Material Safety Data Sheet
Acid Fast, Fluorescent Permanganate Component
58079 - (KIT)
90193 - (individual)
Section 1 - Chemical Product and Company Identification |
MSDS Name: Acid Fast, Fluorescent Permanganate Component
Catalog Numbers:
2300592, 66823, 66823A, 66823B
Synonyms:
None Known.
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7732-18-5 |
Water |
99.5 | 231-791-2 |
7722-64-7 |
Potassium permanganate |
0.5 | 231-760-3 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: purple liquid.
Caution! May cause eye, skin, and respiratory
tract irritation.
Target Organs: None known.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin discoloration.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual
industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual
industrial handling.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Water
|
none listed
|
none listed
|
none listed
|
Potassium permanganate
|
0.2 mg/m3 TWA (as Mn) (listed under Manganese, inorganic compounds).
|
1 mg/m3 TWA (as Mn) (listed under Manganese compounds, n.o.s.).500 mg/m3 IDLH (as Mn) (listed under Manganese compounds, n.o.s.).
|
5 mg/m3 Ceiling (as Mn) (listed under Manganese compounds, n.o.s.).
|
OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Potassium permanganate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: purple
Odor: Slight phenolic odor.
pH: Not available.
Vapor Pressure: 14 mm Hg
Vapor Density: 0.7
Evaporation Rate:>1 (ether=1)
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point:32 deg F
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:1.0
Molecular Formula:KMnO4
Molecular Weight:158.0339
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong acids, strong bases, water reactive substances (e.g. acetic
anyhdride, alkyl aluminum chloride, calcium carbide, ethyl
dichlorosilane).
Hazardous Decomposition Products:
Oxides of potassium, oxides of manganese.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 7722-64-7:
SD6475000
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 =
>90 mL/kg; .
CAS# 7722-64-7: Oral, mouse:
LD50 = 2157 mg/kg; Oral, mouse:
LD50 = 750 mg/kg; Oral, rat: LD50 =
750 mg/kg; .
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7722-64-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Please contact Fisher Scientific for shipping information |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7722-64-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7722-64-7: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7722-64-7: immediate, delayed, fire.
Section 313
This material contains Potassium
permanganate (listed as Manganese compounds, n.o.s.), 0.5%, (CAS#
7722-64-7) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 7722-64-7 (listed as Manganese compounds, n.o.s.) is listed as a
hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7722-64-7 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7722-64-7 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, (listed as Manganese compounds, n.o.s.),
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7722-64-7: 2
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7722-64-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7722-64-7 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/08/1999 Revision #6 Date: 5/16/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
Section 1 - Chemical Product and Company Identification |
MSDS Name: Acid Fast, Fluorescent Decolorizer Component
Catalog Numbers:
2300591, 66822A, 66822B
Synonyms:
None.
Company Identification:
Fisher Diagnostics
Fisher Scientific Company, LLC
8365 Valley Pike
Middletown, VA 22645-0307
For information, call: 800-524-0294
Emergency Number: 800-524-0294
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
64-17-5 |
Ethyl alcohol |
<67 | 200-578-6 |
7732-18-5 |
Deionized water |
>28.5 | 231-791-2 |
67-56-1 |
Methyl alcohol |
<4 | 200-659-6 |
7647-01-0 |
Hydrochloric acid |
<0.5 | 231-595-7 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: Clear liquid. Flash Point: 16.66 deg C.
Danger! Poison! Causes severe eye
irritation. Flammable liquid and vapor.
Causes respiratory tract irritation. May be fatal or cause blindness
if swallowed. Vapor harmful. This substance has caused adverse
reproductive and fetal effects in humans. May be absorbed through
intact skin. May cause central nervous system depression. May cause
liver, kidney and heart damage. Cannot be made non-poisonous. Causes
moderate skin irritation.
Target Organs: Kidneys, heart, central nervous
system, liver, eyes.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause painful sensitization to
light. May cause blindness. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes moderate skin irritation. May be absorbed through the skin.
May cause cyanosis of the extremities.
Ingestion:
May be fatal or cause blindness if swallowed. May cause
gastrointestinal irritation with nausea, vomiting and diarrhea. May
cause systemic toxicity with acidosis. May cause central nervous
system depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause visual
impairment and possible permanent blindness. May cause narcotic
effects in high concentration. Vapors may cause dizziness or
suffocation.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments
have resulted in mutagenic effects. Animal studies have reported the
development of tumors. Prolonged exposure may cause liver, kidney,
and heart damage.
Cas# 64-17-5:Human systemic effects by ingestion and subcutaneous
routes: sleep disorders, hallucinations, distorted perceptions,
convulsions, motor activity changes, ataxia, coma, antipsychotic,
headache, pulmonary changes, alteration in gastric secretion, nausea
or vomiting, other gastrointestinal changes, menstrual cycle
changes, and body temperature decrease.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively. Persons with skin or eye
disorders or liver, kidney, chronic respiratory diseases, or central
and peripheral nervous sytem diseases may be at increased risk from
exposure to this substance. Ethanol may inhibit methanol metabolism.
Antidote:
Ethanol may inhibit methanol metabolism.
Section 5 - Fire Fighting Measures
|
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire.
Flammable Liquid. Can release vapors that form explosive mixtures at
temperatures above the flashpoint. Use water spray to keep
fire-exposed containers cool. Containers may explode in the heat of
a fire. Can form explosive mixtures at temperatures above the
flashpoint.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
Flash Point: 16.66 deg C ( 61.99 deg F)
Autoignition Temperature: 363 deg C ( 685.40 deg F)
Explosion Limits, Lower:3.3 vol %
Upper: 19 vol %
NFPA Rating:
(estimated) Health: 2; Flammability: 3; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. A vapor suppressing
foam may be used to reduce vapors.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Flammables-area. Do not store
near perchlorates, peroxides, chromic acid or nitric acid.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible
exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Ethyl alcohol
|
1000 ppm TWA
|
1000 ppm TWA; 1900 mg/m3 TWA 3300 ppm IDLH
|
1000 ppm TWA; 1900 mg/m3 TWA
|
Deionized water
|
none listed
|
none listed
|
none listed
|
Methyl alcohol
|
200 ppm TWA; 250 ppm STEL; Skin - potential significant contribution to overall exposure by the cutaneous r oute
|
200 ppm TWA; 260 mg/m3 TWA 6000 ppm IDLH
|
200 ppm TWA; 260 mg/m3 TWA
|
Hydrochloric acid
|
2 ppm Ceiling
|
50 ppm IDLH
|
5 ppm Ceiling; 7 mg/m3 Ceiling
|
OSHA Vacated PELs:
Ethyl alcohol:
1000 ppm TWA; 1900 mg/m3 TWA
Deionized water:
No OSHA Vacated PELs are listed for this chemical.
Methyl alcohol:
200 ppm TWA; 260 mg/m3 TWA
Hydrochloric acid:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acids, bases, active metals,
alkali metals, aluminum, amines, ammonia, copper, copper alloys,
hydrazine, nitric acid, peroxides, steel, isocyanates, alliphatic
amines, sodium, caustics (e.g. ammonia, ammonium hydroxide, calcium
hydroxide, potassium hydroxide, sodium hydroxide), acid anhydrides,
calcium hypochlorite, cyanuric chloride, chromyl chloride, nitrosyl
perchlorate, diethyl zinc, bromine pentafluoride, perchloric acid,
silver nitrate, chromic anhydride, mercuric nitrate, phosphorus
trioxide, potassium-tert-butoxide, magnesium perchlorate, acid
chlorides, platinum, uranium hexafluoride, silver oxide, iodine
heptafluoride, Oxidants (such as barium perchlorate, bromine,
chlorine, hydrogen peroxide, lead perchlorate, perchloric acid,
sodium hypochlorite)., acetyl bromide, alkyl aluminum salts,
beryllium dihydride, carbon tetrachloride + metals, chloroform +
heat, chloroform + sodium hydroxide, Attacks some forms of plastics,
rubbers, and coatin.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, oxides of carbon.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
|
RTECS#:
CAS# 64-17-5:
KQ6300000
CAS# 7732-18-5:
ZC0110000
CAS# 67-56-1:
PC1400000
CAS# 7647-01-0:
MW4025000; MW4031000
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit,
eye: 500 mg Severe; Draize test,
rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, skin: 20 mg/24H
Moderate; Inhalation, mouse: LC50 =
39 gm/m3/4H; Inhalation, rat: LC50
= 20000 ppm/10H; Oral, mouse: LD50
= 3450 mg/kg; Oral, rabbit: LD50 =
6300 mg/kg; Oral, rat: LD50 = 7060
mg/kg; Oral, rat: LD50 = 9000
mg/kg; .
CAS# 7732-18-5: Oral, rat:
LD50 = >90 mL/kg; .
CAS# 67-56-1: Draize test,
rabbit, eye: 40 mg Moderate; Draize
test, rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, skin: 20 mg/24H
Moderate; Inhalation, rabbit: LC50
= 81000 mg/m3/14H; Inhalation, rat:
LC50 = 64000 ppm/4H; Oral, mouse:
LD50 = 7300 mg/kg; Oral, rabbit:
LD50 = 14200 mg/kg; Oral, rat:
LD50 = 5600 mg/kg; Skin, rabbit:
LD50 = 15800 mg/kg; .
CAS# 7647-01-0: Inhalation,
mouse: LC50 = 1108 ppm/1H;
Inhalation, mouse: LC50 = 20487
mg/m3/5M; Inhalation, mouse: LC50 =
3940 mg/m3/30M; Inhalation, mouse:
LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H;
Inhalation, rat: LC50 = 60938
mg/m3/5M; Inhalation, rat: LC50 =
7004 mg/m3/30M; Inhalation, rat:
LC50 = 45000 mg/m3/5M; Inhalation,
rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg; .
Carcinogenicity:
CAS# 64-17-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 67-56-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7647-01-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Ethanol has been shown to produce fetotoxicity in the
embryo or fetus of laboratory animals.Prenatal exposure to
ethanol is associated with a distinct pattern of
congenital malformations that have collectively been termed
the "fetal alcohol syndrome".Methanol and phenol have been
shown to produce fetoxicity in the embryo or fetus in
laboratory animals. Specific developmental abnormalities
for methanol include the musculoskeletal, urogenital. and
cardiovascular systems.
Teratogenicity:
Teratogenic effects have occurred in humans.
Reproductive Effects:
Adverse reproductive effects have occurred in humans.
Mutagenicity:
CAS# 64-17-5: DNA Inhibition: Human, Lymphocyte = 220
mmol/L.; Cytogenetic Analysis: Human, Lymphocyte = 1160
gm/L.; Cytogenetic Analysis: Human, Fibroblast = 12000
ppm.; Cytogenetic Analysis: Human, Leukocyte = 1 pph/72H
(Continuous).; Sister Chromatid Exchange: Human, Lymphocyte
= 500 ppm/72H (Continuous).
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Fish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @
24-24.3°CFish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr;
Fingerling (Unspecified)Bacteria: Phytobacterium phosphoreum:
EC50 = 34900 mg/L; 5-30 min; Microtox test
CAS# 64-17-5: When spilled on land it is apt to volatilize,
biodegrade, and leach into the ground water, but no data on the rates
of these processes could be found. Its fate in ground water is
unknown. When released into water it will volatilize and probably
biodegrade. It would not be expected to adsorb to sediment or
bioconcentrate in fish.
Environmental:
CAS# 64-17-5: When released to the atmosphere it will photodegrade in
hours (polluted urban atmosphere) to an estimated range of 4 to 6
days in less polluted areas. Rainout should be significant.
Physical:
No information available.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: CAS# 67-56-1: waste
number U154 (Ignitable waste).
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
CHEMICAL KITS |
No information available. |
Hazard Class: |
9 |
|
UN Number: |
UN3316 |
|
Packing Group: |
III |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 7647-01-0: 500 lb TPQ (gas only)
SARA Codes
CAS # 64-17-5: immediate, delayed, fire.
CAS # 67-56-1: immediate, fire.
CAS # 7647-01-0: immediate.
Section 313
This material contains Methyl
alcohol (CAS# 67-56-1, <4%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Hydrochloric acid is not at a high
enough concentration to be reportable under Section 313.
Clean Air Act:
CAS# 67-56-1 is listed as a hazardous air pollutant (HAP).
CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 7647-01-0 is considered highly hazardous by OSHA.
STATE
CAS# 64-17-5 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 67-56-1 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7647-01-0 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
WARNING: This product contains Ethyl alcohol, a chemical known to the
state of California to cause developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 33 Take precautionary measures against static discharges.
S 7 Keep container tightly closed.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 7732-18-5: No information available.
CAS# 67-56-1: 1
CAS# 7647-01-0: 1
Canada - DSL/NDSL
CAS# 64-17-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List.
CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List.
CAS# 7647-01-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 7/27/1999 Revision #6 Date: 8/14/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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