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MSDS  
:
 Tetramethylammonium chloride, 98+%
CAS  
:
 75-57-0
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Tetramethylammonium chloride, 98+%
Catalog Numbers: AC138330000, AC138330050, AC138331000, AC138332500, AC138335000, O4640-500
Synonyms:
N,N,N-Trimethylmethanaminium chloride.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
75-57-0 Tetramethylammonium chloride >98 200-880-8

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white crystalline powder.
Warning! Causes eye, skin, and respiratory tract irritation. Harmful if swallowed or absorbed through the skin. Hygroscopic (absorbs moisture from the air).
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. Harmful if absorbed through the skin.
Ingestion: Harmful if swallowed.
Inhalation: Causes respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use water spray, dry chemical, or carbon dioxide.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Tetramethylammonium chloride none listed none listed none listed

OSHA Vacated PELs: Tetramethylammonium chloride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Crystalline powder
Appearance: white
Odor: characteristic odor
pH: 6-8 (100g/l water)
Vapor Pressure: Negligible.
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:300 deg C
Decomposition Temperature:> 300 deg C
Solubility: Soluble.
Specific Gravity/Density:1.17
Molecular Formula:C4H12ClN
Molecular Weight:109.60

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Dust generation, moisture.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases.
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 75-57-0: BS7700000
LD50/LC50:
CAS# 75-57-0:
     Oral, rat: LD50 = 50 mg/kg;
.
Dermal, rat: LD50 = 537 mg/kg (Merck); Oral, mouse: LDLo = 125 mg/kg.; Subcutaneous, mouse: LD50 = 40 mg/kg.; Subcutaneous, rabbit: LDLo = 6 mg/kg.
Carcinogenicity:
CAS# 75-57-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1 6.1
UN Number: UN2811 UN2811
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 75-57-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 75-57-0: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 75-57-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T
Risk Phrases:

     R 21 Harmful in contact with skin.
     R 25 Toxic if swallowed.
     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 75-57-0: 2
Canada - DSL/NDSL
     CAS# 75-57-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 6/08/1998
Revision #6 Date: 1/12/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
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tert-Amyl alcohol 75-85-4
Tetrabutylammonium Hydroxide Solution (0.4M to 1M) 2052-49-5
Alpha-Bromo-P-Tolunitrile, 98% 17201-43-3
3-Hydroxybenzaldehyde 100-83-4
Diethoxymethane, 99% (GC) 462-95-3
Tris(4-methoxyphenyl)phosphine 855-38-9
Papain, Proteolytic Activity 46000-50000 nfu/mg 9001-73-4
Ellagic Acid Dihydrate, 97% 476-66-4
L(+)-Potassium hydrogen tartrate, 99% 868-14-4
Ethyl orange sodium salt, 92% 62758-12-7
Tetrachloroethylene 127-18-4Tetrachloroethylene<-td>
l-Serine methyl ester hydrochloride, 98% 5680-80-8
Tetradecane 629-59-4Tetradecane<-td>
1,2,4,5-Tetrakis(Bromomethyl)Benzene 98% 15442-91-8
Tetraethylammonium Bromide 71-91-0
Suberic Acid Monomethyl Ester, 97% 3946-32-5
5,8-Dihydro-1-naphthol, 85%, remainder 5,6,7,8-tetrahydronaphthol 27673-48-9
4,5,8-Trimethylpsoralen 3902-71-4
Methyl 2-Trifluoromethylbenzoylacetate Not available
D(-)-Arginine 157-06-2
Pentafluorobenzenesulfonyl chloride, 99% 832-53-1
Benzo-15-crown-5, 99% 14098-44-3
Tetrahydrofuran (inhibited) 128-37-0
Tetrahydrofuran, 99.5+%, for spectroscopy. 109-99-9
3,5-Dichloropyridine, 98% 2457-47-8
3-Hydroxy-2-quinoxalinecarboxylic acid 1204-75-7
(-)-Chloromethyl menthyl ether, 95% (GC), 97+% e.e. 96662-07-6
Tetrahydroxyquinone 319-89-1
Ethyl L-Lactate (Pract), 90% (GC) 7732-18-5
1,2,3,4-Tetrahydronaphthalene 119-64-21,2,3,4-Tetrahydronaphthalene<-td>
Methyl sulfide, 99+% 75-18-3
Tetramethylammonium chloride, 98+% 75-57-0
2-Thiophene acetyl chloride, 99% 39098-97-0
Tetramethylammonium Hydroxide Pentahydrate 10424-65-4Methanaminium, n,n,n-trimethyl-, hydroxide, pentahydrate<-td>
Tetramethylammonium hydroxide solutions 75-59-2Tetramethylammonium hydroxide<-td>
Silver perchlorate hydrate 14242-05-8
Triphenyl phosphate, 99+% 115-86-6Triphenyl phosphate<-td>
4-Aminophthalonitrile 56765-79-8
Nickel phthalocyanine, 95% (Titr.) 14055-02-8
Methyl p-toluate 99-75-2
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Tetrapropylammonium hydroxide, 10-25% in water 4499-86-9
Potassium phosphate tribasic re 22763-04-8Potassium phosphate tribasic re<-td>
2,4-Dibromoaniline, 98% 615-57-6



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