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Section 1 - Chemical Product and Company Identification |
MSDS Name: Borane-tert-butylamine complex
Catalog Numbers:
AC177300000, AC177300250, AC177301000, AC189220000, AC189220250, AC189221000
AC189221000
Synonyms:
tert-Butylamineborane; Boron, trihydro(2-methyl-2-propanamine)-,
(T-4)-; t-Butylamine, cmpd. with borane (1:1);
(tert-Butylamine)trihydroboron.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7337-45-3 |
Borane-tert-butylamine complex |
95 | 230-851-5 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white solid.
Danger! May be fatal if swallowed. Flammable
solid. Causes eye, skin, and respiratory tract irritation. Harmful if
absorbed through skin or if inhaled. May cause central nervous system
effects. Heat sensitive.
Target Organs: Central nervous system.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract. May cause central nervous system effects.
Inhalation:
Inhalation of dust may cause respiratory tract irritation.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Flammable solid. Reaction with acid evolves highly flammable
hydrogen gas.
Extinguishing Media:
For small fires, use dry chemical, soda ash, lime or sand. For large
fires, use dry sand, dry chemical, soda ash or lime or withdraw from
area and let fire burn.
Flash Point: Not applicable.
Autoignition Temperature: 177 deg C ( 350.60 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 1; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Use only
non-sparking tools and equipment.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Contents may develop
pressure upon prolonged storage. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not ingest or inhale. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store under an inert atmosphere.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Ventilation fans and other electrical service must be non-sparking
and have an explosion-proof design.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Borane-tert-butylamine complex
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Borane-tert-butylamine complex:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:96 deg C
Decomposition Temperature:71 deg C
Solubility: 2.7 g/100ml (20癈)
Specific Gravity/Density:Not available.
Molecular Formula:C4H14BN
Molecular Weight:86.97
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable. However, may decompose if heated. May react with oxygen in
the air.
Conditions to Avoid:
Contact with water, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron,
borane, hydrogen gas.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7337-45-3:
EO3900000
LD50/LC50:
CAS# 7337-45-3:
Dermal, guinea
pig: LD50 = >1 gm/kg;
Oral, mouse:
LD50 = 25 mg/kg;
Oral, rat: LD50 =
96 mg/kg;
Skin, rabbit: LD50 = 820
mg/kg;
.
Oral, rat: LD50 = 25 mg/kg (Eastman Kodak).
Carcinogenicity:
CAS# 7337-45-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
FLAMMABLE SOLIDS, TOXIC, ORGANIC, N.O.S. |
Flammable Solid, Toxic, Organic, N.O.S. (BORANE-TERT-BUTYLAMINE) |
| Hazard Class: |
4.1 |
4.1 |
| UN Number: |
UN2926 |
UN2926 |
| Packing Group: |
II |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7337-45-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7337-45-3 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T F
Risk Phrases:
R 11 Highly flammable.
R 20/21 Harmful by inhalation and in contact with skin.
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 15 Keep away from heat.
S 16 Keep away from sources of ignition - No smoking.
S 33 Take precautionary measures against static discharges.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 7337-45-3: No information available.
Canada - DSL/NDSL
CAS# 7337-45-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B4, D1A, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 6/11/1998
Revision #5 Date: 1/16/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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