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Section 1 - Chemical Product and Company Identification |
MSDS Name: 1,1-Dichloroacetone, 98%
Catalog Numbers:
AC210660000, AC210660050, AC210661000, AC210665000
Synonyms:
1,1-Dichloro-2-propanone; Alpha, alpha-dichloracetone; Dichloromethyl
methyl ketone; 2-Propanone, 1,1-dichloro-
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 513-88-2 |
1,1-Dichloroacetone |
98 | 208-175-7 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: Oily - Colorless Liquid. Flash Point: 46 deg C.
Warning! Flammable liquid and
vapor. Lachrymator (substance which increases the flow
of tears). Causes eye and skin irritation. Causes digestive and
respiratory tract irritation. Hygroscopic (absorbs moisture from the
air).
Target Organs: None.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal tract irritation.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. If
breathing has ceased apply artificial respiration using oxygen and a
suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and
flash back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Will burn if
involved in a fire. Use water spray to keep fire-exposed containers
cool. Containers may explode in the heat of a fire. Flammable liquid
and vapor. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. Cool containers with flooding quantities of water until well
after fire is out.
Flash Point: 46 deg C ( 114.80 deg F)
Autoignition Temperature: 560 deg C ( 1,040.00 deg F)
Explosion Limits, Lower:4.40 vol %
Upper: .00 vol %
NFPA Rating:
(estimated) Health: 1; Flammability: 2; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Stop leak only
if you can do so without risk.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 1,1-Dichloroacetone
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
1,1-Dichloroacetone:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: Oily - Colorless Liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 4.37
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 117.0 - 118.0 deg C @ 760.00m
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Slightly soluble.
Specific Gravity/Density:1.3070g/cm3
Molecular Formula:C3H4Cl2O
Molecular Weight:126.97
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, contact with
water, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases,
moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 513-88-2:
UC1428000
LD50/LC50:
CAS# 513-88-2:
Oral, mouse: LD50 =
250 mg/kg;
.
Oral, mouse: LD50 = 250 mg/kg.; Oral, rat: TDLo = 3600
Carcinogenicity:
CAS# 513-88-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information.
Teratogenicity:
No data available.
Reproductive Effects:
No information.
Mutagenicity:
Mutation in microorganisms: Salmonella typhimurium = 1
umol/plate. Mutation test systems: Escherichia coli = 30
mg/L.
Neurotoxicity:
No information.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
FLAMMABLE LIQUIDS, N.O.S. |
No information available. |
| Hazard Class: |
3 |
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| UN Number: |
UN1993 |
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| Packing Group: |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 513-88-2 is not listed on the TSCA inventory.
It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 513-88-2 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static discharges.
S 7 Keep container tightly closed.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 513-88-2: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
This product has a WHMIS classification of B3, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 11/02/1998
Revision #4 Date: 3/15/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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