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Catalog Numbers: 23-005-84, 23-005-85, 2300585B, 281407B, 66766 Synonyms: Mixture Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: Dark, reddish-brown.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Get medical aid if irritation develops or persists. Wash clothing before reuse. Flush skin with plenty of soap and water. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Notes to Physician: Treat symptomatically and supportively.
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Flash Point: Not available. Autoignition Temperature: Not available. Explosion Limits, Lower:N/A Upper: N/A NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Exposure Limits
OSHA Vacated PELs: Poviodine-Iodine: No OSHA Vacated PELs are listed for this chemical. Potassium iodide: No OSHA Vacated PELs are listed for this chemical. DI Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: Liquid Appearance: Dark, reddish-brown Odor: Iodine pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Solubility: Soluble in water. Specific Gravity/Density:~1 Molecular Formula:Not available. Molecular Weight:Not available.
Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat. Incompatibilities with Other Materials: Incompatable with potassium iodide include: salts of alkaloids, chloral hydrate, calomel(mercurous chloride) potassium chlorate, metallic salts, tartaric and other acids, bromine trifluoride, and fluorine perchlorate, oxidizing agents. Incompatibilities with PVP include oxidizing agents. Hazardous Decomposition Products: Irritating and toxic fumes and gases, oxides of potassium, iodine. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 25655-41-8: TR1579600 CAS# 7681-11-0: TT2975000 CAS# 7732-18-5: ZC0110000 LD50/LC50: CAS# 25655-41-8: Draize test, rabbit, skin: 500 mg Mild; Oral, mouse: LD50 = 8100 mg/kg; Oral, rat: LD50 = >8 gm/kg; . CAS# 7681-11-0: . CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . Carcinogenicity: CAS# 25655-41-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7681-11-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information available. Teratogenicity: Iodine salts can produce deformity, illness, and death of a fetus. PVP(iodine complex) has been shown to present a possible risk of harm to the unborn child. Reproductive Effects: PVP(iodine complex) has been shown to produce reproductive effects when there is overexposure. Mutagenicity: No information available. Neurotoxicity: No information available. Other Studies:
Ecotoxicity: No data available. No information available. Environmental: No information found. Physical: No information found. Other: No information available.
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.
US FEDERAL TSCA CAS# 25655-41-8 is listed on the TSCA inventory. CAS# 7681-11-0 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs None of the chemicals in this material have an RQ. SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 7681-11-0: immediate, delayed. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 25655-41-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7681-11-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 25655-41-8: 2 CAS# 7681-11-0: 1 CAS# 7732-18-5: No information available. Canada - DSL/NDSL CAS# 25655-41-8 is listed on Canada's DSL List. CAS# 7681-11-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. Canada - WHMIS WHMIS: Not available. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 7681-11-0 is listed on the Canadian Ingredient Disclosure List.
MSDS Creation Date: 4/16/1999 Revision #4 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Catalog Numbers: 23255963, 23270183, 23281407D, 23291476, 66762, 66762S, 66770B, 66780B, 66782 Synonyms: Mixture Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: red liquid. Flash Point: 82 deg F.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Get medical aid. Rinse area with large amounts of water for at least 15 minutes. Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively.
General Information: Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution. Flammable liquid and vapor. Extinguishing Media: Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. Flash Point: 82e deg F ( 27.78 deg C) Autoignition Temperature: Not available. Explosion Limits, Lower:3.3 Upper: 19 NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 0
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Provide ventilation.
Handling: Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits
OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Ethyl alcohol: 1000 ppm TWA; 1900 mg/m3 TWA Methyl alcohol: 200 ppm TWA; 260 mg/m3 TWA Safranin: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: Liquid Appearance: red Odor: pungent odor pH: Not available. Vapor Pressure: 40 mm Hg @19 deg C Vapor Density: 1.59 (air=1) Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 95 deg C Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Solubility: Soluble. Specific Gravity/Density:1 Molecular Formula:Not available. Molecular Weight:Not available.
Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Ignition sources, excess heat. Incompatibilities with Other Materials: Ethanol is incompatible with acetic anhydride, acetyl bromide, ammonia + silver nitrate, disulfuric acid + nitric acid, dichloromethane + sulfuric acid, disulfuryl difluoride, magnesium perchlorate, nitric acid + silver, oxidants, phosphorus (III) oxide, platinum, potassium, potassium tert-butoxide, silver nitrate, silver oxide, sodium and tetrachlorosilane. Methanol is incompatible with acetyl bromide, alkylaluminum solutions, beryllium hydride, carbon tetrachloride + metals, chloroform + sodium, chloroform + sodium hydroxide, cyanuric chloride, dichloromethane, diethylzinc, metals, oxidants, phosphorus (III) oxide, and potassium tert-butoxide. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of nitrogen, carbon dioxide, formaldehyde. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 7732-18-5: ZC0110000 CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 477-73-6: SG1623000 LD50/LC50: CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg; . CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg; . CAS# 477-73-6: . Carcinogenicity: CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 64-17-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 67-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 477-73-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: This product contains methanol and ethanol which have been shown to produce fetoxicity in the embryo or fetus. Specific abnormalities for methanol include the cardiovascular, musculoskeletal and urogenital systems. Teratogenicity: No information found Reproductive Effects: Methanol has been shown to produce reproductive effects in laboratory animals. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have been collectively termed the "fetal alcohol syndrome". Among the characteristics of this syndrome are intrauterine and postnatal growth deficiency, a distinctive pattern of physical malformation, and behavioral/cognitive impairment such as fine motor dysfunction and mental retardation. Not all affected children have all of the features of the syndrome. Mutagenicity: Methanol has been shown to produce DNA damage in laboratory animals. Neurotoxicity: No information found Other Studies:
No information available.
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: CAS# 67-56-1: waste number U154 (Ignitable waste).
US FEDERAL TSCA CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 64-17-5 is listed on the TSCA inventory. CAS# 67-56-1 is listed on the TSCA inventory. CAS# 477-73-6 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 64-17-5: immediate, delayed, fire. CAS # 67-56-1: immediate, fire. CAS # 477-73-6: immediate, reactive. Section 313 Methyl alcohol is not at a high enough concentration to be reportable under Section 313. No chemicals are reportable under Section 313. Clean Air Act: CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 64-17-5 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 477-73-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 WARNING: This product contains Ethyl alcohol, a chemical known to the state of California to cause developmental reproductive toxicity. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 7732-18-5: No information available. CAS# 64-17-5: 0 CAS# 67-56-1: 1 CAS# 477-73-6: No information available. Canada - DSL/NDSL CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 64-17-5 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 477-73-6 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of B2. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List. CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List.
MSDS Creation Date: 4/16/1999 Revision #9 Date: 7/23/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Catalog Numbers: 66760B Synonyms: Mixture Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: red liquid. Flash Point: 82 deg F.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Get medical aid. Rinse area with large amounts of water for at least 15 minutes. Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively.
General Information: Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid. Containers may explode when heated. Extinguishing Media: Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. Flash Point: 82e deg F ( 27.78 deg C) Autoignition Temperature: Not available. Explosion Limits, Lower:3.3 Upper: 19 NFPA Rating: (estimated) Health: 1; Flammability: 2; Instability: 0
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up, then place into a suitable container for disposal. Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation.
Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits
OSHA Vacated PELs: Deionized Water: No OSHA Vacated PELs are listed for this chemical. Ethyl Alcohol: 1000 ppm TWA; 1900 mg/m3 TWA Methyl Alcohol: 200 ppm TWA; 260 mg/m3 TWA Safranin: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: Liquid Appearance: red Odor: pungent odor pH: Not available. Vapor Pressure: 40 mm Hg @19C Vapor Density: 1.59 Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 95 deg C Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Solubility: Soluble in water. Specific Gravity/Density:1 Molecular Formula:Not available. Molecular Weight:Not available.
Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, excess heat. Incompatibilities with Other Materials: Ethanol is incompatible with acetic anhydride, acetyl bromide, ammonia + silver nitrate, disulfuric acid + nitric acid, dichloromethane + sulfuric acid, disulfuryl difluoride, magnesium perchlorate, nitric acid + silver, oxidants, phosphorus (III) oxide, platinum, potassium, potassium tert-butoxide, silver nitrate, silver oxide, sodium and tetrachlorosilane. Methanol is incompatible with acetyl bromide, alkylaluminum solutions, beryllium hydride, carbon tetrachloride + metals, chloroform + sodium, chloroform + sodium hydroxide, cyanuric chloride, dichloromethane, diethylzinc, metals, oxidants, phosphorus (III) oxide, and potassium tert-butoxide. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of nitrogen, carbon dioxide, formaldehyde. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 7732-18-5: ZC0110000 CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 477-73-6: SG1623000 LD50/LC50: CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg; . CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg; . CAS# 477-73-6: . Carcinogenicity: CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 64-17-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 67-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 477-73-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: This product contains methanol and ethanol which have been shown to produce fetoxicity in the embryo or fetus. Specific abnormalities for methanol include the cardiovascular, musculoskeletal and urogenital systems. Teratogenicity: No data available. Reproductive Effects: Methanol has been shown to produce reproductive effects in laboratory animals. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have been collectively termed the "fetal alcohol syndrome". Among the characteristics of this syndrome are intrauterine and postnatal growth deficiency, a distinctive pattern of physical malformation, and behavioral/cognitive impairment such as fine motor dysfunction and mental retardation. Not all affected children have all of the features of the syndrome. Mutagenicity: Methanol has been shown to produce DNA damage in laboratory animals. Neurotoxicity: No data available. Other Studies:
No information available.
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: CAS# 67-56-1: waste number U154 (Ignitable waste).
US FEDERAL TSCA CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 64-17-5 is listed on the TSCA inventory. CAS# 67-56-1 is listed on the TSCA inventory. CAS# 477-73-6 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 64-17-5: immediate, delayed, fire. CAS # 67-56-1: immediate, fire. CAS # 477-73-6: immediate, reactive. Section 313 Methyl Alcohol is not at a high enough concentration to be reportable under Section 313. No chemicals are reportable under Section 313. Clean Air Act: CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 64-17-5 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 477-73-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 WARNING: This product contains Ethyl Alcohol, a chemical known to the state of California to cause developmental reproductive toxicity. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 7732-18-5: No information available. CAS# 64-17-5: 0 CAS# 67-56-1: 1 CAS# 477-73-6: No information available. Canada - DSL/NDSL CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 64-17-5 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 477-73-6 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of B3, D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List. CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List.
MSDS Creation Date: 8/04/1998 Revision #7 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Catalog Numbers: Synonyms: Mixture. Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: clear, colorless liquid. Flash Point: 32 deg F.
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively.
General Information: Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May be ignited by heat, sparks, and flame. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. Flash Point: 32e deg F ( 0.00 deg C) Autoignition Temperature: Not applicable. Explosion Limits, Lower:2.2 vol % Upper: 13.0 vol % NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 0
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Wear appropriate protective clothing to minimize contact with skin. Remove all sources of ignition. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces. Clean up residual material by washing area with a 2-5% solution of soda ash.
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits
OSHA Vacated PELs: Acetone: 750 ppm TWA; 1800 mg/m3 TWA Ethyl alcohol: 1000 ppm TWA; 1900 mg/m3 TWA Deionized water: No OSHA Vacated PELs are listed for this chemical. Methyl alcohol: 200 ppm TWA; 260 mg/m3 TWA Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: Liquid Appearance: clear, colorless Odor: Pungent pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 133 deg F Freezing/Melting Point:-116 deg C Decomposition Temperature:Not available. Solubility: Soluble. Specific Gravity/Density:0.794 @ 25癈 Molecular Formula:Not available. Molecular Weight:Not available.
Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: High temperatures, ignition sources, temperatures above 220癈. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 67-64-1: AL3150000 CAS# 64-17-5: KQ6300000 CAS# 7732-18-5: ZC0110000 CAS# 67-56-1: PC1400000 LD50/LC50: CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, eye: 10 uL Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H; Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg; Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg; . CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg; . CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg; . Carcinogenicity: CAS# 67-64-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 64-17-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 67-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information found Teratogenicity: See actual entry in RTECS for complete information. Reproductive Effects: TDLo(Oral, rat) = 273 gm/kg;Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count). Mutagenicity: Sex chromosome loss and nondisjunction(Yeast - Saccharomyces cerevisiae) = 47600 ppm; Cytogenetic analysis(Rodent - hamster Fibroblast)= 40 gm/L. Neurotoxicity: See actual entry in RTECS for complete information. Other Studies:
No information available.
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: CAS# 67-64-1: waste number U002 (Ignitable waste). CAS# 67-56-1: waste number U154 (Ignitable waste).
US FEDERAL TSCA CAS# 67-64-1 is listed on the TSCA inventory. CAS# 64-17-5 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 67-56-1 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules CAS# 67-64-1: Test for Health Effects Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 67-64-1: 5000 lb final RQ; 2270 kg final RQ CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 67-64-1: immediate, fire. CAS # 64-17-5: immediate, delayed, fire. CAS # 67-56-1: immediate, fire. Section 313 This material contains Methyl alcohol (CAS# 67-56-1, 2%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 67-64-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 64-17-5 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. California Prop 65 WARNING: This product contains Ethyl alcohol, a chemical known to the state of California to cause developmental reproductive toxicity. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI F Risk Phrases: R 11 Highly flammable. R 36 Irritating to eyes. R 66 Repeated exposure may cause skin dryness or cracking. R 67 Vapours may cause drowsiness and dizziness. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 9 Keep container in a well-ventilated place. WGK (Water Danger/Protection) CAS# 67-64-1: 0 CAS# 64-17-5: 0 CAS# 7732-18-5: No information available. CAS# 67-56-1: 1 Canada - DSL/NDSL CAS# 67-64-1 is listed on Canada's DSL List. CAS# 64-17-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of B2, D2B. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 67-64-1 is listed on the Canadian Ingredient Disclosure List. CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List. CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List.
MSDS Creation Date: 3/18/1999 Revision #7 Date: 10/05/2004 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Catalog Numbers: 23255960, 23270180, 23291472, 66761 Synonyms: None. Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: purple liquid. Flash Point: 120 deg F.
Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid. Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Extinguishing Media: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Flash Point: 120e deg F ( 48.89 deg C) Autoignition Temperature: Not available. Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 2; Instability: 0
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Provide ventilation.
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits
OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Ethanol: 1000 ppm TWA; 1900 mg/m3 TWA Methanol: 200 ppm TWA; 260 mg/m3 TWA Phenol: 5 ppm TWA; 19 mg/m3 TWA Crystal Violet: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: Liquid Appearance: purple Odor: Alcoholic odor. pH: Not available. Vapor Pressure: 40 mm Hg @19 C Vapor Density: 1.59 (Air=1) Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 98 deg C Freezing/Melting Point:-114 deg C Decomposition Temperature:Not available. Solubility: Complete in water. Specific Gravity/Density:1 (Water=1) Molecular Formula:Not applicable. Molecular Weight:Not available.
Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Ignition sources. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 7732-18-5: ZC0110000 CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 108-95-2: SJ3325000 CAS# 548-62-9: BO9000000 LD50/LC50: CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg; . CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg; . CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, mouse: LC50 = 177 mg/m3/4H; Inhalation, rat: LC50 = 316 mg/m3; Inhalation, rat: LC50 = 316 mg/m3/4H; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 = 317 mg/kg; Oral, rat: LD50 = 512 mg/kg; Skin, rabbit: LD50 = 630 mg/kg; Skin, rat: LD50 = 669 mg/kg; Skin, rat: LD50 = 1500 mg/kg; . CAS# 548-62-9: Oral, mouse: LD50 = 96 mg/kg; Oral, rabbit: LD50 = 150 mg/kg; Oral, rat: LD50 = 420 mg/kg; . Carcinogenicity: CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 64-17-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 67-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 108-95-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 548-62-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information found Teratogenicity: Repeated ingestion of ethanol by pregnant mothers has been shown to adversely affect the central nervous system of the fetus, producing a collection of effects which together constitute the fetal alcohol syndrome. Reproductive Effects: No information found Mutagenicity: No information found Neurotoxicity: No information found Other Studies:
No information available.
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: CAS# 67-56-1: waste number U154 (Ignitable waste). CAS# 108-95-2: waste number U188.
US FEDERAL TSCA CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 64-17-5 is listed on the TSCA inventory. CAS# 67-56-1 is listed on the TSCA inventory. CAS# 108-95-2 is listed on the TSCA inventory. CAS# 548-62-9 is listed on the TSCA inventory. Health & Safety Reporting List CAS# 108-95-2: Effective 6/1/87, Sunset 6/1/97 Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ CAS# 108-95-2: 1000 lb final RQ; 454 kg final RQ SARA Section 302 Extremely Hazardous Substances CAS# 108-95-2: 500 lb TPQ (lower threshold); 10000 lb TPQ (upper thres hold) SARA Codes CAS # 64-17-5: immediate, delayed, fire. CAS # 67-56-1: immediate, fire. CAS # 108-95-2: immediate, delayed, fire. CAS # 548-62-9: immediate. Section 313 Methanol is not at a high enough concentration to be reportable under Section 313. Phenol is not at a high enough concentration to be reportable under Section 313. No chemicals are reportable under Section 313. Clean Air Act: CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). CAS# 108-95-2 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 108-95-2 is listed as a Hazardous Substance under the CWA. CAS# 108-95-2 is listed as a Priority Pollutant under the Clean Water Act. CAS# 108-95-2 is listed as a Toxic Pollutant under the Clean Water Act. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 64-17-5 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 108-95-2 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 548-62-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 WARNING: This product contains Ethanol, a chemical known to the state of California to cause developmental reproductive toxicity. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 7732-18-5: No information available. CAS# 64-17-5: 0 CAS# 67-56-1: 1 CAS# 108-95-2: 2 CAS# 548-62-9: 2 Canada - DSL/NDSL CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 64-17-5 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 108-95-2 is listed on Canada's DSL List. CAS# 548-62-9 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of B3. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List. CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List. CAS# 108-95-2 is listed on the Canadian Ingredient Disclosure List. CAS# 548-62-9 is listed on the Canadian Ingredient Disclosure List.
MSDS Creation Date: 7/28/1998 Revision #13 Date: 2/18/2004 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Catalog Numbers: 2300584, 2300585, 23281407B, 66770 Synonyms: Mixture. Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: dark red-brown liquid.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Wash clothing before reuse. Flush skin with plenty of soap and water. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively.
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Flash Point: Not applicable. Autoignition Temperature: Not applicable. Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a cool, dry, well-ventilated area away from incompatible substances.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits
OSHA Vacated PELs: Povidone-Iodine: No OSHA Vacated PELs are listed for this chemical. Potassium Iodide: No OSHA Vacated PELs are listed for this chemical. Deionized Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: Liquid Appearance: dark red-brown Odor: Iodine pH: Not available. Vapor Pressure: Not available. Vapor Density: >1.00 Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 100 deg C Freezing/Melting Point:> 0 deg C Decomposition Temperature:Not available. Solubility: Soluble in water. Specific Gravity/Density:~1 Molecular Formula:Solution Molecular Weight:Not available.
Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat. Incompatibilities with Other Materials: Incompatabilities with potassium iodide include: salts of alkaloids, chloral hydrate, calomel(mercurous chloride) potassium chlorate, metallic salts, tartaric and other acids, bromine trifluoride, and fluorine perchlorate, oxidizing agents. Incompatibilities with PVP include oxidizing agents. Hazardous Decomposition Products: Irritating and toxic fumes and gases, oxides of potassium, iodine. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 25655-41-8: TR1579600 CAS# 7681-11-0: TT2975000 CAS# 7732-18-5: ZC0110000 LD50/LC50: CAS# 25655-41-8: Draize test, rabbit, skin: 500 mg Mild; Oral, mouse: LD50 = 8100 mg/kg; Oral, rat: LD50 = >8 gm/kg; . CAS# 7681-11-0: . CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . Carcinogenicity: CAS# 25655-41-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7681-11-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Iodine salts can produce deformity, illness, and death of a fetus. PVP(iodine complex) has been shown to present a possible risk of harm to the unborn child. Reproductive Effects: PVP(iodine complex) has been shown to produce reproductive effects when there is overexposure. Mutagenicity: No information found Neurotoxicity: No information found Other Studies:
No information available.
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.
US FEDERAL TSCA CAS# 25655-41-8 is listed on the TSCA inventory. CAS# 7681-11-0 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs None of the chemicals in this material have an RQ. SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 7681-11-0: immediate, delayed. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 25655-41-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7681-11-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 25655-41-8: 2 CAS# 7681-11-0: 1 CAS# 7732-18-5: No information available. Canada - DSL/NDSL CAS# 25655-41-8 is listed on Canada's DSL List. CAS# 7681-11-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 7681-11-0 is listed on the Canadian Ingredient Disclosure List.
MSDS Creation Date: 3/25/1998 Revision #7 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
Catalog Numbers: 23255962, 23270182, 23281407C, 23291474, 255962, 270182, 281407C, 291474, 66759E, 66760E, 66764, 66770D, 66780E, 66784 Synonyms: None. Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Appearance: clear, colorless liquid. Flash Point: 20 deg F.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Ingestion: Potential for aspiration if swallowed. Get medical aid immediately. Do not induce vomiting unless directed to do so by medical |
