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MSDS  
:
 Beryllium acetate, basic
CAS  
:
 19049-40-2
SYNONYMS  
:
 Beryllium oxide acetate; Beryllium oxyacetate.

Section 1 - Chemical Product and Company Identification
MSDS Name: Beryllium acetate, basic
Catalog Numbers: AC197070000, AC197070500
Synonyms:
Beryllium oxide acetate; Beryllium oxyacetate.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
19049-40-2 Beryllium acetate, basic 100 242-785-4

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white flakes.
Warning! Causes eye, skin, and respiratory tract irritation. May cause allergic skin reaction. Cancer suspect agent.
Target Organs: Lungs, skin.


Potential Health Effects
Eye: Causes eye irritation. May cause chemical conjunctivitis.
Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation: Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Chronic: Effects may be delayed. Repeated or prolonged exposure may cause allergic reactions in sensitive individuals. Chronic beryllium disease, an immunologically mediated response occurring after a latent period ranging from a few weeks to many years, causes difficult breathing on exertion, weight loss, nonproductive cough, fatigue, chest pain, anorexia, and weakness. Cancer suspect agent.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Beryllium acetate, basic 0.002 mg/m3 TWA (as Be) (listed under Beryllium compounds, n.o.s.).0.01 mg/m3 STEL (as Be) (listed under Beryllium compounds, n.o.s.). 4 mg/m3 IDLH (as Be) (listed under Beryllium compounds, n.o.s.). 2 g/m3 TWA (listed under Beryllium compounds, n.o.s.).5 g/m3 Ceiling (listed under Beryllium compounds, n.o.s.).

OSHA Vacated PELs: Beryllium acetate, basic: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Flakes
Appearance: white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 331 deg C
Freezing/Melting Point:284 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:1.3600g/cm3
Molecular Formula:C12H18O13Be4
Molecular Weight:406.32

Section 10 - Stability and Reactivity


Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information


RTECS#:      
CAS# 19049-40-2: DS2900000
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 19049-40-2:

  • ACGIH: A1 - Confirmed Human Carcinogen (listed as 'Beryllium compounds, n.o.s.').
  • California: carcinogen, initial date 10/1/87 (listed as Beryllium compounds, n.o.s.).
  • NTP: Known carcinogen (listed as Beryllium compounds, n.o.s.).
  • IARC: Group 1 carcinogen (listed as Beryllium compounds, n.o.s.).

Epidemiology: Epidemiologic studies have demonstrated a statistically significant increase in lung cancer mortality in beryllium-exposed workers.
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: BERYLLIUM COMPOUNDS, N.O.S. No information available.
Hazard Class: 6.1
UN Number: UN1566
Packing Group: II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 19049-40-2 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 19049-40-2: immediate, delayed.
Section 313
     This material contains Beryllium acetate, basic (listed as Beryllium compounds, n.o.s.), 100%, (CAS# 19049-40-2) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 19049-40-2 (listed as Beryllium compounds, n.o.s.) is listed as a      hazardous air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 19049-40-2 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 19049-40-2 can be found on the following state right to know lists: California, (listed as Beryllium compounds, n.o.s.), Pennsylvania, (listed as Beryllium compounds, n.o.s.), Minnesota, (listed as Beryllium compounds, n.o.s.).

California Prop 65
The following statement(s) is(are) made in order to comply with the California Safe Drinking Water Act:
WARNING: This product contains Beryllium acetate, basic, listed as `Beryllium compounds, n.o.s.', a chemical known to the state of California to cause cancer.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T+
Risk Phrases:

     R 25 Toxic if swallowed.
     R 26 Very toxic by inhalation.
     R 36/37/38 Irritating to eyes, respiratory system and skin.
     R 43 May cause sensitization by skin contact.
     R 49 May cause cancer by inhalation.
     R 48/23 Toxic : danger of serious damage to health by prolonged
     exposure through inhalation.

Safety Phrases:

     S 37 Wear suitable gloves.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 53 Avoid exposure - obtain special instructions before use.
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 19049-40-2: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     This product has a WHMIS classification of D2A, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 19049-40-2 (listed as Beryllium compounds, n.o.s.) is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 4/05/1997
Revision #7 Date: 3/22/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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