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MSDS  
:
 1-Heptene
CAS  
:
 592-76-7
SYNONYMS  
:
 None Known.

Section 1 - Chemical Product and Company Identification
MSDS Name: 1-Heptene
Catalog Numbers: AC120390000, AC120390250, AC120391000
Synonyms:
None Known.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
592-76-7 1-Heptene 209-767-8

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless liquid. Flash Point: -9 deg C.
Warning! Flammable liquid and vapor. Breathing vapors may cause drowsiness and dizziness. May cause eye, skin, and respiratory tract irritation. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Target Organs: Central nervous system, lungs.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May be harmful if swallowed. May cause lung damage.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Prolonged or repeated skin contact may cause dermatitis.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Get medical aid. Wash mouth out with water. Potential for aspiration if swallowed. Get medical aid immediately. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs naturally, have victim lean forward.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: -9 deg C ( 15.80 deg F)
Autoignition Temperature: 263 deg C ( 505.40 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 3; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Avoid breathing vapor.
Storage: Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Flammables-area.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
1-Heptene none listed none listed none listed

OSHA Vacated PELs: 1-Heptene: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless
Odor: hydrocarbon-like
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: <1 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 94 deg C @760mmHg
Freezing/Melting Point:-119 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:0.697
Molecular Formula:C7H14
Molecular Weight:98.19

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 592-76-7: MJ9050525
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 592-76-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Fish: Mosquito Fish: LC50 = 49.00 mg/L; 24 Hr.; Unspecified

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: n-HEPTENE n-HEPTENE
Hazard Class: 3 3
UN Number: UN2278 UN2278
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 592-76-7 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 592-76-7 can be found on the following state right to know lists: Pennsylvania.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN F
Risk Phrases:

     R 11 Highly flammable.
     R 65 Harmful: may cause lung damage if swallowed.

Safety Phrases:

     S 16 Keep away from sources of ignition - No smoking.
     S 62 If swallowed, do not induce vomiting: seek medical advice immed
     iately and show this container or label.

WGK (Water Danger/Protection)

     CAS# 592-76-7: 1
Canada - DSL/NDSL
     CAS# 592-76-7 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 1/19/2006
Revision #3 Date: 9/14/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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Methyl 3-(1H-1,2,4-triazol-1-ylmethyl)benzoate 857284-24-3
N-Methyl-p-anisidine, 98% 5961-59-1
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2,3-Dihydrothieno[3,4-b][1,4]dioxine-5-carbaldehyde 204905-77-1
(2-Methyl-2H-indazol-3-yl)methanol 58536-48-4
m-Toluenethiol 108-40-7
Dehydroabietylamine, tech. 1446-61-3
Nitronium hexafluorophosphate 19200-21-6
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N-Bromophthalimide 2439-85-2
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Bismuth(III) trifluoromethanesulfonate 88189-03-1
1-Heptene 592-76-7
cis-2-Pentene 627-20-3
5-Phthalimido-3-pentyne 339310-24-6
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Trimethyl orthopropionate 24823-81-2
Zirconium atomic absorption standard solution, 1 mg/ml Zr in 5% HF 7440-67-7
DL-Bromosuccinic Acid, 96% 923-06-8
Trimethyl orthobutyrate 43083-12-1
Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate 79060-88-1
Aluminium trifluoromethanesulfonate 74974-61-1
Cerium(IV) trifluoromethanesulfonate 107792-63-2
Potassium manganate 10294-64-1
Titanium(III) fluoride 13470-08-1
Nitrosonium hexafluorophosphate 16921-91-8
Silver(I) hydrogenfluoride 12249-52-4
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5-(5-bromo-2-thienyl)-1H-pyrazole 166196-67-4
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3,4-Dimethoxyphenethyl isothiocyanate 21714-25-0
3-Oxo-3-piperidinopropanenitrile 15029-30-8
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