, rat: LD50 = 1700
mg/kg;
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Carcinogenicity:
CAS# 75-09-2:
- ACGIH:
A3 - Confirmed animal carcinogen with unknown relevance to humans
- California:
carcinogen, initial date 4/1/88
- NTP:
Suspect carcinogen
- IARC:
Group 2B carcinogen
CAS# 7726-95-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 75-09-2: waste
number U080.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
CORROSIVE LIQUID, TOXIC, N.O.S.* |
No information available. |
| Hazard Class: |
8 |
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| UN Number: |
UN2922 |
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| Packing Group: |
I |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 75-09-2 is listed on the TSCA inventory.
CAS# 7726-95-6 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 75-09-2: Effective 10/4/82, Sunset 10/4/92
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 75-09-2: Section 4, 0.1 % de minimus concentration
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 75-09-2: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 7726-95-6: 500 lb TPQ
SARA Codes
CAS # 75-09-2: immediate, delayed.
CAS # 7726-95-6: immediate, fire.
Section 313
This material contains Methylene
chloride (CAS# 75-09-2, 70-90%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
This material contains Bromine
(CAS# 7726-95-6, 10-30%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 75-09-2 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
CAS# 75-09-2 is listed as a Priority Pollutant under the Clean Water
Act.
CAS# 75-09-2 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
CAS# 7726-95-6 is considered highly hazardous by OSHA.
STATE
CAS# 75-09-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7726-95-6 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Methylene chloride, a chemical known
to the state of California to cause cancer.
California No Significant Risk Level:
CAS# 75-09-2: 200 鎔/day NSRL (inhalation); 50 鎔/day NSRL
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+ N
Risk Phrases:
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
R 40 Limited evidence of a carcinogenic effect.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 7/9 Keep container tightly closed and in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 75-09-2: 2
CAS# 7726-95-6: 3
Canada - DSL/NDSL
CAS# 75-09-2 is listed on Canada's DSL List.
CAS# 7726-95-6 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 75-09-2 is listed on the Canadian Ingredient Disclosure List.
CAS# 7726-95-6 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 7/13/2006
Revision #1 Date: 3/26/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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