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Section 1 - Chemical Product and Company Identification |
MSDS Name: 1,1,2-Trichloro-1,2,2-trifluoroethane
Catalog Numbers:
AC174170000, AC174170010, AC174170025, AC174170200, AC174170250,
AC174175000, AC222100025, AC222100250, AC222105000, AC265520000,
AC265520010, AC265520025, AC265520500, T178-4, T178-4LC, T178-J4, T180-20,
T180-4, T180-J4
Synonyms:
Freon 113; Fluorocarbon 113; 1,1,2-Trichlorotrifluoroethane; CFC-113;
Chlorofluorocarbon 113.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 76-13-1 |
1,1,2-Trichlorotrifluoroethane |
99 | 200-936-1 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid.
Caution! Vapor reduces oxygen available for
breathing. May cause eye irritation. May cause central nervous
system effects. May cause cardiac disturbances. This is a CFC
substance which destroys ozone in the upper atmosphere. Destruction
of the ozone layer can lead to increased ultraviolet radiation which,
with excess exposure to sunlight, can lead to an increase in skin
cancer and eye cataracts.
Target Organs: Heart, central nervous system.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Instillation of undiluted CFC-113 produced no significant irritation
in the rabbit eye.
Skin:
May cause mild skin irritation. Prolonged or repeated contact may
dry/defat the skin and cause irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Expected to be a low ingestion hazard.
Discomfort due to volatility would be expected.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Vapor reduces oxygen available for breathing. May cause
heart disturbances, possibly leading to cardiac arrest and death. May
cause narcotic effects in high concentration.
Overexposure may cause dizziness and loss of concentration.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Causes cardiac sensitization to endogenous catelcholamines which may
lead to cardiac arrhythmias. Do NOT use adrenergic agents such as
epinephrine or pseudoepinephrine.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Flash Point: None.
Autoignition Temperature: 770 deg C ( 1,418.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. U.S. regulations require reporting spills and releases
to soil, water and air in excess of reportable quantities.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation. Do not
vent to the atmosphere. To comply with provisions of the U.S. Clean
Air Act, any residual must be recovered.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 1,1,2-Trichlorotrifluoroethane
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1000 ppm TWA; 1250 ppm STEL
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1000 ppm TWA; 7600 mg/m3 TWA 2000 ppm IDLH
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1000 ppm TWA; 7600 mg/m3 TWA
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OSHA Vacated PELs:
1,1,2-Trichlorotrifluoroethane:
1000 ppm TWA; 7600 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless
Odor: ethereal odor - weak odor - sweetish odor
pH: Not available.
Vapor Pressure: 273 mm Hg @ 20 deg C
Vapor Density: 6.5 (air=1)
Evaporation Rate:>1 (ether = 1)
Viscosity: Not available.
Boiling Point: 47 - 48 deg C
Freezing/Melting Point:-36 deg C
Decomposition Temperature:> 250 deg C
Solubility: Insoluble.
Specific Gravity/Density:1.47 @ 21癈
Molecular Formula:C2Cl3F3
Molecular Weight:187.38
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, powdered
aluminum.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, hydrogen fluoride gas, carbonyl
fluoride.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 76-13-1:
KJ4000000
LD50/LC50:
CAS# 76-13-1:
Draize test, rabbit,
skin: 500 mg/24H Mild;
Inhalation,
mouse: LC50 = 260 gm/m3/2H;
Inhalation, mouse: LC50 = 467000
mg/m3/2H;
Inhalation, rabbit: LC50
= 59500 ppm/2H;
Inhalation,
rabbit: LC50 = 59.5 ppm/2H;
Inhalation, rat: LC50 = 38500
ppm/4H;
Inhalation, rat: LC50 =
53.3 ppm/4H;
Inhalation, rat: LC50
= 38.5 ppm/4H;
Inhalation, rat:
LC50 = 52.5 ppm/4H;
Oral, rat: LD50
= 43 gm/kg;
Oral, rat: LD50 = 43
gm/kg;
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Carcinogenicity:
CAS# 76-13-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Data from the exposure of human volunteers to CFC-113
indicate that the threshold concentration for impairment of
human psychomotor performance, described as loss of ability
to concentrate and mild lethargy, is about 2500 ppm.After
review of fatality reports, NIOSH concluded that working
with high concentrations of CFC-113 or other
chlorofluorocarbons in confined spaces has the potential to
cause death by cardiac arrhythmia, asphyxiation, or both.
Teratogenicity:
No information available.
Reproductive Effects:
See actual entry in RTECS for complete information.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
Has very limited solubility in water and is highly volatile. Expected
to be eventually conveyed to the atmosphere. Has some potential to
perturb stratospheric ozone.
Physical:
No information available.
Other:
No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
Not Regulated |
Not Regulated |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 76-13-1 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 76-13-1: Effective 4/13/89, Sunset 12/19/95
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 76-13-1: immediate, delayed.
Section 313
This material contains
1,1,2-Trichlorotrifluoroethane (CAS# 76-13-1, 99%),which is subject
to the reporting requirements of Section 313 of SARA Title III and
Clean Air Act:
This material does not contain any hazardous air pollutants.
CAS# 76-13-1 is listed as a Class 1 ozone depletor with an 0.8 ODP
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 76-13-1 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
N
Risk Phrases:
R 59 Dangerous for the ozone layer.
Safety Phrases:
S 59 Refer to manufacturer/supplier for information on recovery/recy
cling.
WGK (Water Danger/Protection)
CAS# 76-13-1: 2
Canada - DSL/NDSL
CAS# 76-13-1 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 76-13-1 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 12/12/1997
Revision #10 Date: 2/15/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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